Abstract
Two new water-soluble diphosphacyclooctanes been synthesized and characterized by NMR and surface tension measurements. Both phosphanes proved to coordinate rhodium in a very selective way as well-defined bidentates were obtained. When used in Rh-catalyzed hydroformylation of terminal alkenes, both ligands positively impacted the reaction chemoselectivity. © 2012 Elsevier B.V.
Original language | English (US) |
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Pages (from-to) | 77-81 |
Number of pages | 5 |
Journal | Catalysis Communications |
Volume | 29 |
DOIs | |
State | Published - Dec 2012 |
Bibliographical note
KAUST Repository Item: Exported on 2020-10-01Acknowledgements: This work was supported by the Centre National de la Recherche Scientifique (CNRS).
ASJC Scopus subject areas
- General Chemistry
- Catalysis
- Process Chemistry and Technology