Organic electrochemical transistors are a promising technology for bioelectronic devices, with applications in neuromorphic computing and healthcare. The active component enabling an organic electrochemical transistor is the organic mixed ionic-electronic conductor whose optimization is critical for realizing high-performing devices. In this study, the influence of purity and molecular weight is examined for a p-type polythiophene and an n-type naphthalene diimide-based polymer in improving the performance and safety of organic electrochemical transistors. Our preparative GPC purification reduced the Pd content in the polymers and improved their organic electrochemical transistor mobility by ~60% and 80% for the p- and n-type materials, respectively. These findings demonstrate the paramount importance of removing residual Pd, which was concluded to be more critical than optimization of a polymer’s molecular weight, to improve organic electrochemical transistor performance and that there is readily available improvement in performance and stability of many of the reported organic mixed ionic-electronic conductors.
|Original language||English (US)|
|State||Published - Dec 27 2022|
Bibliographical noteKAUST Repository Item: Exported on 2022-12-29
Acknowledged KAUST grant number(s): OSR-2018-CARF/CCF-3079, OSR-2019-CRG8-4095, CRG10
Acknowledgements: S.G., A.M., C.M.A., I.M., D.M., and J.R. acknowledge financial support from KAUST Office of Sponsored Research CRG10. S.G., A.M., C.M.A., and I.M. acknowledge funding by EU Horizon2020 grant agreement no. 952911, BOOSTER, grant agreement no. 862474, RoLA-FLEX, and grant agreement no. 101007084 CITYSOLAR, as well as EPSRC Projects EP/T026219/1 and EP/W017091/1. A CC-BY licence is applied to the AAM arising from this submission, in accordance with the grant’s open access conditions. J.R. and E.A.S. gratefully acknowledges funding support from Sloan under award no. FG-2019-12046. B.D.P. and J.R. acknowledge support from the National Science Foundation grant no. NSF DMR-1751308. D.M. and E.A.S. utilized the Keck-II facility of Northwestern University’s NUANCE Center and the Northwestern University Micro/Nano Fabrication Facility (NUFAB), which are both partially supported by Soft and Hybrid Nanotechnology Experimental (SHyNE) Resource (NSF ECCS-1542205), the Materials Research Science and Engineering Center (NSF DMR-1720139), the State of Illinois, and Northwestern University. Additionally, the Keck-II facility is partially supported by the International Institute for Nanotechnology (IIN); the Keck Foundation; and the State of Illinois, through the IIN. D.M. and B.D.P. used resources of the Advanced Photon Source, a U.S. Department of Energy (DOE) Office of Science User Facility operated for the DOE Office of Science by Argonne National Laboratory under Contract No. DE-AC02-06CH11357. J.T. acknowledges financial support from a US Office for Naval Research, ONR YIP (N00014-20-1-2777). Special thanks to J. Strzalka for beam line support. N.B., G.R., and O.B. thank the European Research Council (ERC) for supporting this research by a Starting Grant (No. 714586, OSIRIS) and acknowledge NCCR-MUST, a research instrument of the Swiss National Science Foundation, as well as the University of Bern. M.I.N. and T.D.A. would like to acknowledge the King Abdullah University of Science and Technology (KAUST) Office of Sponsored Research (OSR) under Award No.: OSR-2018-CARF/CCF-3079, and OSR-2019-CRG8-4095 for the funding.
ASJC Scopus subject areas
- Biochemistry, Genetics and Molecular Biology(all)
- Physics and Astronomy(all)