Thermally activated, single component epoxy systems

David A. Unruh; Stefan J. Pastine; Jessica C. Moreton; Jean Frechet

doi:10.1021/ma200673v

Thermally activated, single component epoxy systems

David A. Unruh, Stefan J. Pastine, Jessica C. Moreton, Jean Frechet

Research output: Contribution to journal › Article › peer-review

20 Scopus citations

Abstract

A single component epoxy system in which the resin and hardener components found in many two-component epoxies are combined onto the same molecule is described. The single molecule precursor to the epoxy resin contains both multiple epoxide moieties and a diamine held latent by thermally degradable carbamate linkages. These bis-carbamate "single molecule epoxies" have an essentially infinite shelf life and access a significant range in curing temperatures related to the structure of the carbamate linkages used. © 2011 American Chemical Society.

Original language	English (US)
Pages (from-to)	6318-6325
Number of pages	8
Journal	Macromolecules
Volume	44
Issue number	16
DOIs	https://doi.org/10.1021/ma200673v
State	Published - Aug 23 2011

Bibliographical note

KAUST Repository Item: Exported on 2020-10-01
Acknowledgements: Synthesis of the new materials and their characterization was supported by the Director, Office of Science, Office of Basic Energy Sciences, Division of Materials Sciences and Engineering of the U.S. Department of Energy under Contract No. DE-AC02-05CH11231; additional support by the Frechet Various Donors Gift Funds is also acknowledged.

ASJC Scopus subject areas

Materials Chemistry
Organic Chemistry
Polymers and Plastics
Inorganic Chemistry

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10.1021/ma200673v

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title = "Thermally activated, single component epoxy systems",

abstract = "A single component epoxy system in which the resin and hardener components found in many two-component epoxies are combined onto the same molecule is described. The single molecule precursor to the epoxy resin contains both multiple epoxide moieties and a diamine held latent by thermally degradable carbamate linkages. These bis-carbamate {"}single molecule epoxies{"} have an essentially infinite shelf life and access a significant range in curing temperatures related to the structure of the carbamate linkages used. {\textcopyright} 2011 American Chemical Society.",

author = "Unruh, {David A.} and Pastine, {Stefan J.} and Moreton, {Jessica C.} and Jean Frechet",

note = "KAUST Repository Item: Exported on 2020-10-01 Acknowledgements: Synthesis of the new materials and their characterization was supported by the Director, Office of Science, Office of Basic Energy Sciences, Division of Materials Sciences and Engineering of the U.S. Department of Energy under Contract No. DE-AC02-05CH11231; additional support by the Frechet Various Donors Gift Funds is also acknowledged.",

year = "2011",

month = aug,

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doi = "10.1021/ma200673v",

language = "English (US)",

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journal = "Macromolecules",

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T1 - Thermally activated, single component epoxy systems

AU - Unruh, David A.

AU - Pastine, Stefan J.

AU - Moreton, Jessica C.

AU - Frechet, Jean

N1 - KAUST Repository Item: Exported on 2020-10-01 Acknowledgements: Synthesis of the new materials and their characterization was supported by the Director, Office of Science, Office of Basic Energy Sciences, Division of Materials Sciences and Engineering of the U.S. Department of Energy under Contract No. DE-AC02-05CH11231; additional support by the Frechet Various Donors Gift Funds is also acknowledged.

PY - 2011/8/23

Y1 - 2011/8/23

N2 - A single component epoxy system in which the resin and hardener components found in many two-component epoxies are combined onto the same molecule is described. The single molecule precursor to the epoxy resin contains both multiple epoxide moieties and a diamine held latent by thermally degradable carbamate linkages. These bis-carbamate "single molecule epoxies" have an essentially infinite shelf life and access a significant range in curing temperatures related to the structure of the carbamate linkages used. © 2011 American Chemical Society.

AB - A single component epoxy system in which the resin and hardener components found in many two-component epoxies are combined onto the same molecule is described. The single molecule precursor to the epoxy resin contains both multiple epoxide moieties and a diamine held latent by thermally degradable carbamate linkages. These bis-carbamate "single molecule epoxies" have an essentially infinite shelf life and access a significant range in curing temperatures related to the structure of the carbamate linkages used. © 2011 American Chemical Society.

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UR - https://pubs.acs.org/doi/10.1021/ma200673v

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JO - Macromolecules

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ER -

Thermally activated, single component epoxy systems

Abstract

Bibliographical note

ASJC Scopus subject areas

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