Zr-MOF membranes with ultra-fast water-selective permeation towards intensification of esterification reaction

Guozhen Liu, Zhenggang Wang, Cailing Chen, Jiahui Li, Guangyuan Zhou, Wenqi Ji, Gongping Liu, Wanqin Jin

Research output: Contribution to journalArticlepeer-review

Abstract

Well-intergrown polycrystalline UiO-66 membranes were successfully synthesized on polymeric substrate under mild synthesis conditions of low temperature and short synthesis time. Benefiting from angstrom-sized lattice apertures, the UiO-66 membranes with fast water selective transport channels revealed an unprecedented high solvents dehydration performance with permeation flux of up to ~6100 g·m-2·h-1 and separation factor of ~7500, showing great potential for intensification of esterification reaction.
Original languageEnglish (US)
JournalCHEMICAL COMMUNICATIONS
DOIs
StatePublished - May 31 2023

Bibliographical note

KAUST Repository Item: Exported on 2023-06-06
Acknowledgements: This work was supported by the Natural Science Foundation of Jiangsu Province (BK20220002), the National Natural Science Foundation of China (22278210, 22038006) and the China Postdoctoral Science Foundation (2022TQ0147, 2022M721584).

ASJC Scopus subject areas

  • Materials Chemistry
  • Surfaces, Coatings and Films
  • Metals and Alloys
  • Ceramics and Composites
  • Chemistry(all)
  • Catalysis
  • Electronic, Optical and Magnetic Materials

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