Synthesis of nanoporous 1,2,4-oxadiazole networks with high CO2 capture capacity

Dongah Ko; Hasmukh A. Patel; Cafer T. Yavuz

doi:10.1039/c4cc08649j

Synthesis of nanoporous 1,2,4-oxadiazole networks with high CO2 capture capacity

Dongah Ko, Hasmukh A. Patel, Cafer T. Yavuz

Research output: Contribution to journal › Article › peer-review

39 Scopus citations

Abstract

Developing an adsorbent to mitigate carbon dioxide without large energy penalty is highly desired. Here, we present a silylation synthetic route to form a processable and otherwise impossible porous 1,2,4-oxadiazole network, which achieves 2 mmol g-1 of CO2 capacity owing to a nitrogen-rich structure. This network shows high CO2-N2 selectivity, thermal stability up to 450 °C, and low heat of adsorption (26.4 kJ mol-1), facilitating easy regeneration.

Original language	English (US)
Pages (from-to)	2915-2917
Number of pages	3
Journal	Chemical Communications
Volume	51
Issue number	14
DOIs	https://doi.org/10.1039/c4cc08649j
State	Published - Feb 18 2015
Externally published	Yes

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abstract = "Developing an adsorbent to mitigate carbon dioxide without large energy penalty is highly desired. Here, we present a silylation synthetic route to form a processable and otherwise impossible porous 1,2,4-oxadiazole network, which achieves 2 mmol g-1 of CO2 capacity owing to a nitrogen-rich structure. This network shows high CO2-N2 selectivity, thermal stability up to 450 °C, and low heat of adsorption (26.4 kJ mol-1), facilitating easy regeneration.",

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AU - Ko, Dongah

AU - Patel, Hasmukh A.

AU - Yavuz, Cafer T.

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PY - 2015/2/18

Y1 - 2015/2/18

N2 - Developing an adsorbent to mitigate carbon dioxide without large energy penalty is highly desired. Here, we present a silylation synthetic route to form a processable and otherwise impossible porous 1,2,4-oxadiazole network, which achieves 2 mmol g-1 of CO2 capacity owing to a nitrogen-rich structure. This network shows high CO2-N2 selectivity, thermal stability up to 450 °C, and low heat of adsorption (26.4 kJ mol-1), facilitating easy regeneration.

AB - Developing an adsorbent to mitigate carbon dioxide without large energy penalty is highly desired. Here, we present a silylation synthetic route to form a processable and otherwise impossible porous 1,2,4-oxadiazole network, which achieves 2 mmol g-1 of CO2 capacity owing to a nitrogen-rich structure. This network shows high CO2-N2 selectivity, thermal stability up to 450 °C, and low heat of adsorption (26.4 kJ mol-1), facilitating easy regeneration.

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JF - Chemical Communications

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ER -

Synthesis of nanoporous 1,2,4-oxadiazole networks with high CO2 capture capacity

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