Synthesis of novel bis(perfluorophenyl azides) coupling agents: Evaluation of their performance by crosslinking of poly(ethylene oxide)

Hakim Mehenni; Osman Bakr

doi:10.1016/j.reactfunctpolym.2011.07.011

Synthesis of novel bis(perfluorophenyl azides) coupling agents: Evaluation of their performance by crosslinking of poly(ethylene oxide)

Hakim Mehenni, Osman Bakr

Research output: Contribution to journal › Article › peer-review

3 Scopus citations

Abstract

Novel bis(perfluorophenyl azides) coupling agents, containing spacer arms from ethylene or ethylene glycol subunits, were successfully synthesized. Nitrenes photogenerated from these novel bis(PFPA) coupling agents were applied successfully to the cross-linking of poly(ethylene oxide) (PEO10,000) in either aqueous medium or at the solid state, thus, we demonstrated the potential of these bis(PFPA) molecules as promising coupling agents in surface engineering. © 2011 Elsevier Ltd. All rights reserved.

Original language	English (US)
Pages (from-to)	1110-1117
Number of pages	8
Journal	Reactive and Functional Polymers
Volume	71
Issue number	11
DOIs	https://doi.org/10.1016/j.reactfunctpolym.2011.07.011
State	Published - Nov 2011

Bibliographical note

KAUST Repository Item: Exported on 2020-10-01
Acknowledgements: This work was supported by a grant from the Wallonia region (Belgium) and King Abdullah University of Science and Technology (Saudi Arabia).

ASJC Scopus subject areas

Materials Chemistry
Biochemistry
Polymers and Plastics
Environmental Chemistry
General Chemical Engineering
General Chemistry

Access to Document

10.1016/j.reactfunctpolym.2011.07.011

Cite this

@article{742e6e2ba45a4833893071863dd734cb,

title = "Synthesis of novel bis(perfluorophenyl azides) coupling agents: Evaluation of their performance by crosslinking of poly(ethylene oxide)",

abstract = "Novel bis(perfluorophenyl azides) coupling agents, containing spacer arms from ethylene or ethylene glycol subunits, were successfully synthesized. Nitrenes photogenerated from these novel bis(PFPA) coupling agents were applied successfully to the cross-linking of poly(ethylene oxide) (PEO10,000) in either aqueous medium or at the solid state, thus, we demonstrated the potential of these bis(PFPA) molecules as promising coupling agents in surface engineering. {\textcopyright} 2011 Elsevier Ltd. All rights reserved.",

author = "Hakim Mehenni and Osman Bakr",

note = "KAUST Repository Item: Exported on 2020-10-01 Acknowledgements: This work was supported by a grant from the Wallonia region (Belgium) and King Abdullah University of Science and Technology (Saudi Arabia).",

year = "2011",

month = nov,

doi = "10.1016/j.reactfunctpolym.2011.07.011",

language = "English (US)",

volume = "71",

pages = "1110--1117",

journal = "Reactive and Functional Polymers",

issn = "1381-5148",

publisher = "Elsevier B.V.",

number = "11",

}

TY - JOUR

T1 - Synthesis of novel bis(perfluorophenyl azides) coupling agents: Evaluation of their performance by crosslinking of poly(ethylene oxide)

AU - Mehenni, Hakim

AU - Bakr, Osman

N1 - KAUST Repository Item: Exported on 2020-10-01 Acknowledgements: This work was supported by a grant from the Wallonia region (Belgium) and King Abdullah University of Science and Technology (Saudi Arabia).

PY - 2011/11

Y1 - 2011/11

N2 - Novel bis(perfluorophenyl azides) coupling agents, containing spacer arms from ethylene or ethylene glycol subunits, were successfully synthesized. Nitrenes photogenerated from these novel bis(PFPA) coupling agents were applied successfully to the cross-linking of poly(ethylene oxide) (PEO10,000) in either aqueous medium or at the solid state, thus, we demonstrated the potential of these bis(PFPA) molecules as promising coupling agents in surface engineering. © 2011 Elsevier Ltd. All rights reserved.

AB - Novel bis(perfluorophenyl azides) coupling agents, containing spacer arms from ethylene or ethylene glycol subunits, were successfully synthesized. Nitrenes photogenerated from these novel bis(PFPA) coupling agents were applied successfully to the cross-linking of poly(ethylene oxide) (PEO10,000) in either aqueous medium or at the solid state, thus, we demonstrated the potential of these bis(PFPA) molecules as promising coupling agents in surface engineering. © 2011 Elsevier Ltd. All rights reserved.

UR - http://hdl.handle.net/10754/561906

UR - https://linkinghub.elsevier.com/retrieve/pii/S1381514811001568

UR - http://www.scopus.com/inward/record.url?scp=80053559930&partnerID=8YFLogxK

U2 - 10.1016/j.reactfunctpolym.2011.07.011

DO - 10.1016/j.reactfunctpolym.2011.07.011

M3 - Article

SN - 1381-5148

VL - 71

SP - 1110

EP - 1117

JO - Reactive and Functional Polymers

JF - Reactive and Functional Polymers

IS - 11

ER -

Synthesis of novel bis(perfluorophenyl azides) coupling agents: Evaluation of their performance by crosslinking of poly(ethylene oxide)

Abstract

Bibliographical note

ASJC Scopus subject areas

Access to Document

Other files and links

Fingerprint

Cite this