Terminal co-ligand directed synthesis of a neutral, non-interpenetrated (10,3)-a metal-organic framework

Jarrod F. Eubank; Rosa D. Walsh; Mohamed Eddaoudi

doi:10.1039/b417013j

Terminal co-ligand directed synthesis of a neutral, non-interpenetrated (10,3)-a metal-organic framework

Jarrod F. Eubank, Rosa D. Walsh, Mohamed Eddaoudi^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

70 Scopus citations

Abstract

A neutral, non-interpenetrated porous metal-organic framework (MOF) having (10,3)-a topology, Cu(3,5-PDC)(DMF)(py), (DMF = N,N′-dimethylformamide, py = pyridine), has been constructed via the assembly of the achiral tri-connected building blocks 3,5-pyridinedicarboxylate (3,5-PDC) and CuN(CO ₂)₂, synthesized in situ. Similarly, a 2D structure having (6,3) topology has been generated, each by means of terminal co-ligand directed synthesis.

Original language	English (US)
Pages (from-to)	2095-2097
Number of pages	3
Journal	CHEMICAL COMMUNICATIONS
Issue number	16
DOIs	https://doi.org/10.1039/b417013j
State	Published - Apr 28 2005
Externally published	Yes

ASJC Scopus subject areas

Catalysis
Electronic, Optical and Magnetic Materials
Ceramics and Composites
General Chemistry
Surfaces, Coatings and Films
Metals and Alloys
Materials Chemistry

Access to Document

10.1039/b417013j

Cite this

@article{4d4b4027a1934d29b5ea2228a4614b50,

title = "Terminal co-ligand directed synthesis of a neutral, non-interpenetrated (10,3)-a metal-organic framework",

abstract = "A neutral, non-interpenetrated porous metal-organic framework (MOF) having (10,3)-a topology, Cu(3,5-PDC)(DMF)(py), (DMF = N,N′-dimethylformamide, py = pyridine), has been constructed via the assembly of the achiral tri-connected building blocks 3,5-pyridinedicarboxylate (3,5-PDC) and CuN(CO 2)2, synthesized in situ. Similarly, a 2D structure having (6,3) topology has been generated, each by means of terminal co-ligand directed synthesis.",

author = "Eubank, {Jarrod F.} and Walsh, {Rosa D.} and Mohamed Eddaoudi",

year = "2005",

month = apr,

day = "28",

doi = "10.1039/b417013j",

language = "English (US)",

pages = "2095--2097",

journal = "CHEMICAL COMMUNICATIONS",

issn = "1359-7345",

publisher = "ROYAL SOC CHEMISTRY",

number = "16",

}

TY - JOUR

T1 - Terminal co-ligand directed synthesis of a neutral, non-interpenetrated (10,3)-a metal-organic framework

AU - Eubank, Jarrod F.

AU - Walsh, Rosa D.

AU - Eddaoudi, Mohamed

PY - 2005/4/28

Y1 - 2005/4/28

N2 - A neutral, non-interpenetrated porous metal-organic framework (MOF) having (10,3)-a topology, Cu(3,5-PDC)(DMF)(py), (DMF = N,N′-dimethylformamide, py = pyridine), has been constructed via the assembly of the achiral tri-connected building blocks 3,5-pyridinedicarboxylate (3,5-PDC) and CuN(CO 2)2, synthesized in situ. Similarly, a 2D structure having (6,3) topology has been generated, each by means of terminal co-ligand directed synthesis.

AB - A neutral, non-interpenetrated porous metal-organic framework (MOF) having (10,3)-a topology, Cu(3,5-PDC)(DMF)(py), (DMF = N,N′-dimethylformamide, py = pyridine), has been constructed via the assembly of the achiral tri-connected building blocks 3,5-pyridinedicarboxylate (3,5-PDC) and CuN(CO 2)2, synthesized in situ. Similarly, a 2D structure having (6,3) topology has been generated, each by means of terminal co-ligand directed synthesis.

UR - http://www.scopus.com/inward/record.url?scp=18544365120&partnerID=8YFLogxK

U2 - 10.1039/b417013j

DO - 10.1039/b417013j

M3 - Article

C2 - 15846411

AN - SCOPUS:18544365120

SN - 1359-7345

SP - 2095

EP - 2097

JO - CHEMICAL COMMUNICATIONS

JF - CHEMICAL COMMUNICATIONS

IS - 16

ER -

Terminal co-ligand directed synthesis of a neutral, non-interpenetrated (10,3)-a metal-organic framework

Abstract

ASJC Scopus subject areas

Access to Document

Other files and links

Fingerprint

Cite this