Tetrakis(4-tert-butylphenyl) substituted and fused quinoidal porphyrins

Wangdong Zeng; Byungsun Lee; Youngmo Sung; Kuo-Wei Huang; Yuan Li; Dongho Kim; Jishan Wu

doi:10.1039/c2cc33728b

Tetrakis(4-tert-butylphenyl) substituted and fused quinoidal porphyrins

Wangdong Zeng, Byungsun Lee, Youngmo Sung, Kuo-Wei Huang, Yuan Li, Dongho Kim, Jishan Wu

Research output: Contribution to journal › Article › peer-review

34 Scopus citations

Abstract

4-tert-Butylphenyl-substituted and fused quinoidal porphyrins 1 and 2 are prepared for the first time. They show (1) intense one-photon absorption in the far-red/near-infrared region, (2) enhanced two-photon absorption compared with aromatic porphyrin monomers, and (3) amphoteric redox behavior. Their geometry and electronic structure are studied by DFT calculations. This journal is © 2012 The Royal Society of Chemistry.

Original language	English (US)
Pages (from-to)	7684
Journal	Chemical Communications
Volume	48
Issue number	62
DOIs	https://doi.org/10.1039/c2cc33728b
State	Published - 2012

Bibliographical note

KAUST Repository Item: Exported on 2020-10-01
Acknowledgements: J. W. acknowledges the financial support from the BMRC-NMRC grant (no. 10/1/21/19/642), MOE Tier 2 grant (MOE2011-T2-2-130) and IMRE Core Funding (IMRE/10-1P0509). The work at Yonsei Univ. was supported by WCU (World Class University) programs (R32-2010-10217-0) and an AFSOR/APARD grant (no. FA2386-09-1-4092). K.-W. H. acknowledges the financial support from KAUST.

ASJC Scopus subject areas

Materials Chemistry
Surfaces, Coatings and Films
Metals and Alloys
Ceramics and Composites
General Chemistry
Catalysis
Electronic, Optical and Magnetic Materials

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10.1039/c2cc33728b

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title = "Tetrakis(4-tert-butylphenyl) substituted and fused quinoidal porphyrins",

abstract = "4-tert-Butylphenyl-substituted and fused quinoidal porphyrins 1 and 2 are prepared for the first time. They show (1) intense one-photon absorption in the far-red/near-infrared region, (2) enhanced two-photon absorption compared with aromatic porphyrin monomers, and (3) amphoteric redox behavior. Their geometry and electronic structure are studied by DFT calculations. This journal is {\textcopyright} 2012 The Royal Society of Chemistry.",

author = "Wangdong Zeng and Byungsun Lee and Youngmo Sung and Kuo-Wei Huang and Yuan Li and Dongho Kim and Jishan Wu",

note = "KAUST Repository Item: Exported on 2020-10-01 Acknowledgements: J. W. acknowledges the financial support from the BMRC-NMRC grant (no. 10/1/21/19/642), MOE Tier 2 grant (MOE2011-T2-2-130) and IMRE Core Funding (IMRE/10-1P0509). The work at Yonsei Univ. was supported by WCU (World Class University) programs (R32-2010-10217-0) and an AFSOR/APARD grant (no. FA2386-09-1-4092). K.-W. H. acknowledges the financial support from KAUST.",

year = "2012",

doi = "10.1039/c2cc33728b",

language = "English (US)",

volume = "48",

pages = "7684",

journal = "Chemical Communications",

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publisher = "ROYAL SOC CHEMISTRY",

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TY - JOUR

T1 - Tetrakis(4-tert-butylphenyl) substituted and fused quinoidal porphyrins

AU - Zeng, Wangdong

AU - Lee, Byungsun

AU - Sung, Youngmo

AU - Huang, Kuo-Wei

AU - Li, Yuan

AU - Kim, Dongho

AU - Wu, Jishan

N1 - KAUST Repository Item: Exported on 2020-10-01 Acknowledgements: J. W. acknowledges the financial support from the BMRC-NMRC grant (no. 10/1/21/19/642), MOE Tier 2 grant (MOE2011-T2-2-130) and IMRE Core Funding (IMRE/10-1P0509). The work at Yonsei Univ. was supported by WCU (World Class University) programs (R32-2010-10217-0) and an AFSOR/APARD grant (no. FA2386-09-1-4092). K.-W. H. acknowledges the financial support from KAUST.

PY - 2012

Y1 - 2012

N2 - 4-tert-Butylphenyl-substituted and fused quinoidal porphyrins 1 and 2 are prepared for the first time. They show (1) intense one-photon absorption in the far-red/near-infrared region, (2) enhanced two-photon absorption compared with aromatic porphyrin monomers, and (3) amphoteric redox behavior. Their geometry and electronic structure are studied by DFT calculations. This journal is © 2012 The Royal Society of Chemistry.

AB - 4-tert-Butylphenyl-substituted and fused quinoidal porphyrins 1 and 2 are prepared for the first time. They show (1) intense one-photon absorption in the far-red/near-infrared region, (2) enhanced two-photon absorption compared with aromatic porphyrin monomers, and (3) amphoteric redox behavior. Their geometry and electronic structure are studied by DFT calculations. This journal is © 2012 The Royal Society of Chemistry.

UR - http://hdl.handle.net/10754/562008

UR - http://xlink.rsc.org/?DOI=c2cc33728b

UR - http://www.scopus.com/inward/record.url?scp=84863936000&partnerID=8YFLogxK

U2 - 10.1039/c2cc33728b

DO - 10.1039/c2cc33728b

M3 - Article

SN - 1359-7345

VL - 48

SP - 7684

JO - Chemical Communications

JF - Chemical Communications

IS - 62

ER -

Tetrakis(4-tert-butylphenyl) substituted and fused quinoidal porphyrins

Abstract

Bibliographical note

ASJC Scopus subject areas

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