Wafer-scale single-crystal monolayer graphene grown on sapphire substrate

Junzhu Li, Mingguang Chen, Abdus Samad, Haocong Dong, Avijeet Ray, Junwei Zhang, Xiaochuan Jiang, Udo Schwingenschlögl, Jari Domke, Cailing Chen, Yu Han, Torsten Fritz, Rodney S. Ruoff, Bo Tian, Xixiang Zhang

Research output: Contribution to journalArticlepeer-review

10 Scopus citations


The growth of inch-scale high-quality graphene on insulating substrates is desirable for electronic and optoelectronic applications, but remains challenging due to the lack of metal catalysis. Here we demonstrate the wafer-scale synthesis of adlayer-free ultra-flat single-crystal monolayer graphene on sapphire substrates. We converted polycrystalline Cu foil placed on Al2O3(0001) into single-crystal Cu(111) film via annealing, and then achieved epitaxial growth of graphene at the interface between Cu(111) and Al2O3(0001) by multi-cycle plasma etching-assisted–chemical vapour deposition. Immersion in liquid nitrogen followed by rapid heating causes the Cu(111) film to bulge and peel off easily, while the graphene film remains on the sapphire substrate without degradation. Field-effect transistors fabricated on as-grown graphene exhibited good electronic transport properties with high carrier mobilities. This work breaks a bottleneck of synthesizing wafer-scale single-crystal monolayer graphene on insulating substrates and could contribute to next-generation graphene-based nanodevices.
Original languageEnglish (US)
JournalNature Materials
StatePublished - Jan 20 2022

ASJC Scopus subject areas

  • Mechanics of Materials
  • Materials Science(all)
  • Chemistry(all)
  • Mechanical Engineering
  • Condensed Matter Physics


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