Two anionic metal-organic frameworks with tunable luminescent properties induced by cations

Shu Mei Chen; Yan Fei Chen; Liyang Liu; Tian Wen; Hua Bin Zhang; Jian Zhang

doi:10.1016/j.jssc.2015.11.024

Two anionic metal-organic frameworks with tunable luminescent properties induced by cations

Shu Mei Chen, Yan Fei Chen, Liyang Liu, Tian Wen, Hua Bin Zhang, Jian Zhang

Research output: Contribution to journal › Article › peer-review

12 Scopus citations

Abstract

Two three-dimensional (3-D) MOFs, [(C2H5)4N)]3[H3O]2[Cd6Br(H2-DHBDC)8(DMF)4] (1; H4-DHBDC=2,5-dihydroxy-1,4-benzenedicarboxylic acid, DMF=N,N-dimethylformamide) and [(CH3)2NH2]2[Cd3(H2-DHBDC)4(DMF)2]·2DMF(2), are prepared from the self-assembly reactions between Cd(CH3COO)2 and H4-DHBDC, respectively. Both anionic frameworks consist of linear trinuclear Cd units (e.g., 1: [Cd3BrO2(CO2)7] and [Cd3O2(CO2)8]; 2: [Cd3O2(CO2)8]) linked by the H2-DHBDC ligands. The photoluminescent properties of compound 1 are tunable through cation-exchange with different metal ions. The results demonstrated an effective ion-exchange approach toward the functional modification of MOF materials.

Original language	English (US)
Pages (from-to)	23-27
Number of pages	5
Journal	Journal of Solid State Chemistry
Volume	235
DOIs	https://doi.org/10.1016/j.jssc.2015.11.024
State	Published - Mar 1 2016
Externally published	Yes

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Generated from Scopus record by KAUST IRTS on 2022-09-15

ASJC Scopus subject areas

Materials Chemistry
Ceramics and Composites
Physical and Theoretical Chemistry
Electronic, Optical and Magnetic Materials
Inorganic Chemistry
Condensed Matter Physics

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10.1016/j.jssc.2015.11.024

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@article{f37f8e46b8b6433a89e6f17d45e15b11,

title = "Two anionic metal-organic frameworks with tunable luminescent properties induced by cations",

abstract = "Two three-dimensional (3-D) MOFs, [(C2H5)4N)]3[H3O]2[Cd6Br(H2-DHBDC)8(DMF)4] (1; H4-DHBDC=2,5-dihydroxy-1,4-benzenedicarboxylic acid, DMF=N,N-dimethylformamide) and [(CH3)2NH2]2[Cd3(H2-DHBDC)4(DMF)2]·2DMF(2), are prepared from the self-assembly reactions between Cd(CH3COO)2 and H4-DHBDC, respectively. Both anionic frameworks consist of linear trinuclear Cd units (e.g., 1: [Cd3BrO2(CO2)7] and [Cd3O2(CO2)8]; 2: [Cd3O2(CO2)8]) linked by the H2-DHBDC ligands. The photoluminescent properties of compound 1 are tunable through cation-exchange with different metal ions. The results demonstrated an effective ion-exchange approach toward the functional modification of MOF materials.",

author = "Chen, {Shu Mei} and Chen, {Yan Fei} and Liyang Liu and Tian Wen and Zhang, {Hua Bin} and Jian Zhang",

note = "Generated from Scopus record by KAUST IRTS on 2022-09-15",

year = "2016",

month = mar,

day = "1",

doi = "10.1016/j.jssc.2015.11.024",

language = "English (US)",

volume = "235",

pages = "23--27",

journal = "Journal of Solid State Chemistry",

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TY - JOUR

T1 - Two anionic metal-organic frameworks with tunable luminescent properties induced by cations

AU - Chen, Shu Mei

AU - Chen, Yan Fei

AU - Liu, Liyang

AU - Wen, Tian

AU - Zhang, Hua Bin

AU - Zhang, Jian

N1 - Generated from Scopus record by KAUST IRTS on 2022-09-15

PY - 2016/3/1

Y1 - 2016/3/1

N2 - Two three-dimensional (3-D) MOFs, [(C2H5)4N)]3[H3O]2[Cd6Br(H2-DHBDC)8(DMF)4] (1; H4-DHBDC=2,5-dihydroxy-1,4-benzenedicarboxylic acid, DMF=N,N-dimethylformamide) and [(CH3)2NH2]2[Cd3(H2-DHBDC)4(DMF)2]·2DMF(2), are prepared from the self-assembly reactions between Cd(CH3COO)2 and H4-DHBDC, respectively. Both anionic frameworks consist of linear trinuclear Cd units (e.g., 1: [Cd3BrO2(CO2)7] and [Cd3O2(CO2)8]; 2: [Cd3O2(CO2)8]) linked by the H2-DHBDC ligands. The photoluminescent properties of compound 1 are tunable through cation-exchange with different metal ions. The results demonstrated an effective ion-exchange approach toward the functional modification of MOF materials.

AB - Two three-dimensional (3-D) MOFs, [(C2H5)4N)]3[H3O]2[Cd6Br(H2-DHBDC)8(DMF)4] (1; H4-DHBDC=2,5-dihydroxy-1,4-benzenedicarboxylic acid, DMF=N,N-dimethylformamide) and [(CH3)2NH2]2[Cd3(H2-DHBDC)4(DMF)2]·2DMF(2), are prepared from the self-assembly reactions between Cd(CH3COO)2 and H4-DHBDC, respectively. Both anionic frameworks consist of linear trinuclear Cd units (e.g., 1: [Cd3BrO2(CO2)7] and [Cd3O2(CO2)8]; 2: [Cd3O2(CO2)8]) linked by the H2-DHBDC ligands. The photoluminescent properties of compound 1 are tunable through cation-exchange with different metal ions. The results demonstrated an effective ion-exchange approach toward the functional modification of MOF materials.

UR - https://linkinghub.elsevier.com/retrieve/pii/S0022459615302577

UR - http://www.scopus.com/inward/record.url?scp=84954148875&partnerID=8YFLogxK

U2 - 10.1016/j.jssc.2015.11.024

DO - 10.1016/j.jssc.2015.11.024

M3 - Article

SN - 1095-726X

VL - 235

SP - 23

EP - 27

JO - Journal of Solid State Chemistry

JF - Journal of Solid State Chemistry

ER -

Two anionic metal-organic frameworks with tunable luminescent properties induced by cations

Abstract

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