Abstract
Herein we present the first example of a glycol-coordinated ε-Keggin Al13 chloride (gl-ε-Al13), which is the first chelated version since discovery of Al13 in 1960. The molecular structure consists of [AlO4Al12(OH)12(OC2H4OH)12]Cl7·H2O units with chelating mono-anionic ethylene glycol units replacing one bridging and one terminal oxygen site.
| Original language | English (US) |
|---|---|
| Pages (from-to) | 4148-4151 |
| Number of pages | 4 |
| Journal | Chemical Communications |
| Volume | 54 |
| Issue number | 33 |
| DOIs | |
| State | Published - 2018 |
Bibliographical note
KAUST Repository Item: Exported on 2020-10-01Acknowledgements: S. He thanks financial support from National Natural Science Foundation of China (No. 21206161). WHC acknowledges financial support by the NSF Phase-3 CCI, Center for Sustainable Materials Chemistry (NSF CHE-1606982). WHC and JCF thank the National Science Foundation (Grant CHE-1531193) for the dual-source X-ray diffractometer.
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CCDC 1813736: Experimental Crystal Structure Determination : tetrakis(mu-oxido)-dodecakis(mu-2-hydroxyethan-1-olato)-dodecakis(mu-hydroxo)-trideca-aluminium(iii) heptakis(chloride) monohydrate unknown solvate
Gu, B. (Creator), Sun, C. (Creator), Fettinger, J. C. (Creator), Casey, W. H. (Creator), Dikhtiarenko, A. (Creator), Gascon, J. (Creator), Koichumanova, K. (Creator), Babu Sai Sankar Gupta, K. (Creator), Jan Heeres, H. (Creator), He, S. (Creator), Gu, B. (Creator), Sun, C. (Creator), Fettinger, J. C. (Creator), Casey, W. H. (Creator), Koichumanova, K. (Creator), Babu Sai Sankar Gupta, K. (Creator), Jan Heeres, H. (Creator) & He, S. (Creator), Cambridge Crystallographic Data Centre, Apr 6 2018
DOI: 10.5517/ccdc.csd.cc1ywbms, http://hdl.handle.net/10754/664057
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