Synthesis, characterization and propane metathesis activity of a tantalum-hydride prepared on high surface area "silica supported zirconium hydroxide"

Franck Rataboul; Christophe Copéret; Laurent Lefort; Aimery De Mallmann; Jean Thivolle-Cazat; Jean Marie Basset

doi:10.1039/b616921j

Synthesis, characterization and propane metathesis activity of a tantalum-hydride prepared on high surface area "silica supported zirconium hydroxide"

Franck Rataboul^*, Christophe Copéret, Laurent Lefort, Aimery De Mallmann, Jean Thivolle-Cazat, Jean Marie Basset

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

11 Scopus citations

Abstract

A new tantalum-hydride supported on zirconium hydroxide [(SiO) ₂Zr(H)-O-Ta(H)_x-(OSi)] (x = 1 or 3) was prepared using surface organometallic chemistry and its catalytic properties in the propane metathesis reaction were assessed showing improved activity and selectivities in comparison to the tantalum-hydride supported on silica.

Original language	English (US)
Pages (from-to)	923-927
Number of pages	5
Journal	Dalton transactions
Issue number	9
DOIs	https://doi.org/10.1039/b616921j
State	Published - 2007
Externally published	Yes

Bibliographical note

Funding Information:
Program Directors under contract with the Center for Mental Health Services (DMHS), Substance Abuse and Mental Health Services Administration (SAMHSA), and the US Department of Health and Human Services (HHS).

ASJC Scopus subject areas

Inorganic Chemistry

Access to Document

10.1039/b616921j

Cite this

@article{67e18d6bd48449b6b3cc00099ebab3b4,

title = "Synthesis, characterization and propane metathesis activity of a tantalum-hydride prepared on high surface area {"}silica supported zirconium hydroxide{"}",

abstract = "A new tantalum-hydride supported on zirconium hydroxide [(SiO) 2Zr(H)-O-Ta(H)x-(OSi)] (x = 1 or 3) was prepared using surface organometallic chemistry and its catalytic properties in the propane metathesis reaction were assessed showing improved activity and selectivities in comparison to the tantalum-hydride supported on silica.",

author = "Franck Rataboul and Christophe Cop{\'e}ret and Laurent Lefort and {De Mallmann}, Aimery and Jean Thivolle-Cazat and Basset, {Jean Marie}",

note = "Funding Information: Program Directors under contract with the Center for Mental Health Services (DMHS), Substance Abuse and Mental Health Services Administration (SAMHSA), and the US Department of Health and Human Services (HHS).",

year = "2007",

doi = "10.1039/b616921j",

language = "English (US)",

pages = "923--927",

journal = "Dalton transactions",

issn = "1477-9226",

publisher = "Royal Society of Chemistry",

number = "9",

}

TY - JOUR

T1 - Synthesis, characterization and propane metathesis activity of a tantalum-hydride prepared on high surface area "silica supported zirconium hydroxide"

AU - Rataboul, Franck

AU - Copéret, Christophe

AU - Lefort, Laurent

AU - De Mallmann, Aimery

AU - Thivolle-Cazat, Jean

AU - Basset, Jean Marie

N1 - Funding Information: Program Directors under contract with the Center for Mental Health Services (DMHS), Substance Abuse and Mental Health Services Administration (SAMHSA), and the US Department of Health and Human Services (HHS).

PY - 2007

Y1 - 2007

N2 - A new tantalum-hydride supported on zirconium hydroxide [(SiO) 2Zr(H)-O-Ta(H)x-(OSi)] (x = 1 or 3) was prepared using surface organometallic chemistry and its catalytic properties in the propane metathesis reaction were assessed showing improved activity and selectivities in comparison to the tantalum-hydride supported on silica.

AB - A new tantalum-hydride supported on zirconium hydroxide [(SiO) 2Zr(H)-O-Ta(H)x-(OSi)] (x = 1 or 3) was prepared using surface organometallic chemistry and its catalytic properties in the propane metathesis reaction were assessed showing improved activity and selectivities in comparison to the tantalum-hydride supported on silica.

UR - http://www.scopus.com/inward/record.url?scp=33847221819&partnerID=8YFLogxK

U2 - 10.1039/b616921j

DO - 10.1039/b616921j

M3 - Article

AN - SCOPUS:33847221819

SN - 1477-9226

SP - 923

EP - 927

JO - Dalton transactions

JF - Dalton transactions

IS - 9

ER -

Synthesis, characterization and propane metathesis activity of a tantalum-hydride prepared on high surface area "silica supported zirconium hydroxide"

Abstract

Bibliographical note

ASJC Scopus subject areas

Access to Document

Other files and links

Fingerprint

Cite this