Synthesis, characterization and catalytic activity of stable [(NHC)H][ZnXY2] (NHC=N-Heterocyclic carbene, X, Y=Cl, Br) species

Orlando Santoro; Fady Nahra; David B. Cordes; Alexandra M.Z. Slawin; Steven P. Nolan; Catherine S. J. Cazin

doi:10.1016/j.molcata.2016.05.031

Synthesis, characterization and catalytic activity of stable [(NHC)H][ZnXY2] (NHC=N-Heterocyclic carbene, X, Y=Cl, Br) species

Orlando Santoro, Fady Nahra, David B. Cordes, Alexandra M.Z. Slawin, Steven P. Nolan, Catherine S. J. Cazin

Research output: Contribution to journal › Article › peer-review

11 Scopus citations

Abstract

The synthesis and characterization of imidazol(in)ium-based zinc(II) halide salts are reported. These compounds present interesting structural features and exhibit high stability. Their catalytic activity was explored in the methylation of amines with CO2 and PhSiH3.

Original language	English (US)
Pages (from-to)	85-91
Number of pages	7
Journal	Journal of Molecular Catalysis A: Chemical
Volume	423
DOIs	https://doi.org/10.1016/j.molcata.2016.05.031
State	Published - Jun 4 2016
Externally published	Yes

Bibliographical note

KAUST Repository Item: Exported on 2020-10-01
Acknowledged KAUST grant number(s): OSR-2015-CCF-1974-03
Acknowledgements: The authors gratefully acknowledge the Royal Society (University Research Fellowship to C.S.J.C) and the EPSRC (EP/J500549/1, EP/K00445X/1) for funding. S.P.N. acknowledges support from KSU.This publication is based upon some work supported by the King Abdullah University of Science and Technology (KAUST) Office of Sponsored Research (OSR) under Award No. OSR-2015-CCF-1974-03.
This publication acknowledges KAUST support, but has no KAUST affiliated authors.

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10.1016/j.molcata.2016.05.031

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title = "Synthesis, characterization and catalytic activity of stable [(NHC)H][ZnXY2] (NHC=N-Heterocyclic carbene, X, Y=Cl, Br) species",

abstract = "The synthesis and characterization of imidazol(in)ium-based zinc(II) halide salts are reported. These compounds present interesting structural features and exhibit high stability. Their catalytic activity was explored in the methylation of amines with CO2 and PhSiH3.",

author = "Orlando Santoro and Fady Nahra and Cordes, {David B.} and Slawin, {Alexandra M.Z.} and Nolan, {Steven P.} and Cazin, {Catherine S. J.}",

note = "KAUST Repository Item: Exported on 2020-10-01 Acknowledged KAUST grant number(s): OSR-2015-CCF-1974-03 Acknowledgements: The authors gratefully acknowledge the Royal Society (University Research Fellowship to C.S.J.C) and the EPSRC (EP/J500549/1, EP/K00445X/1) for funding. S.P.N. acknowledges support from KSU.This publication is based upon some work supported by the King Abdullah University of Science and Technology (KAUST) Office of Sponsored Research (OSR) under Award No. OSR-2015-CCF-1974-03. This publication acknowledges KAUST support, but has no KAUST affiliated authors.",

year = "2016",

month = jun,

day = "4",

doi = "10.1016/j.molcata.2016.05.031",

language = "English (US)",

volume = "423",

pages = "85--91",

journal = "Journal of Molecular Catalysis A: Chemical",

issn = "1381-1169",

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TY - JOUR

T1 - Synthesis, characterization and catalytic activity of stable [(NHC)H][ZnXY2] (NHC=N-Heterocyclic carbene, X, Y=Cl, Br) species

AU - Santoro, Orlando

AU - Nahra, Fady

AU - Cordes, David B.

AU - Slawin, Alexandra M.Z.

AU - Nolan, Steven P.

AU - Cazin, Catherine S. J.

N1 - KAUST Repository Item: Exported on 2020-10-01 Acknowledged KAUST grant number(s): OSR-2015-CCF-1974-03 Acknowledgements: The authors gratefully acknowledge the Royal Society (University Research Fellowship to C.S.J.C) and the EPSRC (EP/J500549/1, EP/K00445X/1) for funding. S.P.N. acknowledges support from KSU.This publication is based upon some work supported by the King Abdullah University of Science and Technology (KAUST) Office of Sponsored Research (OSR) under Award No. OSR-2015-CCF-1974-03. This publication acknowledges KAUST support, but has no KAUST affiliated authors.

PY - 2016/6/4

Y1 - 2016/6/4

N2 - The synthesis and characterization of imidazol(in)ium-based zinc(II) halide salts are reported. These compounds present interesting structural features and exhibit high stability. Their catalytic activity was explored in the methylation of amines with CO2 and PhSiH3.

AB - The synthesis and characterization of imidazol(in)ium-based zinc(II) halide salts are reported. These compounds present interesting structural features and exhibit high stability. Their catalytic activity was explored in the methylation of amines with CO2 and PhSiH3.

UR - http://hdl.handle.net/10754/623602

UR - https://linkinghub.elsevier.com/retrieve/pii/S1381116916302138

UR - http://www.scopus.com/inward/record.url?scp=84975789739&partnerID=8YFLogxK

U2 - 10.1016/j.molcata.2016.05.031

DO - 10.1016/j.molcata.2016.05.031

M3 - Article

SN - 1381-1169

VL - 423

SP - 85

EP - 91

JO - Journal of Molecular Catalysis A: Chemical

JF - Journal of Molecular Catalysis A: Chemical

ER -

Synthesis, characterization and catalytic activity of stable [(NHC)H][ZnXY2] (NHC=N-Heterocyclic carbene, X, Y=Cl, Br) species

Abstract

Bibliographical note

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