Synthesis, structures and reactivity of N-donor-functionalised Cu(I) aryloxides

Christopher E. Anson; Lukasz Ponikiewski; Alexander Rothenberger

doi:10.1016/j.ica.2005.12.017

Synthesis, structures and reactivity of N-donor-functionalised Cu(I) aryloxides

Christopher E. Anson, Lukasz Ponikiewski, Alexander Rothenberger^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

12 Scopus citations

Abstract

The preparation and characterisation of the Cu(I) aryloxides [Cu₁₆(3-pyO)₁₆(dppm)₈] (1), [{Cu₂(2-pyO)₂(dppm)}₂] (2) and [{Cu₃(μ₃-6-OQ)₂(dppm)₃}{(6-HOQ)₂(μ-6-OQ)}] (3) (dppm = 1,2-bis-diphenylphosphinomethane, 6-HOQ = 6-hydroxyquinoline, py = pyridine) are described. A first attempt to employ organic anhydrides in insertion reactions with Cu(I) aryloxides was made producing the one-dimensional coordination polymer 1/_∞[Cu₃(3-pyO)(CO₂C₂H₄Boc)(dppm^-)(dppm)]_∞ (4) (Boc = tert-butoxycarbonyl).

Original language	English (US)
Pages (from-to)	2263-2267
Number of pages	5
Journal	Inorganica Chimica Acta
Volume	359
Issue number	7
DOIs	https://doi.org/10.1016/j.ica.2005.12.017
State	Published - Apr 25 2006
Externally published	Yes

Keywords

Insertion reaction
Metal alkoxide
Organic anhydride

ASJC Scopus subject areas

Physical and Theoretical Chemistry
Inorganic Chemistry
Materials Chemistry

Access to Document

10.1016/j.ica.2005.12.017

Cite this

@article{5309bc2550574453b0b01c0ea6411bce,

title = "Synthesis, structures and reactivity of N-donor-functionalised Cu(I) aryloxides",

abstract = "The preparation and characterisation of the Cu(I) aryloxides [Cu16(3-pyO)16(dppm)8] (1), [{Cu2(2-pyO)2(dppm)}2] (2) and [{Cu3(μ3-6-OQ)2(dppm)3}{(6-HOQ)2(μ-6-OQ)}] (3) (dppm = 1,2-bis-diphenylphosphinomethane, 6-HOQ = 6-hydroxyquinoline, py = pyridine) are described. A first attempt to employ organic anhydrides in insertion reactions with Cu(I) aryloxides was made producing the one-dimensional coordination polymer 1/∞[Cu3(3-pyO)(CO2C2H4Boc)(dppm-)(dppm)]∞ (4) (Boc = tert-butoxycarbonyl).",

keywords = "Insertion reaction, Metal alkoxide, Organic anhydride",

author = "Anson, {Christopher E.} and Lukasz Ponikiewski and Alexander Rothenberger",

year = "2006",

month = apr,

day = "25",

doi = "10.1016/j.ica.2005.12.017",

language = "English (US)",

volume = "359",

pages = "2263--2267",

journal = "Inorganica Chimica Acta",

issn = "0020-1693",

publisher = "Elsevier B.V.",

number = "7",

}

TY - JOUR

T1 - Synthesis, structures and reactivity of N-donor-functionalised Cu(I) aryloxides

AU - Anson, Christopher E.

AU - Ponikiewski, Lukasz

AU - Rothenberger, Alexander

PY - 2006/4/25

Y1 - 2006/4/25

N2 - The preparation and characterisation of the Cu(I) aryloxides [Cu16(3-pyO)16(dppm)8] (1), [{Cu2(2-pyO)2(dppm)}2] (2) and [{Cu3(μ3-6-OQ)2(dppm)3}{(6-HOQ)2(μ-6-OQ)}] (3) (dppm = 1,2-bis-diphenylphosphinomethane, 6-HOQ = 6-hydroxyquinoline, py = pyridine) are described. A first attempt to employ organic anhydrides in insertion reactions with Cu(I) aryloxides was made producing the one-dimensional coordination polymer 1/∞[Cu3(3-pyO)(CO2C2H4Boc)(dppm-)(dppm)]∞ (4) (Boc = tert-butoxycarbonyl).

AB - The preparation and characterisation of the Cu(I) aryloxides [Cu16(3-pyO)16(dppm)8] (1), [{Cu2(2-pyO)2(dppm)}2] (2) and [{Cu3(μ3-6-OQ)2(dppm)3}{(6-HOQ)2(μ-6-OQ)}] (3) (dppm = 1,2-bis-diphenylphosphinomethane, 6-HOQ = 6-hydroxyquinoline, py = pyridine) are described. A first attempt to employ organic anhydrides in insertion reactions with Cu(I) aryloxides was made producing the one-dimensional coordination polymer 1/∞[Cu3(3-pyO)(CO2C2H4Boc)(dppm-)(dppm)]∞ (4) (Boc = tert-butoxycarbonyl).

KW - Insertion reaction

KW - Metal alkoxide

KW - Organic anhydride

UR - http://www.scopus.com/inward/record.url?scp=33645848755&partnerID=8YFLogxK

U2 - 10.1016/j.ica.2005.12.017

DO - 10.1016/j.ica.2005.12.017

M3 - Article

AN - SCOPUS:33645848755

SN - 0020-1693

VL - 359

SP - 2263

EP - 2267

JO - Inorganica Chimica Acta

JF - Inorganica Chimica Acta

IS - 7

ER -

Synthesis, structures and reactivity of N-donor-functionalised Cu(I) aryloxides

Abstract

Keywords

ASJC Scopus subject areas

Access to Document

Other files and links

Fingerprint

Cite this