Transport Properties of Polyisobutylene in Dilute Solution

L. J. Fetters; N. Hadjiehristidis; J. S. Lindner; J. W. Mays; W. W. Wilson

doi:10.1021/ma00011a015

Transport Properties of Polyisobutylene in Dilute Solution

L. J. Fetters^*, N. Hadjiehristidis, J. S. Lindner, J. W. Mays, W. W. Wilson

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

36 Scopus citations

Abstract

The dilute-solution transport properties of polyisobutylene (PIB) fractions have been measured under θ conditions and in good solvents of varying thermodynamic quality. The translational diffusion coefficients were evaluated via photon correlation spectroscopy and coupled with the results from intrinsic viscosity and low-angle laser light scattering experiments to yield the appropriate size parameters. The results allow a comparison of the properties of PIB with those of other flexible chains and with various theoretical predictions.

Original language	English (US)
Pages (from-to)	3127-3135
Number of pages	9
Journal	Macromolecules
Volume	24
Issue number	11
DOIs	https://doi.org/10.1021/ma00011a015
State	Published - May 1 1991
Externally published	Yes

ASJC Scopus subject areas

Organic Chemistry
Polymers and Plastics
Inorganic Chemistry
Materials Chemistry

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10.1021/ma00011a015

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abstract = "The dilute-solution transport properties of polyisobutylene (PIB) fractions have been measured under θ conditions and in good solvents of varying thermodynamic quality. The translational diffusion coefficients were evaluated via photon correlation spectroscopy and coupled with the results from intrinsic viscosity and low-angle laser light scattering experiments to yield the appropriate size parameters. The results allow a comparison of the properties of PIB with those of other flexible chains and with various theoretical predictions.",

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AU - Wilson, W. W.

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N2 - The dilute-solution transport properties of polyisobutylene (PIB) fractions have been measured under θ conditions and in good solvents of varying thermodynamic quality. The translational diffusion coefficients were evaluated via photon correlation spectroscopy and coupled with the results from intrinsic viscosity and low-angle laser light scattering experiments to yield the appropriate size parameters. The results allow a comparison of the properties of PIB with those of other flexible chains and with various theoretical predictions.

AB - The dilute-solution transport properties of polyisobutylene (PIB) fractions have been measured under θ conditions and in good solvents of varying thermodynamic quality. The translational diffusion coefficients were evaluated via photon correlation spectroscopy and coupled with the results from intrinsic viscosity and low-angle laser light scattering experiments to yield the appropriate size parameters. The results allow a comparison of the properties of PIB with those of other flexible chains and with various theoretical predictions.

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Transport Properties of Polyisobutylene in Dilute Solution

Abstract

ASJC Scopus subject areas

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