Synthesis and structures of metallated N-heterocyclic derivatives

Lukasz Ponikiewski; Weifeng Shi; Alexander Rothenberger

doi:10.1002/zaac.200800044

Synthesis and structures of metallated N-heterocyclic derivatives

Lukasz Ponikiewski, Weifeng Shi, Alexander Rothenberger^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

4 Scopus citations

Abstract

The synthesis and structures of five new compounds are reported. [Mg(6-Oq)₂(phen)₂] (1), [Na(phen)₃][(6-HOq)(6- Oq)] (2), 1/∞[Cu(3-Opy)(3-HOpy)₂(PPh₃)]∞ (3), 1/∞[Cu₂{μ-(6-Oq)}(PPh₃)₂]∞ (4) and [Cu₂(pht)₂(μ-dppm)₂] (5) (6-HOq = 6-hydroxyquinoline; phen = 1,10-phenanthroline, 3-HOpy = 3-hydroxypyridine; Hpht = phthalimide; dppm = bis-(diphenylphosphino)methane) were prepared by deprotonation of N-heterocyclic aromatic compounds with metal alkoxides. 1-5 represent useful starting materials for investigating the supramolecular cordination chemistry of organic anhydrides.

Original language	English (US)
Pages (from-to)	1770-1774
Number of pages	5
Journal	Zeitschrift fur Anorganische und Allgemeine Chemie
Volume	634
Issue number	10
DOIs	https://doi.org/10.1002/zaac.200800044
State	Published - Aug 2008
Externally published	Yes

Keywords

Coordination polymers
Copper
Hydrogen bonding
Metal alkoxides
Supramolecular chemistry

ASJC Scopus subject areas

Inorganic Chemistry

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10.1002/zaac.200800044

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@article{02de789530724755a5fbadc0afe6664d,

title = "Synthesis and structures of metallated N-heterocyclic derivatives",

abstract = "The synthesis and structures of five new compounds are reported. [Mg(6-Oq)2(phen)2] (1), [Na(phen)3][(6-HOq)(6- Oq)] (2), 1/∞[Cu(3-Opy)(3-HOpy)2(PPh3)]∞ (3), 1/∞[Cu2{μ-(6-Oq)}(PPh3)2]∞ (4) and [Cu2(pht)2(μ-dppm)2] (5) (6-HOq = 6-hydroxyquinoline; phen = 1,10-phenanthroline, 3-HOpy = 3-hydroxypyridine; Hpht = phthalimide; dppm = bis-(diphenylphosphino)methane) were prepared by deprotonation of N-heterocyclic aromatic compounds with metal alkoxides. 1-5 represent useful starting materials for investigating the supramolecular cordination chemistry of organic anhydrides.",

keywords = "Coordination polymers, Copper, Hydrogen bonding, Metal alkoxides, Supramolecular chemistry",

author = "Lukasz Ponikiewski and Weifeng Shi and Alexander Rothenberger",

year = "2008",

month = aug,

doi = "10.1002/zaac.200800044",

language = "English (US)",

volume = "634",

pages = "1770--1774",

journal = "Zeitschrift fur Anorganische und Allgemeine Chemie",

issn = "0044-2313",

publisher = "Wiley",

number = "10",

}

TY - JOUR

T1 - Synthesis and structures of metallated N-heterocyclic derivatives

AU - Ponikiewski, Lukasz

AU - Shi, Weifeng

AU - Rothenberger, Alexander

PY - 2008/8

Y1 - 2008/8

N2 - The synthesis and structures of five new compounds are reported. [Mg(6-Oq)2(phen)2] (1), [Na(phen)3][(6-HOq)(6- Oq)] (2), 1/∞[Cu(3-Opy)(3-HOpy)2(PPh3)]∞ (3), 1/∞[Cu2{μ-(6-Oq)}(PPh3)2]∞ (4) and [Cu2(pht)2(μ-dppm)2] (5) (6-HOq = 6-hydroxyquinoline; phen = 1,10-phenanthroline, 3-HOpy = 3-hydroxypyridine; Hpht = phthalimide; dppm = bis-(diphenylphosphino)methane) were prepared by deprotonation of N-heterocyclic aromatic compounds with metal alkoxides. 1-5 represent useful starting materials for investigating the supramolecular cordination chemistry of organic anhydrides.

AB - The synthesis and structures of five new compounds are reported. [Mg(6-Oq)2(phen)2] (1), [Na(phen)3][(6-HOq)(6- Oq)] (2), 1/∞[Cu(3-Opy)(3-HOpy)2(PPh3)]∞ (3), 1/∞[Cu2{μ-(6-Oq)}(PPh3)2]∞ (4) and [Cu2(pht)2(μ-dppm)2] (5) (6-HOq = 6-hydroxyquinoline; phen = 1,10-phenanthroline, 3-HOpy = 3-hydroxypyridine; Hpht = phthalimide; dppm = bis-(diphenylphosphino)methane) were prepared by deprotonation of N-heterocyclic aromatic compounds with metal alkoxides. 1-5 represent useful starting materials for investigating the supramolecular cordination chemistry of organic anhydrides.

KW - Coordination polymers

KW - Copper

KW - Hydrogen bonding

KW - Metal alkoxides

KW - Supramolecular chemistry

UR - http://www.scopus.com/inward/record.url?scp=53849126108&partnerID=8YFLogxK

U2 - 10.1002/zaac.200800044

DO - 10.1002/zaac.200800044

M3 - Article

AN - SCOPUS:53849126108

SN - 0044-2313

VL - 634

SP - 1770

EP - 1774

JO - Zeitschrift fur Anorganische und Allgemeine Chemie

JF - Zeitschrift fur Anorganische und Allgemeine Chemie

IS - 10

ER -

Synthesis and structures of metallated N-heterocyclic derivatives

Abstract

Keywords

ASJC Scopus subject areas

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