A series of ZSM-5/FDU-12 (ZF-x) composite material with MFI microporous structure and face-centered cubic structure were successfully synthesized using the nano-assembly method under different water bath temperatures. The bath temperature had an apparent influence on the material's physical texture property. The catalytic hydrotreating performance were evaluated inside fix-bed unit, under the reaction conditions of 5 MPa and 350 °C. The sulfur and nitrogen contents of the products obtained from NiMo/ZFA-30 catalyst were reached 11.5 ppm and 4.8 ppm, respectively. The moderate acidity and the highest sulfidation ratio of active phases were responsible for the highest hydrodesulfurization (98.9 %) and hydrodenitrogenation (99.3 %) efficiency over the NiMo/ZFA-30 catalyst.
|Original language||English (US)|
|Number of pages||11|
|State||Published - Jun 10 2021|
Bibliographical noteKAUST Repository Item: Exported on 2022-06-14
Acknowledged KAUST grant number(s): OSR-2019-CPF-4103.2
Acknowledgements: This work was financially supported by the National Natural Science Foundation of China (No. 21878330, 21676298), the National Science and Technology Major Project, CNPC Key Research Project (2016E-0707) and the King Abdullah University of Science and Technology (KAUST) Office of Sponsored Research (OSR) under Award (No. OSR-2019-CPF-4103.2).
This publication acknowledges KAUST support, but has no KAUST affiliated authors.
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