The generation of hydroxide and methoxide ions by photo-irradiation: Use of aromatization to stabilize ionic photo-products from acridine derivatives

Aaron J. Ackmann; Jean Frechet

doi:10.1039/CC9960000605

The generation of hydroxide and methoxide ions by photo-irradiation: Use of aromatization to stabilize ionic photo-products from acridine derivatives

Aaron J. Ackmann, Jean Frechet^*

^*Corresponding author for this work

Physical Sciences and Engineering

Research output: Contribution to journal › Article › peer-review

21 Scopus citations

Abstract

The photolysis of 9-hydroxy-10-methyl-9-phenyl-9,10-dihydroacridine 1 or its 9-methoxy derivative 2 occurs with heterolytic cleavage of a C-O bond and formation of the desired strong base together with a cation that stabilizes itself through aromatization.

Original language	English (US)
Pages (from-to)	605-606
Number of pages	2
Journal	Chemical Communications
Issue number	5
DOIs	https://doi.org/10.1039/CC9960000605
State	Published - Jan 1 1996

ASJC Scopus subject areas

Catalysis
Electronic, Optical and Magnetic Materials
Ceramics and Composites
Chemistry(all)
Surfaces, Coatings and Films
Metals and Alloys
Materials Chemistry

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10.1039/CC9960000605

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title = "The generation of hydroxide and methoxide ions by photo-irradiation: Use of aromatization to stabilize ionic photo-products from acridine derivatives",

abstract = "The photolysis of 9-hydroxy-10-methyl-9-phenyl-9,10-dihydroacridine 1 or its 9-methoxy derivative 2 occurs with heterolytic cleavage of a C-O bond and formation of the desired strong base together with a cation that stabilizes itself through aromatization.",

author = "Ackmann, {Aaron J.} and Jean Frechet",

year = "1996",

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doi = "10.1039/CC9960000605",

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AB - The photolysis of 9-hydroxy-10-methyl-9-phenyl-9,10-dihydroacridine 1 or its 9-methoxy derivative 2 occurs with heterolytic cleavage of a C-O bond and formation of the desired strong base together with a cation that stabilizes itself through aromatization.

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JF - Chemical Communications

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The generation of hydroxide and methoxide ions by photo-irradiation: Use of aromatization to stabilize ionic photo-products from acridine derivatives

Abstract

ASJC Scopus subject areas

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