TY - JOUR
T1 - Trifluoromethylselenolation of Aryldiazonium Salts: A Mild and Convenient Copper-Catalyzed Procedure for the Introduction of the SeCF3Group
AU - Nikolaienko, Pavlo
AU - Rueping, Magnus
N1 - KAUST Repository Item: Exported on 2020-10-01
PY - 2016/1/21
Y1 - 2016/1/21
N2 - The straightforward introduction of the trifluoromethylseleno group into aromatic and heteroaromatic compounds is accomplished by the utilization of readily available aryldiazonium tetrafluoroborates, potassium selenocyanate, and Ruppert-Prakash reagent. The reaction tolerates a wide range of aromatic and heteroaromatic diazonium salts and is also amenable to the synthesis of pentafluoroethyl selenoethers. Furthermore, the methodology can be applied directly starting from anilines. © 2016 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
AB - The straightforward introduction of the trifluoromethylseleno group into aromatic and heteroaromatic compounds is accomplished by the utilization of readily available aryldiazonium tetrafluoroborates, potassium selenocyanate, and Ruppert-Prakash reagent. The reaction tolerates a wide range of aromatic and heteroaromatic diazonium salts and is also amenable to the synthesis of pentafluoroethyl selenoethers. Furthermore, the methodology can be applied directly starting from anilines. © 2016 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
UR - http://hdl.handle.net/10754/621686
UR - http://onlinelibrary.wiley.com/doi/10.1002/chem.201504601/full
UR - http://www.scopus.com/inward/record.url?scp=84958817866&partnerID=8YFLogxK
U2 - 10.1002/chem.201504601
DO - 10.1002/chem.201504601
M3 - Article
C2 - 26797773
SN - 0947-6539
VL - 22
SP - 2620
EP - 2623
JO - Chemistry - A European Journal
JF - Chemistry - A European Journal
IS - 8
ER -