Versatile Strategy for Multi-Stimuli-Responsive Fluorescent Material Based on Cross-Linking-Induced Emission. Application in Encryption

Yu Jiang; Jiahui Ma; Ziyu Ran; Huiqing Zhong; Daohong Zhang; Nikos Hadjichristidis

doi:10.1002/ange.202208516

Versatile Strategy for Multi-Stimuli-Responsive Fluorescent Material Based on Cross-Linking-Induced Emission. Application in Encryption

Yu Jiang, Jiahui Ma, Ziyu Ran, Huiqing Zhong, Daohong Zhang, Nikos Hadjichristidis

Research output: Contribution to journal › Article › peer-review

Abstract

Versatile strategy for smart fluorescent materials is lacking due to their diverse responding mechanisms and incompatibility of responsive behaviors. Herein presents an adaptable strategy toward multi-stimuli-responsive fluorescent material with stage-by-stage responsive behavior by blending linear polymers modified with different stimulus-responsive moieties and AIE cross-linker. Under stimuli, the linear polymer can cross-link with the cross-linker to form networks, which intrinsically restrict the intramolecular rotation of the AIE molecule to induce strong emission. A unified stimuli-responsive mechanism is involved in that various stimuli are transferred through the organized "stimulus-crosslink-emission" process. This strategy ensures the compatibility of different stimuli-responses and the adjustability of stimulus-response behavioral logic. These multi-stimuli-responsive fluorescent materials have exhibited strong accessibility and adaptability for information encryption.

Original language	English (US)
Journal	Angewandte Chemie
DOIs	https://doi.org/10.1002/ange.202208516
State	Published - Sep 9 2022

Bibliographical note

KAUST Repository Item: Exported on 2022-09-12
Acknowledgements: We gratefully acknowledge financial support from the National Natural Science Foundation of China (52103016,51873233), Innovation Group of National Ethnic Affairs Commission of China (MZR20006), and the South-Central Minzu University (YZZ19002). N.H. acknowledges the support of KAUST.

ASJC Scopus subject areas

General Medicine

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10.1002/ange.202208516

https://repository.kaust.edu.sa/bitstream/10754/681120/1/Angewandte%20Chemie%20-%202022%20-%20Jiang%20-%20Versatile%20Strategy%20for%20Multi%e2%80%90Stimuli%e2%80%90Responsive%20Fluorescent%20Material%20Based%20on_removed.pdf

Cite this

@article{f783e81d0ffc4956b6d6079fab391acc,

title = "Versatile Strategy for Multi-Stimuli-Responsive Fluorescent Material Based on Cross-Linking-Induced Emission. Application in Encryption",

abstract = "Versatile strategy for smart fluorescent materials is lacking due to their diverse responding mechanisms and incompatibility of responsive behaviors. Herein presents an adaptable strategy toward multi-stimuli-responsive fluorescent material with stage-by-stage responsive behavior by blending linear polymers modified with different stimulus-responsive moieties and AIE cross-linker. Under stimuli, the linear polymer can cross-link with the cross-linker to form networks, which intrinsically restrict the intramolecular rotation of the AIE molecule to induce strong emission. A unified stimuli-responsive mechanism is involved in that various stimuli are transferred through the organized {"}stimulus-crosslink-emission{"} process. This strategy ensures the compatibility of different stimuli-responses and the adjustability of stimulus-response behavioral logic. These multi-stimuli-responsive fluorescent materials have exhibited strong accessibility and adaptability for information encryption.",

author = "Yu Jiang and Jiahui Ma and Ziyu Ran and Huiqing Zhong and Daohong Zhang and Nikos Hadjichristidis",

note = "KAUST Repository Item: Exported on 2022-09-12 Acknowledgements: We gratefully acknowledge financial support from the National Natural Science Foundation of China (52103016,51873233), Innovation Group of National Ethnic Affairs Commission of China (MZR20006), and the South-Central Minzu University (YZZ19002). N.H. acknowledges the support of KAUST.",

year = "2022",

month = sep,

day = "9",

doi = "10.1002/ange.202208516",

language = "English (US)",

journal = "Angewandte Chemie",

issn = "0044-8249",

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T1 - Versatile Strategy for Multi-Stimuli-Responsive Fluorescent Material Based on Cross-Linking-Induced Emission. Application in Encryption

AU - Jiang, Yu

AU - Ma, Jiahui

AU - Ran, Ziyu

AU - Zhong, Huiqing

AU - Zhang, Daohong

AU - Hadjichristidis, Nikos

N1 - KAUST Repository Item: Exported on 2022-09-12 Acknowledgements: We gratefully acknowledge financial support from the National Natural Science Foundation of China (52103016,51873233), Innovation Group of National Ethnic Affairs Commission of China (MZR20006), and the South-Central Minzu University (YZZ19002). N.H. acknowledges the support of KAUST.

PY - 2022/9/9

Y1 - 2022/9/9

N2 - Versatile strategy for smart fluorescent materials is lacking due to their diverse responding mechanisms and incompatibility of responsive behaviors. Herein presents an adaptable strategy toward multi-stimuli-responsive fluorescent material with stage-by-stage responsive behavior by blending linear polymers modified with different stimulus-responsive moieties and AIE cross-linker. Under stimuli, the linear polymer can cross-link with the cross-linker to form networks, which intrinsically restrict the intramolecular rotation of the AIE molecule to induce strong emission. A unified stimuli-responsive mechanism is involved in that various stimuli are transferred through the organized "stimulus-crosslink-emission" process. This strategy ensures the compatibility of different stimuli-responses and the adjustability of stimulus-response behavioral logic. These multi-stimuli-responsive fluorescent materials have exhibited strong accessibility and adaptability for information encryption.

AB - Versatile strategy for smart fluorescent materials is lacking due to their diverse responding mechanisms and incompatibility of responsive behaviors. Herein presents an adaptable strategy toward multi-stimuli-responsive fluorescent material with stage-by-stage responsive behavior by blending linear polymers modified with different stimulus-responsive moieties and AIE cross-linker. Under stimuli, the linear polymer can cross-link with the cross-linker to form networks, which intrinsically restrict the intramolecular rotation of the AIE molecule to induce strong emission. A unified stimuli-responsive mechanism is involved in that various stimuli are transferred through the organized "stimulus-crosslink-emission" process. This strategy ensures the compatibility of different stimuli-responses and the adjustability of stimulus-response behavioral logic. These multi-stimuli-responsive fluorescent materials have exhibited strong accessibility and adaptability for information encryption.

UR - http://hdl.handle.net/10754/681120

UR - https://onlinelibrary.wiley.com/doi/10.1002/ange.202208516

U2 - 10.1002/ange.202208516

DO - 10.1002/ange.202208516

M3 - Article

SN - 0044-8249

JO - Angewandte Chemie

JF - Angewandte Chemie

ER -

Versatile Strategy for Multi-Stimuli-Responsive Fluorescent Material Based on Cross-Linking-Induced Emission. Application in Encryption

Abstract

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