TY - JOUR
T1 - Visible-Light Photoredox-Catalyzed Giese Reaction: Decarboxylative Addition of Amino Acid Derived α-Amino Radicals to Electron-Deficient Olefins
AU - Millet, Anthony
AU - Lefebvre, Quentin
AU - Rueping, Magnus
N1 - KAUST Repository Item: Exported on 2020-10-01
Acknowledgements: European Research Council
PY - 2016/6/20
Y1 - 2016/6/20
N2 - A tin- and halide-free, visible-light photoredox-catalyzed Giese reaction was developed. Primary and secondary α-amino radicals were generated readily from amino acids in the presence of catalytic amounts of an iridium photocatalyst. The reactivity of the α-amino radicals has been evaluated for the functionalization of a variety of activated olefins. © 2016 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim
AB - A tin- and halide-free, visible-light photoredox-catalyzed Giese reaction was developed. Primary and secondary α-amino radicals were generated readily from amino acids in the presence of catalytic amounts of an iridium photocatalyst. The reactivity of the α-amino radicals has been evaluated for the functionalization of a variety of activated olefins. © 2016 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim
UR - http://hdl.handle.net/10754/621688
UR - http://doi.wiley.com/10.1002/chem.201602257
UR - http://www.scopus.com/inward/record.url?scp=84985997763&partnerID=8YFLogxK
U2 - 10.1002/chem.201602257
DO - 10.1002/chem.201602257
M3 - Article
C2 - 27321136
SN - 0947-6539
VL - 22
SP - 13464
EP - 13468
JO - Chemistry - A European Journal
JF - Chemistry - A European Journal
IS - 38
ER -