Abstract
Apart from being experimentally and theoretically interesting, tetraphenylene has potential applications in different fields, including supramolecular chemistry, material science, and asymmetric catalysis. Although a wide range of substituted tetraphenylenes have been reported, octaamine-based tetraphenylene derivatives have not been reported because of their instability. Here, stable octaaminotetraphenylene octahydrochloride is synthesized from the bromination of tetraphenylene to octabromotetraphenylene, which is subsequently aminated into octaiminotetraphenylene. Finally, the imino derivative is deprotected to yield octaaminotetraphenylene octahydrochloride.
| Original language | English (US) |
|---|---|
| Journal | The Journal of Organic Chemistry |
| DOIs | |
| State | Published - Sep 1 2021 |
Bibliographical note
KAUST Repository Item: Exported on 2021-09-06Acknowledgements: This research was supported by the Creative Research Initiative (CRI, 2014R1A3A2069102), Science Research Center (SRC, 2016R1A5A1009405), and Young Researcher (2019R1C1C1006650) programs through the National Research Foundation (NRF) of Korea. We acknowledge that the single-crystal X-ray diffraction experiments with synchrotron radiation were performed at the BL2D-SMC beamline in the Pohang Accelerator Laboratory.
ASJC Scopus subject areas
- Organic Chemistry
Fingerprint
Dive into the research topics of 'Synthesis of Saddle-Shape Octaaminotetraphenylene Octahydrochloride'. Together they form a unique fingerprint.Datasets
-
CCDC 2083485: Experimental Crystal Structure Determination : tetraphenylene-2,3,6,7,10,11,14,15-octakis(aminium) octakis(chloride) octakis(hydrogen chloride)
Mahmood, J. (Creator), Ahmad, I. (Creator), Kim, D. (Creator), Kodirov, R. (Creator), Yu, S.-Y. (Creator), Seo, J.-M. (Creator) & Baek, J.-B. (Creator), Cambridge Crystallographic Data Centre, Sep 2 2021
DOI: 10.5517/ccdc.csd.cc27y16g, http://hdl.handle.net/10754/686923
Dataset