Towards liquid fuels from biosyngas: Effect of zeolite structure in hierarchical-zeolite-supported cobalt catalysts

Sina Sartipi; Margje Alberts; Mark Meijerink; Tobias C. Keller; Javier Pérez-Ramírez; Jorge Gascon; Freek Kapteijn

doi:10.1002/cssc.201300339

Towards liquid fuels from biosyngas: Effect of zeolite structure in hierarchical-zeolite-supported cobalt catalysts

Sina Sartipi^*, Margje Alberts, Mark Meijerink, Tobias C. Keller, Javier Pérez-Ramírez, Jorge Gascon, Freek Kapteijn

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

62 Scopus citations

Abstract

Wax on, wax off: Bifunctional cobalt-based catalysts on zeolite supports are applied for the valorization of biosyngas through Fischer-Tropsch chemistry. By using these catalysts, waxes can be hydrocracked to shorter-chain hydrocarbons, increasing the selectivity towards the C₅-C ₁₁ (gasoline) fraction. The zeolite topology and the amount and strength of acid sites are key parameters to maximize the performance of these bifunctional catalysts, steering Fischer-Tropsch product selectivity towards liquid hydrocarbons.

Original language	English (US)
Pages (from-to)	1646-1650
Number of pages	5
Journal	CHEMSUSCHEM
Volume	6
Issue number	9
DOIs	https://doi.org/10.1002/cssc.201300339
State	Published - Sep 2013
Externally published	Yes

Keywords

Fischer-Tropsch
biosyngas
cobalt
heterogeneous catalysis
zeolites

ASJC Scopus subject areas

Environmental Chemistry
General Chemical Engineering
General Materials Science
General Energy

Access to Document

10.1002/cssc.201300339

Cite this

@article{b3f043bfeb05494b9e0d59af7c18b36e,

title = "Towards liquid fuels from biosyngas: Effect of zeolite structure in hierarchical-zeolite-supported cobalt catalysts",

abstract = "Wax on, wax off: Bifunctional cobalt-based catalysts on zeolite supports are applied for the valorization of biosyngas through Fischer-Tropsch chemistry. By using these catalysts, waxes can be hydrocracked to shorter-chain hydrocarbons, increasing the selectivity towards the C5-C 11 (gasoline) fraction. The zeolite topology and the amount and strength of acid sites are key parameters to maximize the performance of these bifunctional catalysts, steering Fischer-Tropsch product selectivity towards liquid hydrocarbons.",

keywords = "Fischer-Tropsch, biosyngas, cobalt, heterogeneous catalysis, zeolites",

author = "Sina Sartipi and Margje Alberts and Mark Meijerink and Keller, {Tobias C.} and Javier P{\'e}rez-Ram{\'i}rez and Jorge Gascon and Freek Kapteijn",

year = "2013",

month = sep,

doi = "10.1002/cssc.201300339",

language = "English (US)",

volume = "6",

pages = "1646--1650",

journal = "CHEMSUSCHEM",

issn = "1864-5631",

publisher = "Wiley",

number = "9",

}

TY - JOUR

T1 - Towards liquid fuels from biosyngas

T2 - Effect of zeolite structure in hierarchical-zeolite-supported cobalt catalysts

AU - Sartipi, Sina

AU - Alberts, Margje

AU - Meijerink, Mark

AU - Keller, Tobias C.

AU - Pérez-Ramírez, Javier

AU - Gascon, Jorge

AU - Kapteijn, Freek

PY - 2013/9

Y1 - 2013/9

N2 - Wax on, wax off: Bifunctional cobalt-based catalysts on zeolite supports are applied for the valorization of biosyngas through Fischer-Tropsch chemistry. By using these catalysts, waxes can be hydrocracked to shorter-chain hydrocarbons, increasing the selectivity towards the C5-C 11 (gasoline) fraction. The zeolite topology and the amount and strength of acid sites are key parameters to maximize the performance of these bifunctional catalysts, steering Fischer-Tropsch product selectivity towards liquid hydrocarbons.

AB - Wax on, wax off: Bifunctional cobalt-based catalysts on zeolite supports are applied for the valorization of biosyngas through Fischer-Tropsch chemistry. By using these catalysts, waxes can be hydrocracked to shorter-chain hydrocarbons, increasing the selectivity towards the C5-C 11 (gasoline) fraction. The zeolite topology and the amount and strength of acid sites are key parameters to maximize the performance of these bifunctional catalysts, steering Fischer-Tropsch product selectivity towards liquid hydrocarbons.

KW - Fischer-Tropsch

KW - biosyngas

KW - cobalt

KW - heterogeneous catalysis

KW - zeolites

UR - http://www.scopus.com/inward/record.url?scp=84884954995&partnerID=8YFLogxK

U2 - 10.1002/cssc.201300339

DO - 10.1002/cssc.201300339

M3 - Article

C2 - 23765635

AN - SCOPUS:84884954995

SN - 1864-5631

VL - 6

SP - 1646

EP - 1650

JO - CHEMSUSCHEM

JF - CHEMSUSCHEM

IS - 9

ER -

Towards liquid fuels from biosyngas: Effect of zeolite structure in hierarchical-zeolite-supported cobalt catalysts

Abstract

Keywords

ASJC Scopus subject areas

Access to Document

Other files and links

Fingerprint

Cite this