Thermal evolution of nanosized LaFeO3 powders from a heteronuclear complex, La[Fe(CN)6]·nH2O

Yoshihiko Sadaoka; Hiromichi Aono; Enrico Traversa; Masatomi Sakamoto

doi:10.1016/S0925-8388(98)00602-1

Thermal evolution of nanosized LaFeO₃ powders from a heteronuclear complex, La[Fe(CN)₆]·nH₂O

Yoshihiko Sadaoka^*, Hiromichi Aono, Enrico Traversa, Masatomi Sakamoto

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

73 Scopus citations

Abstract

The thermal decomposition of a heteronuclear complex, La[Fe(CN)₆]·nH₂O, leads to the preparation of nanosized perovskite-type LaFeO₃ powders. The exothermic decomposition of the cyanide groups at 300°C, starting abruptly and the formation of LaFeO₃ without the presence of single oxides such as La₂O₃ and Fe₂O₃ were observed. The formation of LaFeO₃ from the complex involves the formation of carbonates and nitrates, which facilitate the formation of nanosized LaFeO₃ powders. Concomitantly formed carbonate and nitrate decomposed gradually and the specific surface area of nanosized LaFeO₃ increased up to 38 m² g^-1 at 350°C.

Original language	English (US)
Pages (from-to)	135-141
Number of pages	7
Journal	Journal of Alloys and Compounds
Volume	278
Issue number	1-2
DOIs	https://doi.org/10.1016/S0925-8388(98)00602-1
State	Published - Aug 1 1998
Externally published	Yes

Bibliographical note

Funding Information:
The present work was partly supported by a Grant-in-Aid for Scientific Research on Priority Areas “New Development of Rare Earth Complexes” No. 08220250 from the Ministry of Education, Science and Culture of Japan.

Keywords

Heteronuclear cyano complex
LaFeO
La[Fe(CN)]·nho
Perovskite-type oxide
Thermal decomposition

ASJC Scopus subject areas

Mechanics of Materials
Mechanical Engineering
Metals and Alloys
Materials Chemistry

Access to Document

10.1016/S0925-8388(98)00602-1

Cite this

@article{c500c116fb54428997593179e11462c0,

title = "Thermal evolution of nanosized LaFeO3 powders from a heteronuclear complex, La[Fe(CN)6]·nH2O",

abstract = "The thermal decomposition of a heteronuclear complex, La[Fe(CN)6]·nH2O, leads to the preparation of nanosized perovskite-type LaFeO3 powders. The exothermic decomposition of the cyanide groups at 300°C, starting abruptly and the formation of LaFeO3 without the presence of single oxides such as La2O3 and Fe2O3 were observed. The formation of LaFeO3 from the complex involves the formation of carbonates and nitrates, which facilitate the formation of nanosized LaFeO3 powders. Concomitantly formed carbonate and nitrate decomposed gradually and the specific surface area of nanosized LaFeO3 increased up to 38 m2 g-1 at 350°C.",

keywords = "Heteronuclear cyano complex, LaFeO, La[Fe(CN)]·nho, Perovskite-type oxide, Thermal decomposition",

author = "Yoshihiko Sadaoka and Hiromichi Aono and Enrico Traversa and Masatomi Sakamoto",

note = "Funding Information: The present work was partly supported by a Grant-in-Aid for Scientific Research on Priority Areas “New Development of Rare Earth Complexes” No. 08220250 from the Ministry of Education, Science and Culture of Japan.",

year = "1998",

month = aug,

day = "1",

doi = "10.1016/S0925-8388(98)00602-1",

language = "English (US)",

volume = "278",

pages = "135--141",

journal = "Journal of Alloys and Compounds",

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TY - JOUR

T1 - Thermal evolution of nanosized LaFeO3 powders from a heteronuclear complex, La[Fe(CN)6]·nH2O

AU - Sadaoka, Yoshihiko

AU - Aono, Hiromichi

AU - Traversa, Enrico

AU - Sakamoto, Masatomi

N1 - Funding Information: The present work was partly supported by a Grant-in-Aid for Scientific Research on Priority Areas “New Development of Rare Earth Complexes” No. 08220250 from the Ministry of Education, Science and Culture of Japan.

PY - 1998/8/1

Y1 - 1998/8/1

N2 - The thermal decomposition of a heteronuclear complex, La[Fe(CN)6]·nH2O, leads to the preparation of nanosized perovskite-type LaFeO3 powders. The exothermic decomposition of the cyanide groups at 300°C, starting abruptly and the formation of LaFeO3 without the presence of single oxides such as La2O3 and Fe2O3 were observed. The formation of LaFeO3 from the complex involves the formation of carbonates and nitrates, which facilitate the formation of nanosized LaFeO3 powders. Concomitantly formed carbonate and nitrate decomposed gradually and the specific surface area of nanosized LaFeO3 increased up to 38 m2 g-1 at 350°C.

AB - The thermal decomposition of a heteronuclear complex, La[Fe(CN)6]·nH2O, leads to the preparation of nanosized perovskite-type LaFeO3 powders. The exothermic decomposition of the cyanide groups at 300°C, starting abruptly and the formation of LaFeO3 without the presence of single oxides such as La2O3 and Fe2O3 were observed. The formation of LaFeO3 from the complex involves the formation of carbonates and nitrates, which facilitate the formation of nanosized LaFeO3 powders. Concomitantly formed carbonate and nitrate decomposed gradually and the specific surface area of nanosized LaFeO3 increased up to 38 m2 g-1 at 350°C.

KW - Heteronuclear cyano complex

KW - LaFeO

KW - La[Fe(CN)]·nho

KW - Perovskite-type oxide

KW - Thermal decomposition

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U2 - 10.1016/S0925-8388(98)00602-1

DO - 10.1016/S0925-8388(98)00602-1

M3 - Article

AN - SCOPUS:0032137732

SN - 0925-8388

VL - 278

SP - 135

EP - 141

JO - Journal of Alloys and Compounds

JF - Journal of Alloys and Compounds

IS - 1-2

ER -