Synthesis, Structural Characterization and Thermal Behavior of New Organic–Inorganic Sulfate

Sami Soukrata; Mohamed Belhouchet; Karim Adil; Tahar Mhiri

doi:10.1007/s10876-014-0823-0

Synthesis, Structural Characterization and Thermal Behavior of New Organic–Inorganic Sulfate

Sami Soukrata^*, Mohamed Belhouchet, Karim Adil, Tahar Mhiri

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

1 Scopus citations

Abstract

The new organic–inorganic compound has been synthesized and characterized by X-ray single crystal, infra-red, Raman spectroscopy and thermal investigations. It crystallizes in the monoclinic space group P2₁ with following unit cell dimensions: a = 4.5542(2) Å, b = 10.5171(5) Å, c = 13.7373(6) Å, β = 93.936(2)°, Z = 2 and V = 656.42(5) Å³. The crystal structure has been determined and refined to R₁ = 0.0395 and wR₂ = 0.1143 using 3950 independent reflections. The atomic arrangement is defined by infinite anionic chains running parallel to the [100] direction. These last are interconnected to the organic cation by hydrogen bonds N–H…O to form a one dimensional network.

Original language	English (US)
Pages (from-to)	1413-1424
Number of pages	12
Journal	Journal of Cluster Science
Volume	26
Issue number	4
DOIs	https://doi.org/10.1007/s10876-014-0823-0
State	Published - Dec 13 2015
Externally published	Yes

Keywords

Chemical synthesis
Crystal structure
Inorganic compounds
NMR spectroscopy
Thermal analysis

ASJC Scopus subject areas

Chemistry(all)
Biochemistry
Materials Science(all)
Condensed Matter Physics

Access to Document

10.1007/s10876-014-0823-0

Cite this

@article{7ed7b60055924cdd81bff3f33f62f473,

title = "Synthesis, Structural Characterization and Thermal Behavior of New Organic–Inorganic Sulfate",

abstract = "The new organic–inorganic compound has been synthesized and characterized by X-ray single crystal, infra-red, Raman spectroscopy and thermal investigations. It crystallizes in the monoclinic space group P21 with following unit cell dimensions: a = 4.5542(2) {\AA}, b = 10.5171(5) {\AA}, c = 13.7373(6) {\AA}, β = 93.936(2)°, Z = 2 and V = 656.42(5) {\AA}3. The crystal structure has been determined and refined to R1 = 0.0395 and wR2 = 0.1143 using 3950 independent reflections. The atomic arrangement is defined by infinite anionic chains running parallel to the [100] direction. These last are interconnected to the organic cation by hydrogen bonds N–H…O to form a one dimensional network.",

keywords = "Chemical synthesis, Crystal structure, Inorganic compounds, NMR spectroscopy, Thermal analysis",

author = "Sami Soukrata and Mohamed Belhouchet and Karim Adil and Tahar Mhiri",

year = "2015",

month = dec,

day = "13",

doi = "10.1007/s10876-014-0823-0",

language = "English (US)",

volume = "26",

pages = "1413--1424",

journal = "Journal of Cluster Science",

issn = "1040-7278",

publisher = "Springer New York",

number = "4",

}

TY - JOUR

T1 - Synthesis, Structural Characterization and Thermal Behavior of New Organic–Inorganic Sulfate

AU - Soukrata, Sami

AU - Belhouchet, Mohamed

AU - Adil, Karim

AU - Mhiri, Tahar

PY - 2015/12/13

Y1 - 2015/12/13

N2 - The new organic–inorganic compound has been synthesized and characterized by X-ray single crystal, infra-red, Raman spectroscopy and thermal investigations. It crystallizes in the monoclinic space group P21 with following unit cell dimensions: a = 4.5542(2) Å, b = 10.5171(5) Å, c = 13.7373(6) Å, β = 93.936(2)°, Z = 2 and V = 656.42(5) Å3. The crystal structure has been determined and refined to R1 = 0.0395 and wR2 = 0.1143 using 3950 independent reflections. The atomic arrangement is defined by infinite anionic chains running parallel to the [100] direction. These last are interconnected to the organic cation by hydrogen bonds N–H…O to form a one dimensional network.

AB - The new organic–inorganic compound has been synthesized and characterized by X-ray single crystal, infra-red, Raman spectroscopy and thermal investigations. It crystallizes in the monoclinic space group P21 with following unit cell dimensions: a = 4.5542(2) Å, b = 10.5171(5) Å, c = 13.7373(6) Å, β = 93.936(2)°, Z = 2 and V = 656.42(5) Å3. The crystal structure has been determined and refined to R1 = 0.0395 and wR2 = 0.1143 using 3950 independent reflections. The atomic arrangement is defined by infinite anionic chains running parallel to the [100] direction. These last are interconnected to the organic cation by hydrogen bonds N–H…O to form a one dimensional network.

KW - Chemical synthesis

KW - Crystal structure

KW - Inorganic compounds

KW - NMR spectroscopy

KW - Thermal analysis

UR - http://www.scopus.com/inward/record.url?scp=84934434979&partnerID=8YFLogxK

U2 - 10.1007/s10876-014-0823-0

DO - 10.1007/s10876-014-0823-0

M3 - Article

AN - SCOPUS:84934434979

SN - 1040-7278

VL - 26

SP - 1413

EP - 1424

JO - Journal of Cluster Science

JF - Journal of Cluster Science

IS - 4

ER -

Synthesis, Structural Characterization and Thermal Behavior of New Organic–Inorganic Sulfate

Abstract

Keywords

ASJC Scopus subject areas

Access to Document

Other files and links

Fingerprint

Cite this