Abstract
Grafting of Zr(NMe2)4 on mesoporous silica SBA-15 afforded selectively well-defined surface species SiOZr(NMe2) (η2NMeCH2). 2D solid-state NMR (1H- 13C HETCOR, Multiple Quantum) experiments have shown a unique structural rearrangement occurring on the immobilised zirconium bis methylamido ligand. © The Royal Society of Chemistry 2013.
Original language | English (US) |
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Pages (from-to) | 4616 |
Journal | Chemical Communications |
Volume | 49 |
Issue number | 41 |
DOIs | |
State | Published - 2013 |
Bibliographical note
KAUST Repository Item: Exported on 2020-10-01ASJC Scopus subject areas
- Materials Chemistry
- Surfaces, Coatings and Films
- Metals and Alloys
- Ceramics and Composites
- General Chemistry
- Catalysis
- Electronic, Optical and Magnetic Materials