Synthesis of Ni-SiO2/silicalite-1 core-shell micromembrane reactors and their reaction/diffusion performance

Easir A. Khan; Arvind Rajendran; Zhiping Lai

doi:10.1021/ie101850j

Synthesis of Ni-SiO2/silicalite-1 core-shell micromembrane reactors and their reaction/diffusion performance

Easir A. Khan, Arvind Rajendran, Zhiping Lai

Research output: Contribution to journal › Article › peer-review

13 Scopus citations

Abstract

Core-shell micromembrane reactors are a novel class of materials where a catalyst and a shape-selective membrane are synergistically housed in a single particle. In this work, we report the synthesis of micrometer -sized core-shell particles containing a catalyst core and a thin permselective zeolite shell and their application as a micromembrane reactor for the selective hydrogenation of the 1-hexene and 3,3-dimethyl-1-butene isomers. The bare catalyst, which is made from porous silica loaded with catalytically active nickel, showed no reactant selectivity between hexene isomers, but the core-shell particles showed high selectivities up to 300 for a 1-hexene conversion of 90%. © 2010 American Chemical Society.

Original language	English (US)
Pages (from-to)	12423-12428
Number of pages	6
Journal	Industrial & Engineering Chemistry Research
Volume	49
Issue number	24
DOIs	https://doi.org/10.1021/ie101850j
State	Published - Dec 15 2010

Bibliographical note

KAUST Repository Item: Exported on 2020-10-01
Acknowledgements: Financial supports provided by the NTU start-up funding M58120001 and AcRF tier-1 funding RG26/07, and KAUST distribution fund allocated to Z.P Lai are gratefully acknowledged

ASJC Scopus subject areas

General Chemical Engineering
General Chemistry
Industrial and Manufacturing Engineering

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10.1021/ie101850j

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title = "Synthesis of Ni-SiO2/silicalite-1 core-shell micromembrane reactors and their reaction/diffusion performance",

abstract = "Core-shell micromembrane reactors are a novel class of materials where a catalyst and a shape-selective membrane are synergistically housed in a single particle. In this work, we report the synthesis of micrometer -sized core-shell particles containing a catalyst core and a thin permselective zeolite shell and their application as a micromembrane reactor for the selective hydrogenation of the 1-hexene and 3,3-dimethyl-1-butene isomers. The bare catalyst, which is made from porous silica loaded with catalytically active nickel, showed no reactant selectivity between hexene isomers, but the core-shell particles showed high selectivities up to 300 for a 1-hexene conversion of 90%. {\textcopyright} 2010 American Chemical Society.",

author = "Khan, {Easir A.} and Arvind Rajendran and Zhiping Lai",

note = "KAUST Repository Item: Exported on 2020-10-01 Acknowledgements: Financial supports provided by the NTU start-up funding M58120001 and AcRF tier-1 funding RG26/07, and KAUST distribution fund allocated to Z.P Lai are gratefully acknowledged",

year = "2010",

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doi = "10.1021/ie101850j",

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journal = "Industrial & Engineering Chemistry Research",

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AU - Khan, Easir A.

AU - Rajendran, Arvind

AU - Lai, Zhiping

N1 - KAUST Repository Item: Exported on 2020-10-01 Acknowledgements: Financial supports provided by the NTU start-up funding M58120001 and AcRF tier-1 funding RG26/07, and KAUST distribution fund allocated to Z.P Lai are gratefully acknowledged

PY - 2010/12/15

Y1 - 2010/12/15

N2 - Core-shell micromembrane reactors are a novel class of materials where a catalyst and a shape-selective membrane are synergistically housed in a single particle. In this work, we report the synthesis of micrometer -sized core-shell particles containing a catalyst core and a thin permselective zeolite shell and their application as a micromembrane reactor for the selective hydrogenation of the 1-hexene and 3,3-dimethyl-1-butene isomers. The bare catalyst, which is made from porous silica loaded with catalytically active nickel, showed no reactant selectivity between hexene isomers, but the core-shell particles showed high selectivities up to 300 for a 1-hexene conversion of 90%. © 2010 American Chemical Society.

AB - Core-shell micromembrane reactors are a novel class of materials where a catalyst and a shape-selective membrane are synergistically housed in a single particle. In this work, we report the synthesis of micrometer -sized core-shell particles containing a catalyst core and a thin permselective zeolite shell and their application as a micromembrane reactor for the selective hydrogenation of the 1-hexene and 3,3-dimethyl-1-butene isomers. The bare catalyst, which is made from porous silica loaded with catalytically active nickel, showed no reactant selectivity between hexene isomers, but the core-shell particles showed high selectivities up to 300 for a 1-hexene conversion of 90%. © 2010 American Chemical Society.

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U2 - 10.1021/ie101850j

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SN - 0888-5885

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JO - Industrial & Engineering Chemistry Research

JF - Industrial & Engineering Chemistry Research

IS - 24

ER -

Synthesis of Ni-SiO2/silicalite-1 core-shell micromembrane reactors and their reaction/diffusion performance

Abstract

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ASJC Scopus subject areas

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