The unique rht-MOF platform, ideal for pinpointing the functionalization and CO 2 adsorption relationship

Ryan Luebke; Jarrod F. Eubank; Amy Cairns; Youssef Belmabkhout; Łukasz Wojtas; Mohamed Eddaoudi

doi:10.1039/c1cc15962c

The unique rht-MOF platform, ideal for pinpointing the functionalization and CO 2 adsorption relationship

Ryan Luebke, Jarrod F. Eubank, Amy Cairns, Youssef Belmabkhout, Łukasz Wojtas, Mohamed Eddaoudi

Research output: Contribution to journal › Article › peer-review

159 Scopus citations

Abstract

The uniqueness of the rht-MOF platform, based on the singular (3,24)-connected net, allows for the facile design and synthesis of functionalized materials for desired applications. Here we designed a nitrogen-rich trefoil hexacarboxylate (trigonal tri-isophthalate) ligand, which serves to act as the trigonal molecular building block while concurrently coding the formation of the targeted truncated cuboctahedral supermolecular building block (in situ), and enhancing the CO 2 uptake in the resultant rht-MOF. © 2012 The Royal Society of Chemistry.

Original language	English (US)
Pages (from-to)	1455-1457
Number of pages	3
Journal	Chem. Commun.
Volume	48
Issue number	10
DOIs	https://doi.org/10.1039/c1cc15962c
State	Published - 2012

Bibliographical note

KAUST Repository Item: Exported on 2020-10-01
Acknowledgements: The authors gratefully acknowledge KAUST funds.

ASJC Scopus subject areas

Materials Chemistry
Surfaces, Coatings and Films
Metals and Alloys
Ceramics and Composites
General Chemistry
Catalysis
Electronic, Optical and Magnetic Materials

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10.1039/c1cc15962c

Cite this

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title = "The unique rht-MOF platform, ideal for pinpointing the functionalization and CO 2 adsorption relationship",

abstract = "The uniqueness of the rht-MOF platform, based on the singular (3,24)-connected net, allows for the facile design and synthesis of functionalized materials for desired applications. Here we designed a nitrogen-rich trefoil hexacarboxylate (trigonal tri-isophthalate) ligand, which serves to act as the trigonal molecular building block while concurrently coding the formation of the targeted truncated cuboctahedral supermolecular building block (in situ), and enhancing the CO 2 uptake in the resultant rht-MOF. {\textcopyright} 2012 The Royal Society of Chemistry.",

author = "Ryan Luebke and Eubank, {Jarrod F.} and Amy Cairns and Youssef Belmabkhout and {\L}ukasz Wojtas and Mohamed Eddaoudi",

note = "KAUST Repository Item: Exported on 2020-10-01 Acknowledgements: The authors gratefully acknowledge KAUST funds.",

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language = "English (US)",

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T1 - The unique rht-MOF platform, ideal for pinpointing the functionalization and CO 2 adsorption relationship

AU - Luebke, Ryan

AU - Eubank, Jarrod F.

AU - Cairns, Amy

AU - Belmabkhout, Youssef

AU - Wojtas, Łukasz

AU - Eddaoudi, Mohamed

N1 - KAUST Repository Item: Exported on 2020-10-01 Acknowledgements: The authors gratefully acknowledge KAUST funds.

PY - 2012

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AB - The uniqueness of the rht-MOF platform, based on the singular (3,24)-connected net, allows for the facile design and synthesis of functionalized materials for desired applications. Here we designed a nitrogen-rich trefoil hexacarboxylate (trigonal tri-isophthalate) ligand, which serves to act as the trigonal molecular building block while concurrently coding the formation of the targeted truncated cuboctahedral supermolecular building block (in situ), and enhancing the CO 2 uptake in the resultant rht-MOF. © 2012 The Royal Society of Chemistry.

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The unique rht-MOF platform, ideal for pinpointing the functionalization and CO 2 adsorption relationship

Abstract

Bibliographical note

ASJC Scopus subject areas

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CCDC 846266: Experimental Crystal Structure Determination : catena-(bis(mu~12~-2,4,6-tris(3,5-Dicarboxylatophenylamino)-1,3,5-triazine)-hexa-aqua-hexa-copper unknown solvate)

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The unique rht-MOF platform, ideal for pinpointing the functionalization and CO 2 adsorption relationship

Abstract

Bibliographical note

ASJC Scopus subject areas

Access to Document

Other files and links

Fingerprint

Datasets

CCDC 846266: Experimental Crystal Structure Determination : catena-(bis(mu~12~-2,4,6-tris(3,5-Dicarboxylatophenylamino)-1,3,5-triazine)-hexa-aqua-hexa-copper unknown solvate)

Cite this