Tetracrystalline Tetrablock Quarterpolymers: Four Different Crystallites under the Same Roof.

Nikos Hadjichristidis; Viko Ladelta; Georgios Zapsas; Edy Abou-Hamad; Yves Gnanou

doi:10.1002/anie.201908688

Tetracrystalline Tetrablock Quarterpolymers: Four Different Crystallites under the Same Roof.

Nikos Hadjichristidis, Viko Ladelta, Georgios Zapsas, Edy Abou-Hamad, Yves Gnanou

Research output: Contribution to journal › Article › peer-review

19 Scopus citations

Abstract

Multicrystalline block copolymers having three or more crystalline segments are essential materials for the advancement of physics in the field of crystallinity. Due to the challenging synthesis of multicrystalline polymers only a limited number of tricrystalline terpolymers are reported until now. We report, for the first time, the synthesis of poly(ethylene)-b-poly(ethylene oxide)-b-poly(ε-caprolactone)-b-poly(L-Lactide) (PE-b-PEO-b-PCL-b-PLLA) tetracrystalline tetrablock quarterpolymer, by combining polyhomologation, ring-opening polymerization, and an organic/metal “catalyst switch” strategy.1H NMR spectroscopy and gel-permeation chromatography confirm the formation of the tetrablock quarterpolymer, while differential scanning calorimetry, X-ray diffraction, and wide-line separation solid-state NMR spectroscopy reveal the existence of four different crystalline domains.

Original language	English (US)
Pages (from-to)	16267-16274
Number of pages	8
Journal	Angewandte Chemie (International ed. in English)
Volume	58
Issue number	45
DOIs	https://doi.org/10.1002/anie.201908688
State	Published - Aug 26 2019

Bibliographical note

KAUST Repository Item: Exported on 2020-10-01
Acknowledgements: The research reported in this publication was supported by King Abdullah University of Science and Technology (KAUST).The authors thank Professor Alejandro J. Müller (University of the Basque Country) for the fruitful discussion on the crystallizationof multicrystalline multiblock copolymers

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https://repository.kaust.edu.sa/bitstream/10754/656668/1/Hadjichristidis_et_al-2019-Angewandte_Chemie_International_Edition.pdf

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title = "Tetracrystalline Tetrablock Quarterpolymers: Four Different Crystallites under the Same Roof.",

abstract = "Multicrystalline block copolymers having three or more crystalline segments are essential materials for the advancement of physics in the field of crystallinity. Due to the challenging synthesis of multicrystalline polymers only a limited number of tricrystalline terpolymers are reported until now. We report, for the first time, the synthesis of poly(ethylene)-b-poly(ethylene oxide)-b-poly(ε-caprolactone)-b-poly(L-Lactide) (PE-b-PEO-b-PCL-b-PLLA) tetracrystalline tetrablock quarterpolymer, by combining polyhomologation, ring-opening polymerization, and an organic/metal “catalyst switch” strategy.1H NMR spectroscopy and gel-permeation chromatography confirm the formation of the tetrablock quarterpolymer, while differential scanning calorimetry, X-ray diffraction, and wide-line separation solid-state NMR spectroscopy reveal the existence of four different crystalline domains.",

author = "Nikos Hadjichristidis and Viko Ladelta and Georgios Zapsas and Edy Abou-Hamad and Yves Gnanou",

note = "KAUST Repository Item: Exported on 2020-10-01 Acknowledgements: The research reported in this publication was supported by King Abdullah University of Science and Technology (KAUST).The authors thank Professor Alejandro J. M{\"u}ller (University of the Basque Country) for the fruitful discussion on the crystallizationof multicrystalline multiblock copolymers",

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AU - Ladelta, Viko

AU - Zapsas, Georgios

AU - Abou-Hamad, Edy

AU - Gnanou, Yves

N1 - KAUST Repository Item: Exported on 2020-10-01 Acknowledgements: The research reported in this publication was supported by King Abdullah University of Science and Technology (KAUST).The authors thank Professor Alejandro J. Müller (University of the Basque Country) for the fruitful discussion on the crystallizationof multicrystalline multiblock copolymers

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N2 - Multicrystalline block copolymers having three or more crystalline segments are essential materials for the advancement of physics in the field of crystallinity. Due to the challenging synthesis of multicrystalline polymers only a limited number of tricrystalline terpolymers are reported until now. We report, for the first time, the synthesis of poly(ethylene)-b-poly(ethylene oxide)-b-poly(ε-caprolactone)-b-poly(L-Lactide) (PE-b-PEO-b-PCL-b-PLLA) tetracrystalline tetrablock quarterpolymer, by combining polyhomologation, ring-opening polymerization, and an organic/metal “catalyst switch” strategy.1H NMR spectroscopy and gel-permeation chromatography confirm the formation of the tetrablock quarterpolymer, while differential scanning calorimetry, X-ray diffraction, and wide-line separation solid-state NMR spectroscopy reveal the existence of four different crystalline domains.

AB - Multicrystalline block copolymers having three or more crystalline segments are essential materials for the advancement of physics in the field of crystallinity. Due to the challenging synthesis of multicrystalline polymers only a limited number of tricrystalline terpolymers are reported until now. We report, for the first time, the synthesis of poly(ethylene)-b-poly(ethylene oxide)-b-poly(ε-caprolactone)-b-poly(L-Lactide) (PE-b-PEO-b-PCL-b-PLLA) tetracrystalline tetrablock quarterpolymer, by combining polyhomologation, ring-opening polymerization, and an organic/metal “catalyst switch” strategy.1H NMR spectroscopy and gel-permeation chromatography confirm the formation of the tetrablock quarterpolymer, while differential scanning calorimetry, X-ray diffraction, and wide-line separation solid-state NMR spectroscopy reveal the existence of four different crystalline domains.

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Tetracrystalline Tetrablock Quarterpolymers: Four Different Crystallites under the Same Roof.

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