Towards syntheses and structures of heterometallic clusters containing tantalum-tetrachalcogenato building blocks

Dieter Fenske; Ibrahim Issac; Alexander Rothenberger

doi:10.1007/s10876-006-0097-2

Towards syntheses and structures of heterometallic clusters containing tantalum-tetrachalcogenato building blocks

Dieter Fenske^*, Ibrahim Issac, Alexander Rothenberger

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

1 Scopus citations

Abstract

An approach to tackle the synthesis of mixed-transition metal tantalum chalcogenide clusters is described. The synthesis of 1/ _∞[Li₃(TaSe₄)(MeCN)₄] _∞ (1) will in future allow the construction of Ta-Se-transition metal clusters. The potential of this route was demonstrated by the synthesis of the mixed-metal Ta-S-Fe and Ta-S-Cu complexes (Et₄N) ₃[Fe₂(SPh)₄(TaS₄)] (2) and [Cu ₃(TaS₄)(PPh₃)₄] (3).

Original language	English (US)
Pages (from-to)	19-26
Number of pages	8
Journal	Journal of Cluster Science
Volume	18
Issue number	1
DOIs	https://doi.org/10.1007/s10876-006-0097-2
State	Published - Mar 2007
Externally published	Yes

Keywords

Crystal structure
Heterometallic chalcogenides
Iron
Tantalum

ASJC Scopus subject areas

General Chemistry
Condensed Matter Physics
Biochemistry
General Materials Science

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10.1007/s10876-006-0097-2

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title = "Towards syntheses and structures of heterometallic clusters containing tantalum-tetrachalcogenato building blocks",

abstract = "An approach to tackle the synthesis of mixed-transition metal tantalum chalcogenide clusters is described. The synthesis of 1/ ∞[Li3(TaSe4)(MeCN)4] ∞ (1) will in future allow the construction of Ta-Se-transition metal clusters. The potential of this route was demonstrated by the synthesis of the mixed-metal Ta-S-Fe and Ta-S-Cu complexes (Et4N) 3[Fe2(SPh)4(TaS4)] (2) and [Cu 3(TaS4)(PPh3)4] (3).",

keywords = "Crystal structure, Heterometallic chalcogenides, Iron, Tantalum",

author = "Dieter Fenske and Ibrahim Issac and Alexander Rothenberger",

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doi = "10.1007/s10876-006-0097-2",

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T1 - Towards syntheses and structures of heterometallic clusters containing tantalum-tetrachalcogenato building blocks

AU - Fenske, Dieter

AU - Issac, Ibrahim

AU - Rothenberger, Alexander

PY - 2007/3

Y1 - 2007/3

N2 - An approach to tackle the synthesis of mixed-transition metal tantalum chalcogenide clusters is described. The synthesis of 1/ ∞[Li3(TaSe4)(MeCN)4] ∞ (1) will in future allow the construction of Ta-Se-transition metal clusters. The potential of this route was demonstrated by the synthesis of the mixed-metal Ta-S-Fe and Ta-S-Cu complexes (Et4N) 3[Fe2(SPh)4(TaS4)] (2) and [Cu 3(TaS4)(PPh3)4] (3).

AB - An approach to tackle the synthesis of mixed-transition metal tantalum chalcogenide clusters is described. The synthesis of 1/ ∞[Li3(TaSe4)(MeCN)4] ∞ (1) will in future allow the construction of Ta-Se-transition metal clusters. The potential of this route was demonstrated by the synthesis of the mixed-metal Ta-S-Fe and Ta-S-Cu complexes (Et4N) 3[Fe2(SPh)4(TaS4)] (2) and [Cu 3(TaS4)(PPh3)4] (3).

KW - Crystal structure

KW - Heterometallic chalcogenides

KW - Iron

KW - Tantalum

UR - http://www.scopus.com/inward/record.url?scp=34147188509&partnerID=8YFLogxK

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DO - 10.1007/s10876-006-0097-2

M3 - Article

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SN - 1040-7278

VL - 18

SP - 19

EP - 26

JO - Journal of Cluster Science

JF - Journal of Cluster Science

IS - 1

ER -

Towards syntheses and structures of heterometallic clusters containing tantalum-tetrachalcogenato building blocks

Abstract

Keywords

ASJC Scopus subject areas

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