Ternary and tetrahedral symmetry in hybrid fluorides, fluoride carbonates and carbonates

Karim Adil; Amor Ben Ali; Gilles Dujardin; Robert Dhal; Marc Leblanc; Vincent Maisonneuve

doi:10.1016/j.jfluchem.2004.09.019

Ternary and tetrahedral symmetry in hybrid fluorides, fluoride carbonates and carbonates

Karim Adil, Amor Ben Ali, Gilles Dujardin, Robert Dhal, Marc Leblanc, Vincent Maisonneuve

Research output: Contribution to journal › Article › peer-review

8 Scopus citations

Abstract

Tren amine cations and carbonate anions adopt a ternary symmetry while tetra amine cations are tetrahedral. The symmetry of these constitutive ions influences strongly the nature of the solids which crystallise from solutions. Large fluorinated aluminate polyanions with tetrahedral symmetry appear in the presence of tren amine, while infinite chains of AlF₆ octahedra are observed with tetra amine and that noncentrosymmetric structures are frequently encountered in rare earth fluoride carbonates.

Original language	English (US)
Pages (from-to)	1709-1714
Number of pages	6
Journal	Journal of Fluorine Chemistry
Volume	125
Issue number	11 SPEC. ISS.
DOIs	https://doi.org/10.1016/j.jfluchem.2004.09.019
State	Published - Nov 2004
Externally published	Yes

Keywords

Carbonates
Hybrid fluorides
Hydrothermal synthesis
Microwave heating
Solid state
Solvothermal synthesis

ASJC Scopus subject areas

Biochemistry
Environmental Chemistry
Physical and Theoretical Chemistry
Organic Chemistry
Inorganic Chemistry

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10.1016/j.jfluchem.2004.09.019

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title = "Ternary and tetrahedral symmetry in hybrid fluorides, fluoride carbonates and carbonates",

abstract = "Tren amine cations and carbonate anions adopt a ternary symmetry while tetra amine cations are tetrahedral. The symmetry of these constitutive ions influences strongly the nature of the solids which crystallise from solutions. Large fluorinated aluminate polyanions with tetrahedral symmetry appear in the presence of tren amine, while infinite chains of AlF6 octahedra are observed with tetra amine and that noncentrosymmetric structures are frequently encountered in rare earth fluoride carbonates.",

keywords = "Carbonates, Hybrid fluorides, Hydrothermal synthesis, Microwave heating, Solid state, Solvothermal synthesis",

author = "Karim Adil and Ali, {Amor Ben} and Gilles Dujardin and Robert Dhal and Marc Leblanc and Vincent Maisonneuve",

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language = "English (US)",

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T1 - Ternary and tetrahedral symmetry in hybrid fluorides, fluoride carbonates and carbonates

AU - Adil, Karim

AU - Ali, Amor Ben

AU - Dujardin, Gilles

AU - Dhal, Robert

AU - Leblanc, Marc

AU - Maisonneuve, Vincent

PY - 2004/11

Y1 - 2004/11

N2 - Tren amine cations and carbonate anions adopt a ternary symmetry while tetra amine cations are tetrahedral. The symmetry of these constitutive ions influences strongly the nature of the solids which crystallise from solutions. Large fluorinated aluminate polyanions with tetrahedral symmetry appear in the presence of tren amine, while infinite chains of AlF6 octahedra are observed with tetra amine and that noncentrosymmetric structures are frequently encountered in rare earth fluoride carbonates.

AB - Tren amine cations and carbonate anions adopt a ternary symmetry while tetra amine cations are tetrahedral. The symmetry of these constitutive ions influences strongly the nature of the solids which crystallise from solutions. Large fluorinated aluminate polyanions with tetrahedral symmetry appear in the presence of tren amine, while infinite chains of AlF6 octahedra are observed with tetra amine and that noncentrosymmetric structures are frequently encountered in rare earth fluoride carbonates.

KW - Carbonates

KW - Hybrid fluorides

KW - Hydrothermal synthesis

KW - Microwave heating

KW - Solid state

KW - Solvothermal synthesis

UR - http://www.scopus.com/inward/record.url?scp=9944225793&partnerID=8YFLogxK

U2 - 10.1016/j.jfluchem.2004.09.019

DO - 10.1016/j.jfluchem.2004.09.019

M3 - Article

AN - SCOPUS:9944225793

SN - 0022-1139

VL - 125

SP - 1709

EP - 1714

JO - Journal of Fluorine Chemistry

JF - Journal of Fluorine Chemistry

IS - 11 SPEC. ISS.

ER -

Ternary and tetrahedral symmetry in hybrid fluorides, fluoride carbonates and carbonates

Abstract

Keywords

ASJC Scopus subject areas

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