Synthesis, structure and magnetic behavior of new 1D metal-organic coordination polymer with Fe3O core

Maxim P. Yutkin; Marina S. Zavakhina; Alexander V. Virovets; Danil N. Dybtsev; Vladimir P. Fedin; Tetsuro Kusamoto; Hiroshi Nishihara

doi:10.1016/j.ica.2010.10.015

Synthesis, structure and magnetic behavior of new 1D metal-organic coordination polymer with Fe₃O core

Maxim P. Yutkin, Marina S. Zavakhina, Alexander V. Virovets, Danil N. Dybtsev, Vladimir P. Fedin, Tetsuro Kusamoto, Hiroshi Nishihara

Research output: Contribution to journal › Article › peer-review

12 Scopus citations

Abstract

New metal-organic coordination polymer, (Me₃NH)[Fe ₃(μ₃-O)(μ-HCOO)₈]·DMF (1), was synthesized by heating of Fe(NO₃)₃·9H₂O and [NH(CH₃)₃]Cl in DMF/HCOOH solution. The single-crystal X-ray structure analysis reveals this compound has 1D anionic framework structure built from Fe₃O(μ-HCOO)₆ cluster units linked by formate bridges. Compound 1 was characterized by elemental analysis, IR and TGA. The magnetic susceptibility measurements indicate a strong antiferromagnetic exchange interaction between Fe^III ions in the cluster and intercluster magnetic interaction.

Original language	English (US)
Pages (from-to)	513-516
Number of pages	4
Journal	Inorganica Chimica Acta
Volume	365
Issue number	1
DOIs	https://doi.org/10.1016/j.ica.2010.10.015
State	Published - Jan 15 2011
Externally published	Yes

Keywords

Coordination polymers
Iron(III) complexes
Magnetic properties
Metal-organic formates
X-ray single-crystal analysis

ASJC Scopus subject areas

Physical and Theoretical Chemistry
Inorganic Chemistry
Materials Chemistry

Access to Document

10.1016/j.ica.2010.10.015

Cite this

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title = "Synthesis, structure and magnetic behavior of new 1D metal-organic coordination polymer with Fe3O core",

abstract = "New metal-organic coordination polymer, (Me3NH)[Fe 3(μ3-O)(μ-HCOO)8]·DMF (1), was synthesized by heating of Fe(NO3)3·9H2O and [NH(CH3)3]Cl in DMF/HCOOH solution. The single-crystal X-ray structure analysis reveals this compound has 1D anionic framework structure built from Fe3O(μ-HCOO)6 cluster units linked by formate bridges. Compound 1 was characterized by elemental analysis, IR and TGA. The magnetic susceptibility measurements indicate a strong antiferromagnetic exchange interaction between FeIII ions in the cluster and intercluster magnetic interaction.",

keywords = "Coordination polymers, Iron(III) complexes, Magnetic properties, Metal-organic formates, X-ray single-crystal analysis",

author = "Yutkin, {Maxim P.} and Zavakhina, {Marina S.} and Virovets, {Alexander V.} and Dybtsev, {Danil N.} and Fedin, {Vladimir P.} and Tetsuro Kusamoto and Hiroshi Nishihara",

year = "2011",

month = jan,

day = "15",

doi = "10.1016/j.ica.2010.10.015",

language = "English (US)",

volume = "365",

pages = "513--516",

journal = "Inorganica Chimica Acta",

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T1 - Synthesis, structure and magnetic behavior of new 1D metal-organic coordination polymer with Fe3O core

AU - Yutkin, Maxim P.

AU - Zavakhina, Marina S.

AU - Virovets, Alexander V.

AU - Dybtsev, Danil N.

AU - Fedin, Vladimir P.

AU - Kusamoto, Tetsuro

AU - Nishihara, Hiroshi

PY - 2011/1/15

Y1 - 2011/1/15

N2 - New metal-organic coordination polymer, (Me3NH)[Fe 3(μ3-O)(μ-HCOO)8]·DMF (1), was synthesized by heating of Fe(NO3)3·9H2O and [NH(CH3)3]Cl in DMF/HCOOH solution. The single-crystal X-ray structure analysis reveals this compound has 1D anionic framework structure built from Fe3O(μ-HCOO)6 cluster units linked by formate bridges. Compound 1 was characterized by elemental analysis, IR and TGA. The magnetic susceptibility measurements indicate a strong antiferromagnetic exchange interaction between FeIII ions in the cluster and intercluster magnetic interaction.

AB - New metal-organic coordination polymer, (Me3NH)[Fe 3(μ3-O)(μ-HCOO)8]·DMF (1), was synthesized by heating of Fe(NO3)3·9H2O and [NH(CH3)3]Cl in DMF/HCOOH solution. The single-crystal X-ray structure analysis reveals this compound has 1D anionic framework structure built from Fe3O(μ-HCOO)6 cluster units linked by formate bridges. Compound 1 was characterized by elemental analysis, IR and TGA. The magnetic susceptibility measurements indicate a strong antiferromagnetic exchange interaction between FeIII ions in the cluster and intercluster magnetic interaction.

KW - Coordination polymers

KW - Iron(III) complexes

KW - Magnetic properties

KW - Metal-organic formates

KW - X-ray single-crystal analysis

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DO - 10.1016/j.ica.2010.10.015

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