Templated synthesis, postsynthetic metal exchange, and properties of a porphyrin-encapsulating metal-organic material

Zhenjie Zhang; Linping Zhang; Łukasz Wojtas; Patrick S. Nugent; Mohamed Eddaoudi; Michael J. Zaworotko

doi:10.1021/ja209643b

Templated synthesis, postsynthetic metal exchange, and properties of a porphyrin-encapsulating metal-organic material

Zhenjie Zhang, Linping Zhang, Łukasz Wojtas, Patrick S. Nugent, Mohamed Eddaoudi, Michael J. Zaworotko

Research output: Contribution to journal › Article › peer-review

218 Scopus citations

Abstract

Reaction of biphenyl-3,4′,5-tricarboxylate (H 3BPT) and CdCl 2 in the presence of meso-tetra(N-methyl-4-pyridyl)porphine tetratosylate (TMPyP) afforded porph@MOM-10, a microporous metal-organic material containing CdTMPyP cations encapsulated in an anionic Cd(II) carboxylate framework, [Cd 6(BPT) 4Cl 4(H 2O) 4]. Porph@MOM-10 is a versatile platform that undergoes exchange to serve as the parent of a series of porph@MOMs that exhibit permanent porosity and heterogeneous catalytic activity. © 2011 American Chemical Society.

Original language	English (US)
Pages (from-to)	924-927
Number of pages	4
Journal	Journal of the American Chemical Society
Volume	134
Issue number	2
DOIs	https://doi.org/10.1021/ja209643b
State	Published - Dec 28 2011

Bibliographical note

KAUST Repository Item: Exported on 2020-10-01
Acknowledged KAUST grant number(s): FIC/2010/06
Acknowledgements: This publication is based on work supported by Award FIC/2010/06 made by King Abdullah University of Science and Technology (KAUST).

ASJC Scopus subject areas

Biochemistry
Colloid and Surface Chemistry
General Chemistry
Catalysis

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10.1021/ja209643b

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title = "Templated synthesis, postsynthetic metal exchange, and properties of a porphyrin-encapsulating metal-organic material",

abstract = "Reaction of biphenyl-3,4′,5-tricarboxylate (H 3BPT) and CdCl 2 in the presence of meso-tetra(N-methyl-4-pyridyl)porphine tetratosylate (TMPyP) afforded porph@MOM-10, a microporous metal-organic material containing CdTMPyP cations encapsulated in an anionic Cd(II) carboxylate framework, [Cd 6(BPT) 4Cl 4(H 2O) 4]. Porph@MOM-10 is a versatile platform that undergoes exchange to serve as the parent of a series of porph@MOMs that exhibit permanent porosity and heterogeneous catalytic activity. {\textcopyright} 2011 American Chemical Society.",

author = "Zhenjie Zhang and Linping Zhang and {\L}ukasz Wojtas and Nugent, {Patrick S.} and Mohamed Eddaoudi and Zaworotko, {Michael J.}",

note = "KAUST Repository Item: Exported on 2020-10-01 Acknowledged KAUST grant number(s): FIC/2010/06 Acknowledgements: This publication is based on work supported by Award FIC/2010/06 made by King Abdullah University of Science and Technology (KAUST).",

year = "2011",

month = dec,

day = "28",

doi = "10.1021/ja209643b",

language = "English (US)",

volume = "134",

pages = "924--927",

journal = "Journal of the American Chemical Society",

issn = "0002-7863",

publisher = "American Chemical Society",

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T1 - Templated synthesis, postsynthetic metal exchange, and properties of a porphyrin-encapsulating metal-organic material

AU - Zhang, Zhenjie

AU - Zhang, Linping

AU - Wojtas, Łukasz

AU - Nugent, Patrick S.

AU - Eddaoudi, Mohamed

AU - Zaworotko, Michael J.

N1 - KAUST Repository Item: Exported on 2020-10-01 Acknowledged KAUST grant number(s): FIC/2010/06 Acknowledgements: This publication is based on work supported by Award FIC/2010/06 made by King Abdullah University of Science and Technology (KAUST).

PY - 2011/12/28

Y1 - 2011/12/28

N2 - Reaction of biphenyl-3,4′,5-tricarboxylate (H 3BPT) and CdCl 2 in the presence of meso-tetra(N-methyl-4-pyridyl)porphine tetratosylate (TMPyP) afforded porph@MOM-10, a microporous metal-organic material containing CdTMPyP cations encapsulated in an anionic Cd(II) carboxylate framework, [Cd 6(BPT) 4Cl 4(H 2O) 4]. Porph@MOM-10 is a versatile platform that undergoes exchange to serve as the parent of a series of porph@MOMs that exhibit permanent porosity and heterogeneous catalytic activity. © 2011 American Chemical Society.

AB - Reaction of biphenyl-3,4′,5-tricarboxylate (H 3BPT) and CdCl 2 in the presence of meso-tetra(N-methyl-4-pyridyl)porphine tetratosylate (TMPyP) afforded porph@MOM-10, a microporous metal-organic material containing CdTMPyP cations encapsulated in an anionic Cd(II) carboxylate framework, [Cd 6(BPT) 4Cl 4(H 2O) 4]. Porph@MOM-10 is a versatile platform that undergoes exchange to serve as the parent of a series of porph@MOMs that exhibit permanent porosity and heterogeneous catalytic activity. © 2011 American Chemical Society.

UR - http://hdl.handle.net/10754/562060

UR - https://pubs.acs.org/doi/10.1021/ja209643b

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DO - 10.1021/ja209643b

M3 - Article

SN - 0002-7863

VL - 134

SP - 924

EP - 927

JO - Journal of the American Chemical Society

JF - Journal of the American Chemical Society

IS - 2

ER -

Templated synthesis, postsynthetic metal exchange, and properties of a porphyrin-encapsulating metal-organic material

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CCDC 877425: Experimental Crystal Structure Determination : catena-((5,10,15,20-tetrakis(N-Methylpyridinium-4-yl)porphyrinato)-copper tetrakis(mu~5~-biphenyl-3,4',5-tricarboxylato)-tetrakis(mu~2~-chloro)-tetra-aqua-di-cadmium-tetra-copper)

CCDC 877423: Experimental Crystal Structure Determination : catena-(Chloro-(5,10,15,20-tetrakis(N-methylpyridinium-4-yl)porphyrinato)-cadmium tetrakis(mu~5~-biphenyl-3,4',5-tricarboxylato)-tetrakis(mu~2~-chloro)-tetra-aqua-hexa-cadmium dimethylformamide so

CCDC 877424: Experimental Crystal Structure Determination : catena-(Diaqua-(5,10,15,20-tetrakis(N-methylpyridinium-4-yl)porphyrinato)-manganese tetrakis(mu~5~-biphenyl-3,4',5-tricarboxylato)-tetrakis(mu~2~-chloro)-tetrakis(methanol)-hexa-manganese chloride

Cite this

Templated synthesis, postsynthetic metal exchange, and properties of a porphyrin-encapsulating metal-organic material

Abstract

Bibliographical note

ASJC Scopus subject areas

Access to Document

Other files and links

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CCDC 877425: Experimental Crystal Structure Determination : catena-((5,10,15,20-tetrakis(N-Methylpyridinium-4-yl)porphyrinato)-copper tetrakis(mu~5~-biphenyl-3,4',5-tricarboxylato)-tetrakis(mu~2~-chloro)-tetra-aqua-di-cadmium-tetra-copper)

CCDC 877423: Experimental Crystal Structure Determination : catena-(Chloro-(5,10,15,20-tetrakis(N-methylpyridinium-4-yl)porphyrinato)-cadmium tetrakis(mu~5~-biphenyl-3,4',5-tricarboxylato)-tetrakis(mu~2~-chloro)-tetra-aqua-hexa-cadmium dimethylformamide so

CCDC 877424: Experimental Crystal Structure Determination : catena-(Diaqua-(5,10,15,20-tetrakis(N-methylpyridinium-4-yl)porphyrinato)-manganese tetrakis(mu~5~-biphenyl-3,4',5-tricarboxylato)-tetrakis(mu~2~-chloro)-tetrakis(methanol)-hexa-manganese chloride

Cite this