Synthesis of α-norbornenylpoly(ethylene oxide) macromonomers and their ring-opening metathesis polymerization

Valérie Heroguez; Stefan Breunig; Yves Gnanou; Michel Fontanille

doi:10.1021/ma951797v

Synthesis of α-norbornenylpoly(ethylene oxide) macromonomers and their ring-opening metathesis polymerization

Valérie Heroguez, Stefan Breunig, Yves Gnanou^*, Michel Fontanille

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

83 Scopus citations

Abstract

This work focuses on the synthesis and the ring-opening metathesis polymerization of α-norbornenylpoly(ethylene oxide) macromonomers. Although obtained in 100% yield and with a narrow distribution of molar masses, the polymacromonomers exhibit degrees of polymerization that are systematically higher than expected. The reasons for this feature are thoroughly discussed.

Original language	English (US)
Pages (from-to)	4459-4464
Number of pages	6
Journal	Macromolecules
Volume	29
Issue number	13
DOIs	https://doi.org/10.1021/ma951797v
State	Published - Jan 1 1996
Externally published	Yes

ASJC Scopus subject areas

Materials Chemistry

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10.1021/ma951797v

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title = "Synthesis of α-norbornenylpoly(ethylene oxide) macromonomers and their ring-opening metathesis polymerization",

abstract = "This work focuses on the synthesis and the ring-opening metathesis polymerization of α-norbornenylpoly(ethylene oxide) macromonomers. Although obtained in 100% yield and with a narrow distribution of molar masses, the polymacromonomers exhibit degrees of polymerization that are systematically higher than expected. The reasons for this feature are thoroughly discussed.",

author = "Val{\'e}rie Heroguez and Stefan Breunig and Yves Gnanou and Michel Fontanille",

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AU - Heroguez, Valérie

AU - Breunig, Stefan

AU - Gnanou, Yves

AU - Fontanille, Michel

PY - 1996/1/1

Y1 - 1996/1/1

N2 - This work focuses on the synthesis and the ring-opening metathesis polymerization of α-norbornenylpoly(ethylene oxide) macromonomers. Although obtained in 100% yield and with a narrow distribution of molar masses, the polymacromonomers exhibit degrees of polymerization that are systematically higher than expected. The reasons for this feature are thoroughly discussed.

AB - This work focuses on the synthesis and the ring-opening metathesis polymerization of α-norbornenylpoly(ethylene oxide) macromonomers. Although obtained in 100% yield and with a narrow distribution of molar masses, the polymacromonomers exhibit degrees of polymerization that are systematically higher than expected. The reasons for this feature are thoroughly discussed.

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U2 - 10.1021/ma951797v

DO - 10.1021/ma951797v

M3 - Article

AN - SCOPUS:0030169851

SN - 0024-9297

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JO - Macromolecules

JF - Macromolecules

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ER -

Synthesis of α-norbornenylpoly(ethylene oxide) macromonomers and their ring-opening metathesis polymerization

Abstract

ASJC Scopus subject areas

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