Synthesis by metathesis. II. Kinetics of metathesis of ω-arylolefins

Paul Chevalier; Denis Sinou; Gerard Descotes; Robert Mutin; Jean Basset

doi:10.1016/S0022-328X(00)91755-8

Synthesis by metathesis. II. Kinetics of metathesis of ω-arylolefins

Paul Chevalier^*, Denis Sinou, Gerard Descotes, Robert Mutin, Jean Basset

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

18 Scopus citations

Abstract

Kinetic studies of metathesis of ω-arylolefins have been performed with two types of catalytic systems derived from molybdenum and tungsten. The effect of the structure of these olefins on their reactivity has been studied in terms of three variables: length of the chain between the aromatic ring and the double bond, substituent effects at the double bond, and substituent effects on the aromatic ring. The results are discussed in terms of a "one carbene" exchange mechanism, on the basis of steric and electronic effects of the olefin.

Original language	English (US)
Pages (from-to)	1-9
Number of pages	9
Journal	Journal of Organometallic Chemistry
Volume	113
Issue number	1
DOIs	https://doi.org/10.1016/S0022-328X(00)91755-8
State	Published - Jun 15 1976
Externally published	Yes

ASJC Scopus subject areas

Biochemistry
Physical and Theoretical Chemistry
Organic Chemistry
Inorganic Chemistry
Materials Chemistry

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10.1016/S0022-328X(00)91755-8

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abstract = "Kinetic studies of metathesis of ω-arylolefins have been performed with two types of catalytic systems derived from molybdenum and tungsten. The effect of the structure of these olefins on their reactivity has been studied in terms of three variables: length of the chain between the aromatic ring and the double bond, substituent effects at the double bond, and substituent effects on the aromatic ring. The results are discussed in terms of a {"}one carbene{"} exchange mechanism, on the basis of steric and electronic effects of the olefin.",

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AU - Chevalier, Paul

AU - Sinou, Denis

AU - Descotes, Gerard

AU - Mutin, Robert

AU - Basset, Jean

PY - 1976/6/15

Y1 - 1976/6/15

N2 - Kinetic studies of metathesis of ω-arylolefins have been performed with two types of catalytic systems derived from molybdenum and tungsten. The effect of the structure of these olefins on their reactivity has been studied in terms of three variables: length of the chain between the aromatic ring and the double bond, substituent effects at the double bond, and substituent effects on the aromatic ring. The results are discussed in terms of a "one carbene" exchange mechanism, on the basis of steric and electronic effects of the olefin.

AB - Kinetic studies of metathesis of ω-arylolefins have been performed with two types of catalytic systems derived from molybdenum and tungsten. The effect of the structure of these olefins on their reactivity has been studied in terms of three variables: length of the chain between the aromatic ring and the double bond, substituent effects at the double bond, and substituent effects on the aromatic ring. The results are discussed in terms of a "one carbene" exchange mechanism, on the basis of steric and electronic effects of the olefin.

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Synthesis by metathesis. II. Kinetics of metathesis of ω-arylolefins

Abstract

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