Toward New 2D Zirconium-Based Metal–Organic Frameworks: Synthesis, Structures, and Electronic Properties

Amandine Cadiau; Lilia S. Xie; Nikita Kolobov; Aleksander Shkurenko; Muhammad Qureshi; Mohammed Tchalala; Sarah S. Park; Anastasiya Bavykina; Mohamed Eddaoudi; Mircea Dincǎ; Christopher H. Hendon; Jorge Gascon

doi:10.1021/acs.chemmater.9b02462

Toward New 2D Zirconium-Based Metal–Organic Frameworks: Synthesis, Structures, and Electronic Properties

Amandine Cadiau, Lilia S. Xie, Nikita Kolobov, Aleksander Shkurenko, Muhammad Qureshi, Mohammed Tchalala, Sarah S. Park, Anastasiya Bavykina, Mohamed Eddaoudi, Mircea Dincǎ, Christopher H. Hendon, Jorge Gascon

Research output: Contribution to journal › Article › peer-review

40 Scopus citations

Abstract

Nowadays, zirconium metal-organic frameworks attract more attention because of their robustness and their easier predictability in terms of topology. Herein, we have been able to control synthetic parameters in order to construct two new 2D MOFs with the same sql topology. Both materials, ACM-10 and ACM-11, have been characterized by single-crystal X-ray diffraction, thermogravimetric analysis, and UV-vis spectroscopy. Their textural, electrochemical, and conductivity properties are presented along with the opportunities that these new topologically interesting scaffolds offer for the design of new structures.

Original language	English (US)
Pages (from-to)	97-104
Number of pages	8
Journal	Chemistry of Materials
Volume	32
Issue number	1
DOIs	https://doi.org/10.1021/acs.chemmater.9b02462
State	Published - Dec 18 2019

Bibliographical note

KAUST Repository Item: Exported on 2020-10-01
Acknowledgements: The work at MIT was supported by the U.S. Department of Energy, Office of Science, Office of Basic Energy Sciences (DESC0018235). L.S.X. and S.S.P. thank the National Science Foundation for support through the Graduate Research Fellowship Program (1122374). A.C. thanks the program P.I.A “MOPGA” (APPAT) for funding. This work used the Extreme Science and Engineering Discovery Environment (XSEDE), which is supported by the National Science Foundation grant number ACI-1548562, and the PICS machine, Coeus, which is supported by the NSF
(DMS1624776). The KAUST Office of Sponsored Research is gratefully acknowledged for funding through the 2019 CRG program.

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10.1021/acs.chemmater.9b02462

https://repository.kaust.edu.sa/bitstream/10754/661365/1/Accepted%5bCadiau%20et%20al_revised%5d.pdf

Cite this

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title = "Toward New 2D Zirconium-Based Metal–Organic Frameworks: Synthesis, Structures, and Electronic Properties",

abstract = "Nowadays, zirconium metal-organic frameworks attract more attention because of their robustness and their easier predictability in terms of topology. Herein, we have been able to control synthetic parameters in order to construct two new 2D MOFs with the same sql topology. Both materials, ACM-10 and ACM-11, have been characterized by single-crystal X-ray diffraction, thermogravimetric analysis, and UV-vis spectroscopy. Their textural, electrochemical, and conductivity properties are presented along with the opportunities that these new topologically interesting scaffolds offer for the design of new structures.",

author = "Amandine Cadiau and Xie, {Lilia S.} and Nikita Kolobov and Aleksander Shkurenko and Muhammad Qureshi and Mohammed Tchalala and Park, {Sarah S.} and Anastasiya Bavykina and Mohamed Eddaoudi and Mircea Dincǎ and Hendon, {Christopher H.} and Jorge Gascon",

note = "KAUST Repository Item: Exported on 2020-10-01 Acknowledgements: The work at MIT was supported by the U.S. Department of Energy, Office of Science, Office of Basic Energy Sciences (DESC0018235). L.S.X. and S.S.P. thank the National Science Foundation for support through the Graduate Research Fellowship Program (1122374). A.C. thanks the program P.I.A “MOPGA” (APPAT) for funding. This work used the Extreme Science and Engineering Discovery Environment (XSEDE), which is supported by the National Science Foundation grant number ACI-1548562, and the PICS machine, Coeus, which is supported by the NSF (DMS1624776). The KAUST Office of Sponsored Research is gratefully acknowledged for funding through the 2019 CRG program.",

year = "2019",

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doi = "10.1021/acs.chemmater.9b02462",

language = "English (US)",

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AU - Cadiau, Amandine

AU - Xie, Lilia S.

AU - Kolobov, Nikita

AU - Shkurenko, Aleksander

AU - Qureshi, Muhammad

AU - Tchalala, Mohammed

AU - Park, Sarah S.

AU - Bavykina, Anastasiya

AU - Eddaoudi, Mohamed

AU - Dincǎ, Mircea

AU - Hendon, Christopher H.

AU - Gascon, Jorge

N1 - KAUST Repository Item: Exported on 2020-10-01 Acknowledgements: The work at MIT was supported by the U.S. Department of Energy, Office of Science, Office of Basic Energy Sciences (DESC0018235). L.S.X. and S.S.P. thank the National Science Foundation for support through the Graduate Research Fellowship Program (1122374). A.C. thanks the program P.I.A “MOPGA” (APPAT) for funding. This work used the Extreme Science and Engineering Discovery Environment (XSEDE), which is supported by the National Science Foundation grant number ACI-1548562, and the PICS machine, Coeus, which is supported by the NSF (DMS1624776). The KAUST Office of Sponsored Research is gratefully acknowledged for funding through the 2019 CRG program.

PY - 2019/12/18

Y1 - 2019/12/18

N2 - Nowadays, zirconium metal-organic frameworks attract more attention because of their robustness and their easier predictability in terms of topology. Herein, we have been able to control synthetic parameters in order to construct two new 2D MOFs with the same sql topology. Both materials, ACM-10 and ACM-11, have been characterized by single-crystal X-ray diffraction, thermogravimetric analysis, and UV-vis spectroscopy. Their textural, electrochemical, and conductivity properties are presented along with the opportunities that these new topologically interesting scaffolds offer for the design of new structures.

AB - Nowadays, zirconium metal-organic frameworks attract more attention because of their robustness and their easier predictability in terms of topology. Herein, we have been able to control synthetic parameters in order to construct two new 2D MOFs with the same sql topology. Both materials, ACM-10 and ACM-11, have been characterized by single-crystal X-ray diffraction, thermogravimetric analysis, and UV-vis spectroscopy. Their textural, electrochemical, and conductivity properties are presented along with the opportunities that these new topologically interesting scaffolds offer for the design of new structures.

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Toward New 2D Zirconium-Based Metal–Organic Frameworks: Synthesis, Structures, and Electronic Properties

Abstract

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CCDC 1910185: Experimental Crystal Structure Determination : catena-[(mu-tetrathiafulvalene tetrabenzoato)-bis(mu-hydroxo)-bis(mu-oxido)-(mu-formato)-formato-(aqua)-tri-zirconium(iv) N,N-dimethylformamide solvate sesquihydrate]

CCDC 1910226: Experimental Crystal Structure Determination

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Toward New 2D Zirconium-Based Metal–Organic Frameworks: Synthesis, Structures, and Electronic Properties

Abstract

Bibliographical note

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CCDC 1910185: Experimental Crystal Structure Determination : catena-[(mu-tetrathiafulvalene tetrabenzoato)-bis(mu-hydroxo)-bis(mu-oxido)-(mu-formato)-formato-(aqua)-tri-zirconium(iv) N,N-dimethylformamide solvate sesquihydrate]

CCDC 1910226: Experimental Crystal Structure Determination

Cite this