Two-step crystal engineering of porous nets from [Cr3(μ 3-O)(RCO2)6] and [Cu3(μ 3-Cl)(RNH2)6Cl6] molecular building blocks

Sameh K. Elsaidi; Mona Hassan Mohamed; Łukasz Wojtas; Amy Cairns; Mohamed Eddaoudi; Michael J. Zaworotko

doi:10.1039/c3cc44133d

Two-step crystal engineering of porous nets from [Cr3(μ 3-O)(RCO2)6] and [Cu3(μ 3-Cl)(RNH2)6Cl6] molecular building blocks

Sameh K. Elsaidi, Mona Hassan Mohamed, Łukasz Wojtas, Amy Cairns, Mohamed Eddaoudi, Michael J. Zaworotko

Research output: Contribution to journal › Article › peer-review

40 Scopus citations

Abstract

Two porous nets have been prepared via a 2-step crystal engineering approach that links decorated trigonal prismatic [Cr3(μ 3-O)(CO2)6] and [Cu3(μ 3-Cl)(RNH2)6Cl6] molecular building blocks, MBBs. tp-PMBB-5-acs-1 is a rare example of a rigid acs underlying net whereas tp-PMBB-6-stp-1, an stp underlying net, exhibits free NH2 groups in its channels and a relatively high isosteric heat of adsorption for CO2. © 2013 The Royal Society of Chemistry.

Original language	English (US)
Pages (from-to)	8154
Journal	Chemical Communications
Volume	49
Issue number	74
DOIs	https://doi.org/10.1039/c3cc44133d
State	Published - 2013

Bibliographical note

KAUST Repository Item: Exported on 2020-10-01

ASJC Scopus subject areas

Materials Chemistry
Surfaces, Coatings and Films
Metals and Alloys
Ceramics and Composites
General Chemistry
Catalysis
Electronic, Optical and Magnetic Materials

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10.1039/c3cc44133d

Cite this

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title = "Two-step crystal engineering of porous nets from [Cr3(μ 3-O)(RCO2)6] and [Cu3(μ 3-Cl)(RNH2)6Cl6] molecular building blocks",

abstract = "Two porous nets have been prepared via a 2-step crystal engineering approach that links decorated trigonal prismatic [Cr3(μ 3-O)(CO2)6] and [Cu3(μ 3-Cl)(RNH2)6Cl6] molecular building blocks, MBBs. tp-PMBB-5-acs-1 is a rare example of a rigid acs underlying net whereas tp-PMBB-6-stp-1, an stp underlying net, exhibits free NH2 groups in its channels and a relatively high isosteric heat of adsorption for CO2. {\textcopyright} 2013 The Royal Society of Chemistry.",

author = "Elsaidi, {Sameh K.} and Mohamed, {Mona Hassan} and {\L}ukasz Wojtas and Amy Cairns and Mohamed Eddaoudi and Zaworotko, {Michael J.}",

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doi = "10.1039/c3cc44133d",

language = "English (US)",

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pages = "8154",

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AU - Mohamed, Mona Hassan

AU - Wojtas, Łukasz

AU - Cairns, Amy

AU - Eddaoudi, Mohamed

AU - Zaworotko, Michael J.

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PY - 2013

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N2 - Two porous nets have been prepared via a 2-step crystal engineering approach that links decorated trigonal prismatic [Cr3(μ 3-O)(CO2)6] and [Cu3(μ 3-Cl)(RNH2)6Cl6] molecular building blocks, MBBs. tp-PMBB-5-acs-1 is a rare example of a rigid acs underlying net whereas tp-PMBB-6-stp-1, an stp underlying net, exhibits free NH2 groups in its channels and a relatively high isosteric heat of adsorption for CO2. © 2013 The Royal Society of Chemistry.

AB - Two porous nets have been prepared via a 2-step crystal engineering approach that links decorated trigonal prismatic [Cr3(μ 3-O)(CO2)6] and [Cu3(μ 3-Cl)(RNH2)6Cl6] molecular building blocks, MBBs. tp-PMBB-5-acs-1 is a rare example of a rigid acs underlying net whereas tp-PMBB-6-stp-1, an stp underlying net, exhibits free NH2 groups in its channels and a relatively high isosteric heat of adsorption for CO2. © 2013 The Royal Society of Chemistry.

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Two-step crystal engineering of porous nets from [Cr3(μ 3-O)(RCO2)6] and [Cu3(μ 3-Cl)(RNH2)6Cl6] molecular building blocks

Abstract

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ASJC Scopus subject areas

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CCDC 943025: Experimental Crystal Structure Determination : catena-(hexakis(mu~3~-3-Aminobenzoato-N,O,O')-(mu~3~-chloro)-(mu~3~-oxo)-triaqua-hexachloro-tri-chromium-tri-copper acetonitrile dimethylformamide solvate hydrate)

CCDC 943024: Experimental Crystal Structure Determination : (mu~3~-Oxo)-hexakis(mu~2~-4-ammoniobenzoato)-tris(methanol)-tri-chromium heptanitrate chloroform methanol solvate hydrate

CCDC 943023: Experimental Crystal Structure Determination : catena-(dodecakis(mu~3~-4-Aminobenzoato-N,O,O')-bis(mu~3~-chloro)-tris(mu~3~-oxo)-hexakis(mu~2~-4-aminobenzoato-O,O')-nona-aqua-dodecachloro-nona-chromium-hexa-copper hydrate)

Cite this

Two-step crystal engineering of porous nets from [Cr3(μ 3-O)(RCO2)6] and [Cu3(μ 3-Cl)(RNH2)6Cl6] molecular building blocks

Abstract

Bibliographical note

ASJC Scopus subject areas

Access to Document

Other files and links

Fingerprint

Datasets

CCDC 943025: Experimental Crystal Structure Determination : catena-(hexakis(mu~3~-3-Aminobenzoato-N,O,O')-(mu~3~-chloro)-(mu~3~-oxo)-triaqua-hexachloro-tri-chromium-tri-copper acetonitrile dimethylformamide solvate hydrate)

CCDC 943024: Experimental Crystal Structure Determination : (mu~3~-Oxo)-hexakis(mu~2~-4-ammoniobenzoato)-tris(methanol)-tri-chromium heptanitrate chloroform methanol solvate hydrate

CCDC 943023: Experimental Crystal Structure Determination : catena-(dodecakis(mu~3~-4-Aminobenzoato-N,O,O')-bis(mu~3~-chloro)-tris(mu~3~-oxo)-hexakis(mu~2~-4-aminobenzoato-O,O')-nona-aqua-dodecachloro-nona-chromium-hexa-copper hydrate)

Cite this