The quest for modular nanocages: Tbo -MOF as an archetype for mutual substitution, functionalization, and expansion of quadrangular pillar building blocks

Jarrod F. Eubank; Hasnaa Mouttaki; Amy Cairns; Youssef Belmabkhout; Łukasz Wojtas; Ryan Luebke; Mohamed Al Kordi; Mohamed Eddaoudi

doi:10.1021/ja205658j

The quest for modular nanocages: Tbo -MOF as an archetype for mutual substitution, functionalization, and expansion of quadrangular pillar building blocks

Jarrod F. Eubank, Hasnaa Mouttaki, Amy Cairns, Youssef Belmabkhout, Łukasz Wojtas, Ryan Luebke, Mohamed Al Kordi, Mohamed Eddaoudi

Research output: Contribution to journal › Article › peer-review

109 Scopus citations

Abstract

A new blueprint network for the design and synthesis of porous, functional 3D metal-organic frameworks (MOFs) has been identified, namely, the tbo net. Accordingly, tbo-MOFs based on this unique (3,4)-connected net can be exclusively constructed utilizing a combination of well-known and readily targeted [M(R-BDC)]n MOF layers [i.e., supermolecular building layers (SBLs)] based on the edge-transitive 4,4 square lattice (sql) (i.e., 2D four-building units) and a novel pillaring strategy based on four proximal isophthalate ligands from neighboring SBL membered rings (i.e., two pairs from each layer) covalently cross-linked through an organic quadrangular core (e.g., tetrasubstituted benzene). Our strategy permits the rational design and synthesis of isoreticular structures, functionalized and/or expanded, that possess extra-large nanocapsule-like cages, high porosity, and potential for gas separation and storage, among others. Thus, tbo-MOF serves as an archetypal tunable, isoreticular MOF platform for targeting desired applications. © 2011 American Chemical Society.

Original language	English (US)
Pages (from-to)	14204-14207
Number of pages	4
Journal	Journal of the American Chemical Society
Volume	133
Issue number	36
DOIs	https://doi.org/10.1021/ja205658j
State	Published - Sep 14 2011

Bibliographical note

KAUST Repository Item: Exported on 2020-10-01
Acknowledgements: This work is dedicated to the memory of I. Dale Shellhammer (1924-2010). The authors gratefully acknowledge funds from NSF (DMR 0548117) and KAUST as well as beamline 151D-C of ChemMatCARS Sector 15 at APS, ANL (DOE DE-AC02-06CH11357, NSF CHE-0822838).

ASJC Scopus subject areas

Biochemistry
Colloid and Surface Chemistry
General Chemistry
Catalysis

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10.1021/ja205658j

Cite this

Eubank, J. F., Mouttaki, H., Cairns, A., Belmabkhout, Y., Wojtas, Ł., Luebke, R., Al Kordi, M., & Eddaoudi, M. (2011). The quest for modular nanocages: Tbo -MOF as an archetype for mutual substitution, functionalization, and expansion of quadrangular pillar building blocks. Journal of the American Chemical Society, 133(36), 14204-14207. https://doi.org/10.1021/ja205658j

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title = "The quest for modular nanocages: Tbo -MOF as an archetype for mutual substitution, functionalization, and expansion of quadrangular pillar building blocks",

abstract = "A new blueprint network for the design and synthesis of porous, functional 3D metal-organic frameworks (MOFs) has been identified, namely, the tbo net. Accordingly, tbo-MOFs based on this unique (3,4)-connected net can be exclusively constructed utilizing a combination of well-known and readily targeted [M(R-BDC)]n MOF layers [i.e., supermolecular building layers (SBLs)] based on the edge-transitive 4,4 square lattice (sql) (i.e., 2D four-building units) and a novel pillaring strategy based on four proximal isophthalate ligands from neighboring SBL membered rings (i.e., two pairs from each layer) covalently cross-linked through an organic quadrangular core (e.g., tetrasubstituted benzene). Our strategy permits the rational design and synthesis of isoreticular structures, functionalized and/or expanded, that possess extra-large nanocapsule-like cages, high porosity, and potential for gas separation and storage, among others. Thus, tbo-MOF serves as an archetypal tunable, isoreticular MOF platform for targeting desired applications. {\textcopyright} 2011 American Chemical Society.",

author = "Eubank, {Jarrod F.} and Hasnaa Mouttaki and Amy Cairns and Youssef Belmabkhout and {\L}ukasz Wojtas and Ryan Luebke and {Al Kordi}, Mohamed and Mohamed Eddaoudi",

note = "KAUST Repository Item: Exported on 2020-10-01 Acknowledgements: This work is dedicated to the memory of I. Dale Shellhammer (1924-2010). The authors gratefully acknowledge funds from NSF (DMR 0548117) and KAUST as well as beamline 151D-C of ChemMatCARS Sector 15 at APS, ANL (DOE DE-AC02-06CH11357, NSF CHE-0822838).",

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Eubank, JF, Mouttaki, H, Cairns, A, Belmabkhout, Y, Wojtas, Ł, Luebke, R, Al Kordi, M & Eddaoudi, M 2011, 'The quest for modular nanocages: Tbo -MOF as an archetype for mutual substitution, functionalization, and expansion of quadrangular pillar building blocks', Journal of the American Chemical Society, vol. 133, no. 36, pp. 14204-14207. https://doi.org/10.1021/ja205658j

The quest for modular nanocages: Tbo -MOF as an archetype for mutual substitution, functionalization, and expansion of quadrangular pillar building blocks. / Eubank, Jarrod F.; Mouttaki, Hasnaa; Cairns, Amy et al.
In: Journal of the American Chemical Society, Vol. 133, No. 36, 14.09.2011, p. 14204-14207.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - The quest for modular nanocages: Tbo -MOF as an archetype for mutual substitution, functionalization, and expansion of quadrangular pillar building blocks

AU - Eubank, Jarrod F.

AU - Mouttaki, Hasnaa

AU - Cairns, Amy

AU - Belmabkhout, Youssef

AU - Wojtas, Łukasz

AU - Luebke, Ryan

AU - Al Kordi, Mohamed

AU - Eddaoudi, Mohamed

N1 - KAUST Repository Item: Exported on 2020-10-01 Acknowledgements: This work is dedicated to the memory of I. Dale Shellhammer (1924-2010). The authors gratefully acknowledge funds from NSF (DMR 0548117) and KAUST as well as beamline 151D-C of ChemMatCARS Sector 15 at APS, ANL (DOE DE-AC02-06CH11357, NSF CHE-0822838).

PY - 2011/9/14

Y1 - 2011/9/14

N2 - A new blueprint network for the design and synthesis of porous, functional 3D metal-organic frameworks (MOFs) has been identified, namely, the tbo net. Accordingly, tbo-MOFs based on this unique (3,4)-connected net can be exclusively constructed utilizing a combination of well-known and readily targeted [M(R-BDC)]n MOF layers [i.e., supermolecular building layers (SBLs)] based on the edge-transitive 4,4 square lattice (sql) (i.e., 2D four-building units) and a novel pillaring strategy based on four proximal isophthalate ligands from neighboring SBL membered rings (i.e., two pairs from each layer) covalently cross-linked through an organic quadrangular core (e.g., tetrasubstituted benzene). Our strategy permits the rational design and synthesis of isoreticular structures, functionalized and/or expanded, that possess extra-large nanocapsule-like cages, high porosity, and potential for gas separation and storage, among others. Thus, tbo-MOF serves as an archetypal tunable, isoreticular MOF platform for targeting desired applications. © 2011 American Chemical Society.

AB - A new blueprint network for the design and synthesis of porous, functional 3D metal-organic frameworks (MOFs) has been identified, namely, the tbo net. Accordingly, tbo-MOFs based on this unique (3,4)-connected net can be exclusively constructed utilizing a combination of well-known and readily targeted [M(R-BDC)]n MOF layers [i.e., supermolecular building layers (SBLs)] based on the edge-transitive 4,4 square lattice (sql) (i.e., 2D four-building units) and a novel pillaring strategy based on four proximal isophthalate ligands from neighboring SBL membered rings (i.e., two pairs from each layer) covalently cross-linked through an organic quadrangular core (e.g., tetrasubstituted benzene). Our strategy permits the rational design and synthesis of isoreticular structures, functionalized and/or expanded, that possess extra-large nanocapsule-like cages, high porosity, and potential for gas separation and storage, among others. Thus, tbo-MOF serves as an archetypal tunable, isoreticular MOF platform for targeting desired applications. © 2011 American Chemical Society.

UR - http://hdl.handle.net/10754/561875

UR - https://pubs.acs.org/doi/10.1021/ja205658j

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JF - Journal of the American Chemical Society

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The quest for modular nanocages: Tbo -MOF as an archetype for mutual substitution, functionalization, and expansion of quadrangular pillar building blocks

Abstract

Bibliographical note

ASJC Scopus subject areas

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CCDC 855129: Experimental Crystal Structure Determination : catena-[(mu16-5,5',5'',5''',5'''',5'''''-(1,2,3,4,5,6-Benzenehexamethoxy)hexaisophthalato)-tetraaqua-tetra-copper tetrahydrate]

CCDC 855128: Experimental Crystal Structure Determination : catena-[(mu~16~-5,5',5'',5'''-(1,2,4,5-Benzenetetramethoxy)tetraisophthalato)-tetraaqua-tetra-copper]

CCDC 855130: Experimental Crystal Structure Determination : catena-[(mu~16~-5,5',5'',5'''-(1,2,4,5-Benzenetetrakis(4-methoxyphenylazo)tetraisophthalato))-triaqua-dimethylformamide-tetra-copper]

Cite this

The quest for modular nanocages: Tbo -MOF as an archetype for mutual substitution, functionalization, and expansion of quadrangular pillar building blocks

Abstract

Bibliographical note

ASJC Scopus subject areas

Access to Document

Other files and links

Fingerprint

Datasets

CCDC 855129: Experimental Crystal Structure Determination : catena-[(mu16-5,5',5'',5''',5'''',5'''''-(1,2,3,4,5,6-Benzenehexamethoxy)hexaisophthalato)-tetraaqua-tetra-copper tetrahydrate]

CCDC 855128: Experimental Crystal Structure Determination : catena-[(mu~16~-5,5',5'',5'''-(1,2,4,5-Benzenetetramethoxy)tetraisophthalato)-tetraaqua-tetra-copper]

CCDC 855130: Experimental Crystal Structure Determination : catena-[(mu~16~-5,5',5'',5'''-(1,2,4,5-Benzenetetrakis(4-methoxyphenylazo)tetraisophthalato))-triaqua-dimethylformamide-tetra-copper]

Cite this