Understanding Photocatalytic Activity Dependence on Node Topology in Ti-Based Metal–Organic Frameworks

Nikita Kolobov, Abdelali Zaki, Katarzyna Świrk, Partha Maity, Luis Carlos Garzon Tovar, Giasemi K. Angeli, Alla Dikhtiarenko, G. Delahay, Pantelis N. Trikalitis, Abdul-Hamid M. Emwas, Amandine Cadiau, Omar F. Mohammed, Christopher H. Hendon, Karim Adil, Jorge Gascon

Research output: Contribution to journalArticlepeer-review

3 Scopus citations

Abstract

Despite the drive to develop more efficient Ti-based metal–organic framework (MOF) photocatalysts, MIL-125-NH2 is still the benchmark, and only a few design principles have been offered to improve photocatalytic performance. Linker functionalization in Ti MOFs has been shown to enable photocatalysis under visible light by closing the electronic band gap, significantly improving charge carrier lifetimes. Limited by known Ti-based MOFs, the role of node nuclearity and topology on photocatalytic activity remains unclear. Here, we report a new MOF, ICGM-1, a 3D-connected framework featuring 1D Ti–O rods. Photocatalytic hydrogen evolution reveals a significant difference in activity, which we attribute solely to node geometry. Using time-resolved spectroscopy and DFT calculations, we ascribe these differences to subtle electronic and geometric properties, paving the way for the development of Ti-MOF photocatalysts.
Original languageEnglish (US)
Pages (from-to)1481-1487
Number of pages7
JournalACS Materials Letters
DOIs
StatePublished - Apr 17 2023

Bibliographical note

KAUST Repository Item: Exported on 2023-05-05
Acknowledgements: Funding for this work was provided by King Abdullah University of Science and Technology (KAUST). Funding for this work was provided by King Abdullah University of Science and Technology (KAUST) This work is based upon work supported by the National Science Foundation through the Division of Materials Research under Grant No. DMR-1956403. C.H.H. also acknowledges the Camille and Henry Dreyfus Foundation.

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