Abstract
Controlling the electron transfer process at donor-
acceptor
interfaces is a research direction that has not yet
seen much
progress. Here, with careful control of the charge
localization on
the porphyrin macrocycle using
β
-Cyclodextrin as an external
cage, we are able to improve the electron injection
efficiency
from cationic porphyrin to graphene carboxylate by
120%
. The
detailed reaction mechanism is also discussed.
| Original language | English (US) |
|---|---|
| Pages (from-to) | 14513-14517 |
| Number of pages | 5 |
| Journal | Phys. Chem. Chem. Phys. |
| Volume | 17 |
| Issue number | 22 |
| DOIs | |
| State | Published - 2015 |