Synthesis of organic photodimeric cage molecules based on cycloaddition via metal-ligand directed assembly

Jarrod Eubank; Victor Ch Kravtsov; Mohamed Eddaoudi

doi:10.1021/ja070924n

Synthesis of organic photodimeric cage molecules based on cycloaddition via metal-ligand directed assembly

Jarrod Eubank, Victor Ch Kravtsov, Mohamed Eddaoudi^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

92 Scopus citations

Abstract

Metal-ligand directed assembly of copper(II) ions and chelidonate (CDO) ligands into a metal-organic assembly has resulted in the proper orientation and positioning of CDO ligands for [2 + 2] photodimerization in the solid state. Upon exposure to ultraviolet light, pairs of adjacent CDO ligands photoreact via single-crystal-to-single-crystal cycloaddition to form novel cage dimers within the metal-organic assembly, which can be isolated successively as the organic sodium salt.

Original language	English (US)
Pages (from-to)	5820-5821
Number of pages	2
Journal	Journal of the American Chemical Society
Volume	129
Issue number	18
DOIs	https://doi.org/10.1021/ja070924n
State	Published - May 9 2007
Externally published	Yes

ASJC Scopus subject areas

Catalysis
General Chemistry
Biochemistry
Colloid and Surface Chemistry

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title = "Synthesis of organic photodimeric cage molecules based on cycloaddition via metal-ligand directed assembly",

abstract = "Metal-ligand directed assembly of copper(II) ions and chelidonate (CDO) ligands into a metal-organic assembly has resulted in the proper orientation and positioning of CDO ligands for [2 + 2] photodimerization in the solid state. Upon exposure to ultraviolet light, pairs of adjacent CDO ligands photoreact via single-crystal-to-single-crystal cycloaddition to form novel cage dimers within the metal-organic assembly, which can be isolated successively as the organic sodium salt.",

author = "Jarrod Eubank and Kravtsov, {Victor Ch} and Mohamed Eddaoudi",

year = "2007",

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language = "English (US)",

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AU - Eubank, Jarrod

AU - Kravtsov, Victor Ch

AU - Eddaoudi, Mohamed

PY - 2007/5/9

Y1 - 2007/5/9

N2 - Metal-ligand directed assembly of copper(II) ions and chelidonate (CDO) ligands into a metal-organic assembly has resulted in the proper orientation and positioning of CDO ligands for [2 + 2] photodimerization in the solid state. Upon exposure to ultraviolet light, pairs of adjacent CDO ligands photoreact via single-crystal-to-single-crystal cycloaddition to form novel cage dimers within the metal-organic assembly, which can be isolated successively as the organic sodium salt.

AB - Metal-ligand directed assembly of copper(II) ions and chelidonate (CDO) ligands into a metal-organic assembly has resulted in the proper orientation and positioning of CDO ligands for [2 + 2] photodimerization in the solid state. Upon exposure to ultraviolet light, pairs of adjacent CDO ligands photoreact via single-crystal-to-single-crystal cycloaddition to form novel cage dimers within the metal-organic assembly, which can be isolated successively as the organic sodium salt.

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U2 - 10.1021/ja070924n

DO - 10.1021/ja070924n

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Synthesis of organic photodimeric cage molecules based on cycloaddition via metal-ligand directed assembly

Abstract

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