Synthesis, Structural Characterization and Thermal Behavior of New Organic–Inorganic Sulfate

Sami Soukrata; Mohamed Belhouchet; Karim Adil; Tahar Mhiri

doi:10.1007/s10876-014-0823-0

Synthesis, Structural Characterization and Thermal Behavior of New Organic–Inorganic Sulfate

Sami Soukrata^*, Mohamed Belhouchet, Karim Adil, Tahar Mhiri

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

1 Scopus citations

Abstract

The new organic–inorganic compound has been synthesized and characterized by X-ray single crystal, infra-red, Raman spectroscopy and thermal investigations. It crystallizes in the monoclinic space group P2₁ with following unit cell dimensions: a = 4.5542(2) Å, b = 10.5171(5) Å, c = 13.7373(6) Å, β = 93.936(2)°, Z = 2 and V = 656.42(5) Å³. The crystal structure has been determined and refined to R₁ = 0.0395 and wR₂ = 0.1143 using 3950 independent reflections. The atomic arrangement is defined by infinite anionic chains running parallel to the [100] direction. These last are interconnected to the organic cation by hydrogen bonds N–H…O to form a one dimensional network.

Original language	English (US)
Pages (from-to)	1413-1424
Number of pages	12
Journal	Journal of Cluster Science
Volume	26
Issue number	4
DOIs	https://doi.org/10.1007/s10876-014-0823-0
State	Published - Dec 13 2015

Bibliographical note

Publisher Copyright:
© 2014, Springer Science+Business Media New York.

Keywords

Chemical synthesis
Crystal structure
Inorganic compounds
NMR spectroscopy
Thermal analysis

ASJC Scopus subject areas

General Chemistry
Condensed Matter Physics
Biochemistry
General Materials Science

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10.1007/s10876-014-0823-0

Cite this

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title = "Synthesis, Structural Characterization and Thermal Behavior of New Organic–Inorganic Sulfate",

abstract = "The new organic–inorganic compound has been synthesized and characterized by X-ray single crystal, infra-red, Raman spectroscopy and thermal investigations. It crystallizes in the monoclinic space group P21 with following unit cell dimensions: a = 4.5542(2) {\AA}, b = 10.5171(5) {\AA}, c = 13.7373(6) {\AA}, β = 93.936(2)°, Z = 2 and V = 656.42(5) {\AA}3. The crystal structure has been determined and refined to R1 = 0.0395 and wR2 = 0.1143 using 3950 independent reflections. The atomic arrangement is defined by infinite anionic chains running parallel to the [100] direction. These last are interconnected to the organic cation by hydrogen bonds N–H…O to form a one dimensional network.",

keywords = "Chemical synthesis, Crystal structure, Inorganic compounds, NMR spectroscopy, Thermal analysis",

author = "Sami Soukrata and Mohamed Belhouchet and Karim Adil and Tahar Mhiri",

note = "Publisher Copyright: {\textcopyright} 2014, Springer Science+Business Media New York.",

year = "2015",

month = dec,

day = "13",

doi = "10.1007/s10876-014-0823-0",

language = "English (US)",

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TY - JOUR

T1 - Synthesis, Structural Characterization and Thermal Behavior of New Organic–Inorganic Sulfate

AU - Soukrata, Sami

AU - Belhouchet, Mohamed

AU - Adil, Karim

AU - Mhiri, Tahar

PY - 2015/12/13

Y1 - 2015/12/13

N2 - The new organic–inorganic compound has been synthesized and characterized by X-ray single crystal, infra-red, Raman spectroscopy and thermal investigations. It crystallizes in the monoclinic space group P21 with following unit cell dimensions: a = 4.5542(2) Å, b = 10.5171(5) Å, c = 13.7373(6) Å, β = 93.936(2)°, Z = 2 and V = 656.42(5) Å3. The crystal structure has been determined and refined to R1 = 0.0395 and wR2 = 0.1143 using 3950 independent reflections. The atomic arrangement is defined by infinite anionic chains running parallel to the [100] direction. These last are interconnected to the organic cation by hydrogen bonds N–H…O to form a one dimensional network.

AB - The new organic–inorganic compound has been synthesized and characterized by X-ray single crystal, infra-red, Raman spectroscopy and thermal investigations. It crystallizes in the monoclinic space group P21 with following unit cell dimensions: a = 4.5542(2) Å, b = 10.5171(5) Å, c = 13.7373(6) Å, β = 93.936(2)°, Z = 2 and V = 656.42(5) Å3. The crystal structure has been determined and refined to R1 = 0.0395 and wR2 = 0.1143 using 3950 independent reflections. The atomic arrangement is defined by infinite anionic chains running parallel to the [100] direction. These last are interconnected to the organic cation by hydrogen bonds N–H…O to form a one dimensional network.

KW - Chemical synthesis

KW - Crystal structure

KW - Inorganic compounds

KW - NMR spectroscopy

KW - Thermal analysis

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U2 - 10.1007/s10876-014-0823-0

DO - 10.1007/s10876-014-0823-0

M3 - Article

AN - SCOPUS:84934434979

SN - 1040-7278

VL - 26

SP - 1413

EP - 1424

JO - Journal of Cluster Science

JF - Journal of Cluster Science

IS - 4

ER -

Synthesis, Structural Characterization and Thermal Behavior of New Organic–Inorganic Sulfate

Abstract

Bibliographical note

Keywords

ASJC Scopus subject areas

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