Trianglamine-Based Supramolecular Organic Framework with Permanent Intrinsic Porosity and Tunable Selectivity

Arnaud Chaix; Georges Mouchaham; Aleksander Shkurenko; PHUONG HOANG; Basem Moosa; Prashant Bhatt; Karim Adil; Khaled N. Salama; Mohamed Eddaoudi; Niveen M. Khashab

doi:10.1021/jacs.8b08770

Trianglamine-Based Supramolecular Organic Framework with Permanent Intrinsic Porosity and Tunable Selectivity

Arnaud Chaix, Georges Mouchaham, Aleksander Shkurenko, PHUONG HOANG, Basem Moosa, Prashant Bhatt, Karim Adil, Khaled N. Salama, Mohamed Eddaoudi, Niveen M. Khashab

Research output: Contribution to journal › Article › peer-review

88 Scopus citations

Abstract

Here we introduce for the first time a metal-free trianglamine-based supramolecular organic framework, T-SOF-1, with permanent intrinsic porosity and high affinity to CO2. The capability of tuning the pore aperture dimensions is also demonstrated by molecular guest encapsulation to afford excellent CO2/CH4 separation for natural gas upgrading.

Original language	English (US)
Pages (from-to)	14571-14575
Number of pages	5
Journal	Journal of the American Chemical Society
Volume	140
Issue number	44
DOIs	https://doi.org/10.1021/jacs.8b08770
State	Published - Oct 8 2018

Bibliographical note

KAUST Repository Item: Exported on 2020-10-01
Acknowledgements: Authors acknowledge Dr. Y. Belmabkhout for the helpful discussions and Dr. O. El-Tall for technical assistance.

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10.1021/jacs.8b08770

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title = "Trianglamine-Based Supramolecular Organic Framework with Permanent Intrinsic Porosity and Tunable Selectivity",

abstract = "Here we introduce for the first time a metal-free trianglamine-based supramolecular organic framework, T-SOF-1, with permanent intrinsic porosity and high affinity to CO2. The capability of tuning the pore aperture dimensions is also demonstrated by molecular guest encapsulation to afford excellent CO2/CH4 separation for natural gas upgrading.",

author = "Arnaud Chaix and Georges Mouchaham and Aleksander Shkurenko and PHUONG HOANG and Basem Moosa and Prashant Bhatt and Karim Adil and Salama, {Khaled N.} and Mohamed Eddaoudi and Khashab, {Niveen M.}",

note = "KAUST Repository Item: Exported on 2020-10-01 Acknowledgements: Authors acknowledge Dr. Y. Belmabkhout for the helpful discussions and Dr. O. El-Tall for technical assistance.",

year = "2018",

month = oct,

day = "8",

doi = "10.1021/jacs.8b08770",

language = "English (US)",

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T1 - Trianglamine-Based Supramolecular Organic Framework with Permanent Intrinsic Porosity and Tunable Selectivity

AU - Chaix, Arnaud

AU - Mouchaham, Georges

AU - Shkurenko, Aleksander

AU - HOANG, PHUONG

AU - Moosa, Basem

AU - Bhatt, Prashant

AU - Adil, Karim

AU - Salama, Khaled N.

AU - Eddaoudi, Mohamed

AU - Khashab, Niveen M.

N1 - KAUST Repository Item: Exported on 2020-10-01 Acknowledgements: Authors acknowledge Dr. Y. Belmabkhout for the helpful discussions and Dr. O. El-Tall for technical assistance.

PY - 2018/10/8

Y1 - 2018/10/8

N2 - Here we introduce for the first time a metal-free trianglamine-based supramolecular organic framework, T-SOF-1, with permanent intrinsic porosity and high affinity to CO2. The capability of tuning the pore aperture dimensions is also demonstrated by molecular guest encapsulation to afford excellent CO2/CH4 separation for natural gas upgrading.

AB - Here we introduce for the first time a metal-free trianglamine-based supramolecular organic framework, T-SOF-1, with permanent intrinsic porosity and high affinity to CO2. The capability of tuning the pore aperture dimensions is also demonstrated by molecular guest encapsulation to afford excellent CO2/CH4 separation for natural gas upgrading.

UR - http://hdl.handle.net/10754/630580

UR - https://pubs.acs.org/doi/10.1021/jacs.8b08770

UR - http://www.scopus.com/inward/record.url?scp=85055000754&partnerID=8YFLogxK

U2 - 10.1021/jacs.8b08770

DO - 10.1021/jacs.8b08770

M3 - Article

C2 - 30293426

SN - 0002-7863

VL - 140

SP - 14571

EP - 14575

JO - Journal of the American Chemical Society

JF - Journal of the American Chemical Society

IS - 44

ER -

Trianglamine-Based Supramolecular Organic Framework with Permanent Intrinsic Porosity and Tunable Selectivity

Abstract

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CCDC 1868816: Experimental Crystal Structure Determination : 3,10,17,24,31,38-hexaazaheptacyclo[38.2.2.212,15.226,29.04,9.018,23.032,37]octatetraconta-1(42),12,14,26,28,40,43,45,47-nonaene-3,10,17,24,31,38-hexaium hexachloride iodine unknown solvate

CCDC 1868815: Experimental Crystal Structure Determination : 3,10,17,24,31,38-hexaazoniaheptacyclo[38.2.2.212,15.226,29.04,9.018,23.032,37]octatetraconta-1(42),12,14,26,28,40,43,45,47-nonaene hexachloride hydrate

Cite this

Trianglamine-Based Supramolecular Organic Framework with Permanent Intrinsic Porosity and Tunable Selectivity

Abstract

Bibliographical note

Access to Document

Other files and links

Fingerprint

Datasets

CCDC 1868816: Experimental Crystal Structure Determination : 3,10,17,24,31,38-hexaazaheptacyclo[38.2.2.212,15.226,29.04,9.018,23.032,37]octatetraconta-1(42),12,14,26,28,40,43,45,47-nonaene-3,10,17,24,31,38-hexaium hexachloride iodine unknown solvate

CCDC 1868815: Experimental Crystal Structure Determination : 3,10,17,24,31,38-hexaazoniaheptacyclo[38.2.2.212,15.226,29.04,9.018,23.032,37]octatetraconta-1(42),12,14,26,28,40,43,45,47-nonaene hexachloride hydrate

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