Synthesis and structures of two new coordination polymers formed by large polyoxometalate fragments and lanthanide cations

N. V. Izarova; M. N. Sokolov; D. G. Samsonenko; A. Rothenberger; D. Fenske; V. P. Fedin

doi:10.1007/s11172-008-0011-1

Synthesis and structures of two new coordination polymers formed by large polyoxometalate fragments and lanthanide cations

N. V. Izarova, M. N. Sokolov, D. G. Samsonenko, A. Rothenberger, D. Fenske, V. P. Fedin

Research output: Contribution to journal › Article › peer-review

6 Scopus citations

Abstract

The reactions of the polyoxometalate [Mo₃₆O₁₀₈(NO) ₄(H₂O)₁₆]^12- with EuCl ₃• 6H₂O and Tm₂(SO₄) ₃ • 8H₂O afford the coordination polymers with the following composition: (H₃O)_3.67{Eu(H₂O) ₄}{Eu(H₂O)₆}₂ {Mo ₃₆(NO)₄O₁₀₈(H₂O)₁₆)} Cl_0.67 • 29.5H₂O and (H₃O) ₅[{Tm(H₂O)₆}₂{Tm(H ₂O)₄} {Mo₃₆(NO)₄ O ₁₀₈(H₂O)₁₆}]Cl₂ • 45H ₂O, respectively, in which the polyoxometalate fragments are linked to each other by lanthanide cations to form infinite chains.

Original language	English (US)
Pages (from-to)	78-82
Number of pages	5
Journal	Russian Chemical Bulletin
Volume	57
Issue number	1
DOIs	https://doi.org/10.1007/s11172-008-0011-1
State	Published - Jan 2008
Externally published	Yes

Keywords

Coordination polymers
Crystal structure
Lanthanides
Molybdenum
Polyoxometalates

ASJC Scopus subject areas

General Chemistry

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@article{5cda001b3a96491eb69ef6440f23f127,

title = "Synthesis and structures of two new coordination polymers formed by large polyoxometalate fragments and lanthanide cations",

abstract = "The reactions of the polyoxometalate [Mo36O108(NO) 4(H2O)16]12- with EuCl 3• 6H2O and Tm2(SO4) 3 • 8H2O afford the coordination polymers with the following composition: (H3O)3.67{Eu(H2O) 4}{Eu(H2O)6}2 {Mo 36(NO)4O108(H2O)16)} Cl0.67 • 29.5H2O and (H3O) 5[{Tm(H2O)6}2{Tm(H 2O)4} {Mo36(NO)4 O 108(H2O)16}]Cl2 • 45H 2O, respectively, in which the polyoxometalate fragments are linked to each other by lanthanide cations to form infinite chains.",

keywords = "Coordination polymers, Crystal structure, Lanthanides, Molybdenum, Polyoxometalates",

author = "Izarova, {N. V.} and Sokolov, {M. N.} and Samsonenko, {D. G.} and A. Rothenberger and D. Fenske and Fedin, {V. P.}",

year = "2008",

month = jan,

doi = "10.1007/s11172-008-0011-1",

language = "English (US)",

volume = "57",

pages = "78--82",

journal = "Russian Chemical Bulletin",

issn = "1066-5285",

publisher = "Springer New York",

number = "1",

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TY - JOUR

T1 - Synthesis and structures of two new coordination polymers formed by large polyoxometalate fragments and lanthanide cations

AU - Izarova, N. V.

AU - Sokolov, M. N.

AU - Samsonenko, D. G.

AU - Rothenberger, A.

AU - Fenske, D.

AU - Fedin, V. P.

PY - 2008/1

Y1 - 2008/1

N2 - The reactions of the polyoxometalate [Mo36O108(NO) 4(H2O)16]12- with EuCl 3• 6H2O and Tm2(SO4) 3 • 8H2O afford the coordination polymers with the following composition: (H3O)3.67{Eu(H2O) 4}{Eu(H2O)6}2 {Mo 36(NO)4O108(H2O)16)} Cl0.67 • 29.5H2O and (H3O) 5[{Tm(H2O)6}2{Tm(H 2O)4} {Mo36(NO)4 O 108(H2O)16}]Cl2 • 45H 2O, respectively, in which the polyoxometalate fragments are linked to each other by lanthanide cations to form infinite chains.

AB - The reactions of the polyoxometalate [Mo36O108(NO) 4(H2O)16]12- with EuCl 3• 6H2O and Tm2(SO4) 3 • 8H2O afford the coordination polymers with the following composition: (H3O)3.67{Eu(H2O) 4}{Eu(H2O)6}2 {Mo 36(NO)4O108(H2O)16)} Cl0.67 • 29.5H2O and (H3O) 5[{Tm(H2O)6}2{Tm(H 2O)4} {Mo36(NO)4 O 108(H2O)16}]Cl2 • 45H 2O, respectively, in which the polyoxometalate fragments are linked to each other by lanthanide cations to form infinite chains.

KW - Coordination polymers

KW - Crystal structure

KW - Lanthanides

KW - Molybdenum

KW - Polyoxometalates

UR - http://www.scopus.com/inward/record.url?scp=58149528002&partnerID=8YFLogxK

U2 - 10.1007/s11172-008-0011-1

DO - 10.1007/s11172-008-0011-1

M3 - Article

AN - SCOPUS:58149528002

SN - 1066-5285

VL - 57

SP - 78

EP - 82

JO - Russian Chemical Bulletin

JF - Russian Chemical Bulletin

IS - 1

ER -

Synthesis and structures of two new coordination polymers formed by large polyoxometalate fragments and lanthanide cations

Abstract

Keywords

ASJC Scopus subject areas

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