Synthesis of latex particles by ring-opening metathesis polymerization in dispersed medium

V. Heroguez; M. Fontanille; Y. Gnanou

doi:10.1002/1521-3900(200002)150:1<269::AID-MASY269>3.0.CO;2-I

Synthesis of latex particles by ring-opening metathesis polymerization in dispersed medium

V. Heroguez^*, M. Fontanille, Y. Gnanou

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

17 Scopus citations

Abstract

Colloidal particles of polyalkenamers were obtained by ring-opening metathesis polymerization of norbornene (NB) or cyclooctadiene (COD) in dichloromethane/methanol medium, using α-norbornenyl poly(ethylene oxide) macromonomer as steric stabilizer. The dispersions obtained were characterized by electron microscopy and dynamic light scattering. Depending upon the experimental conditions used, the size of these particles was found to range from 150 nm to 15 μm. In particular, the particle size was shown to decrease upon increasing the concentration and molar mass of the macromonomer. Beside these factors, it appears that the main parameter that governs the size of the particles formed is the ability of these macromonomers to randomly copolymerize with either NB or COD.

Original language	English (US)
Pages (from-to)	269-274
Number of pages	6
Journal	Macromolecular Symposia
Volume	150
DOIs	https://doi.org/10.1002/1521-3900(200002)150:1<269::AID-MASY269>3.0.CO;2-I
State	Published - 2000
Externally published	Yes

ASJC Scopus subject areas

Condensed Matter Physics
Organic Chemistry
Polymers and Plastics
Materials Chemistry

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10.1002/1521-3900(200002)150:1<269::AID-MASY269>3.0.CO;2-I

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title = "Synthesis of latex particles by ring-opening metathesis polymerization in dispersed medium",

abstract = "Colloidal particles of polyalkenamers were obtained by ring-opening metathesis polymerization of norbornene (NB) or cyclooctadiene (COD) in dichloromethane/methanol medium, using α-norbornenyl poly(ethylene oxide) macromonomer as steric stabilizer. The dispersions obtained were characterized by electron microscopy and dynamic light scattering. Depending upon the experimental conditions used, the size of these particles was found to range from 150 nm to 15 μm. In particular, the particle size was shown to decrease upon increasing the concentration and molar mass of the macromonomer. Beside these factors, it appears that the main parameter that governs the size of the particles formed is the ability of these macromonomers to randomly copolymerize with either NB or COD.",

author = "V. Heroguez and M. Fontanille and Y. Gnanou",

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doi = "10.1002/1521-3900(200002)150:1<269::AID-MASY269>3.0.CO;2-I",

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pages = "269--274",

journal = "Macromolecular Symposia",

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TY - JOUR

T1 - Synthesis of latex particles by ring-opening metathesis polymerization in dispersed medium

AU - Heroguez, V.

AU - Fontanille, M.

AU - Gnanou, Y.

PY - 2000

Y1 - 2000

N2 - Colloidal particles of polyalkenamers were obtained by ring-opening metathesis polymerization of norbornene (NB) or cyclooctadiene (COD) in dichloromethane/methanol medium, using α-norbornenyl poly(ethylene oxide) macromonomer as steric stabilizer. The dispersions obtained were characterized by electron microscopy and dynamic light scattering. Depending upon the experimental conditions used, the size of these particles was found to range from 150 nm to 15 μm. In particular, the particle size was shown to decrease upon increasing the concentration and molar mass of the macromonomer. Beside these factors, it appears that the main parameter that governs the size of the particles formed is the ability of these macromonomers to randomly copolymerize with either NB or COD.

AB - Colloidal particles of polyalkenamers were obtained by ring-opening metathesis polymerization of norbornene (NB) or cyclooctadiene (COD) in dichloromethane/methanol medium, using α-norbornenyl poly(ethylene oxide) macromonomer as steric stabilizer. The dispersions obtained were characterized by electron microscopy and dynamic light scattering. Depending upon the experimental conditions used, the size of these particles was found to range from 150 nm to 15 μm. In particular, the particle size was shown to decrease upon increasing the concentration and molar mass of the macromonomer. Beside these factors, it appears that the main parameter that governs the size of the particles formed is the ability of these macromonomers to randomly copolymerize with either NB or COD.

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DO - 10.1002/1521-3900(200002)150:1<269::AID-MASY269>3.0.CO;2-I

M3 - Article

AN - SCOPUS:0033653559

SN - 1022-1360

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EP - 274

JO - Macromolecular Symposia

JF - Macromolecular Symposia

ER -

Synthesis of latex particles by ring-opening metathesis polymerization in dispersed medium

Abstract

ASJC Scopus subject areas

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