Unusual C-C bond cleavage in the formation of amine-bis(phenoxy) group 4 benzyl complexes: Mechanism of formation and application to stereospecific polymerization

Keyphrases

• Phenoxy 100%
• Protonolysis 100%
• Phenoxy Group 100%
• Stereospecific Polymerization 100%
• Benzylium 100%
• Dibenzyl 66%
• Abstractive 33%
• 6H2O 33%
• Benzyl Group 33%
• Radical Coupling 33%
• Oxidation-elimination 33%
• Photochemical Decomposition 33%
• Mechanistic Pathways 33%
• Tautomerization 33%
• Ti(IV) 33%
• Adamantyl 33%
• Bond Loss 33%
• Benzyl Cation 33%
• Cationic Complexes 33%
• H Radical 33%
• Benzyl Radical 33%
• Tetradentate Amine 33%

Chemistry

• Ambient Reaction Temperature 100%
• Stereospecific Polymerization 100%
• Phenol 100%
• Density Functional Theory 50%
• X-Ray Diffraction 50%
• Tris 50%
• Stereoregular Polymer 50%
• Tautomerization 50%
• Benzyl Group 50%
• Cation 50%