Transformation of Nickelalactones to Methyl Acrylate: On the Way to a Catalytic Conversion of Carbon Dioxide

S. Y. Tina Lee; Mirza Cokoja; Markus Drees; Yang Li; János Mink; Wolfgang A. Herrmann; Fritz E. Kühn

doi:10.1002/cssc.201000445

Transformation of Nickelalactones to Methyl Acrylate: On the Way to a Catalytic Conversion of Carbon Dioxide

S. Y. Tina Lee, Mirza Cokoja, Markus Drees, Yang Li, János Mink, Wolfgang A. Herrmann, Fritz E. Kühn

Research output: Contribution to journal › Article › peer-review

65 Scopus citations

Abstract

Mu-nick: The methyl iodide-mediated ring opening of nickelalactones, which can be formed by oxidative coupling of carbon dioxide and ethylene at Ni 0 complexes, induces β-H elimination, producing methyl acrylate in yields of up to 56 %. This reaction is found to be very sensitive to the ligands coordinated to the central nickel atom. © 2011 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Original language	English (US)
Pages (from-to)	1275-1279
Number of pages	5
Journal	ChemSusChem
Volume	4
Issue number	9
DOIs	https://doi.org/10.1002/cssc.201000445
State	Published - Aug 26 2011
Externally published	Yes

Bibliographical note

KAUST Repository Item: Exported on 2020-10-01
Acknowledged KAUST grant number(s): KSA-C0069/UK-C0020
Acknowledgements: This publication is based on work supported by Award KSA-C0069/UK-C0020, made by the King Abdullah University of Science and Technology (KAUST). The authors thank Dr. Bettina Bechlars for the measurement and refinement of the X-ray single crystal structure of complex 1. The authors also thank the Leibniz-Rechenzentrum for providing computing time.
This publication acknowledges KAUST support, but has no KAUST affiliated authors.

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title = "Transformation of Nickelalactones to Methyl Acrylate: On the Way to a Catalytic Conversion of Carbon Dioxide",

abstract = "Mu-nick: The methyl iodide-mediated ring opening of nickelalactones, which can be formed by oxidative coupling of carbon dioxide and ethylene at Ni 0 complexes, induces β-H elimination, producing methyl acrylate in yields of up to 56 %. This reaction is found to be very sensitive to the ligands coordinated to the central nickel atom. {\textcopyright} 2011 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.",

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note = "KAUST Repository Item: Exported on 2020-10-01 Acknowledged KAUST grant number(s): KSA-C0069/UK-C0020 Acknowledgements: This publication is based on work supported by Award KSA-C0069/UK-C0020, made by the King Abdullah University of Science and Technology (KAUST). The authors thank Dr. Bettina Bechlars for the measurement and refinement of the X-ray single crystal structure of complex 1. The authors also thank the Leibniz-Rechenzentrum for providing computing time. This publication acknowledges KAUST support, but has no KAUST affiliated authors.",

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doi = "10.1002/cssc.201000445",

language = "English (US)",

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AU - Lee, S. Y. Tina

AU - Cokoja, Mirza

AU - Drees, Markus

AU - Li, Yang

AU - Mink, János

AU - Herrmann, Wolfgang A.

AU - Kühn, Fritz E.

N1 - KAUST Repository Item: Exported on 2020-10-01 Acknowledged KAUST grant number(s): KSA-C0069/UK-C0020 Acknowledgements: This publication is based on work supported by Award KSA-C0069/UK-C0020, made by the King Abdullah University of Science and Technology (KAUST). The authors thank Dr. Bettina Bechlars for the measurement and refinement of the X-ray single crystal structure of complex 1. The authors also thank the Leibniz-Rechenzentrum for providing computing time. This publication acknowledges KAUST support, but has no KAUST affiliated authors.

PY - 2011/8/26

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ER -

Transformation of Nickelalactones to Methyl Acrylate: On the Way to a Catalytic Conversion of Carbon Dioxide

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