Synthesis and structure of [{Sb(μ-NCy)}2(μ-N)]3(Li·THF)3- (LiN=NH), containing a macrocyclic [{Sb(μ-NCy)}2N]33- trianion

Felipe García; David J. Linton; Mary McPartlin; Alexander Rothenberger; Andrew E.H. Wheatley; Dominic S. Wright

doi:10.1039/b110984g

Synthesis and structure of [{Sb(μ-NCy)}₂(μ-N)]₃(Li·THF)₃- (LiN=NH), containing a macrocyclic [{Sb(μ-NCy)}₂N]₃^3- trianion

Felipe García, David J. Linton, Mary McPartlin, Alexander Rothenberger, Andrew E.H. Wheatley, Dominic S. Wright^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

10 Scopus citations

Abstract

Reaction of the Sb(III) dimer [Me₂NSb(μ-NCy)]₂ with Li-NH₂ (1:2 equivalents, respectively) gives [{Sb(μ-NCy)}₂N]₃-(Li·THF)₃ (LiN=NH)·0.25(dioxane) 4, in which four Li⁺ cations are coordinated within the trimeric cavity of the macrocyclic trianion [{Sb(μ-NCy)}₂N]₃^3-.

Original language	English (US)
Pages (from-to)	481-483
Number of pages	3
Journal	Journal of the Chemical Society, Dalton Transactions
Issue number	4
DOIs	https://doi.org/10.1039/b110984g
State	Published - 2002
Externally published	Yes

ASJC Scopus subject areas

General Chemistry

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@article{8c32d13e23c143a7acc0580622079243,

title = "Synthesis and structure of [{Sb(μ-NCy)}2(μ-N)]3(Li·THF)3- (LiN=NH), containing a macrocyclic [{Sb(μ-NCy)}2N]33- trianion",

abstract = "Reaction of the Sb(III) dimer [Me2NSb(μ-NCy)]2 with Li-NH2 (1:2 equivalents, respectively) gives [{Sb(μ-NCy)}2N]3-(Li·THF)3 (LiN=NH)·0.25(dioxane) 4, in which four Li+ cations are coordinated within the trimeric cavity of the macrocyclic trianion [{Sb(μ-NCy)}2N]33-.",

author = "Felipe Garc{\'i}a and Linton, {David J.} and Mary McPartlin and Alexander Rothenberger and Wheatley, {Andrew E.H.} and Wright, {Dominic S.}",

year = "2002",

doi = "10.1039/b110984g",

language = "English (US)",

pages = "481--483",

journal = "Journal of the Chemical Society, Dalton Transactions",

issn = "1470-479X",

publisher = "Royal Society of Chemistry",

number = "4",

}

TY - JOUR

T1 - Synthesis and structure of [{Sb(μ-NCy)}2(μ-N)]3(Li·THF)3- (LiN=NH), containing a macrocyclic [{Sb(μ-NCy)}2N]33- trianion

AU - García, Felipe

AU - Linton, David J.

AU - McPartlin, Mary

AU - Rothenberger, Alexander

AU - Wheatley, Andrew E.H.

AU - Wright, Dominic S.

PY - 2002

Y1 - 2002

N2 - Reaction of the Sb(III) dimer [Me2NSb(μ-NCy)]2 with Li-NH2 (1:2 equivalents, respectively) gives [{Sb(μ-NCy)}2N]3-(Li·THF)3 (LiN=NH)·0.25(dioxane) 4, in which four Li+ cations are coordinated within the trimeric cavity of the macrocyclic trianion [{Sb(μ-NCy)}2N]33-.

AB - Reaction of the Sb(III) dimer [Me2NSb(μ-NCy)]2 with Li-NH2 (1:2 equivalents, respectively) gives [{Sb(μ-NCy)}2N]3-(Li·THF)3 (LiN=NH)·0.25(dioxane) 4, in which four Li+ cations are coordinated within the trimeric cavity of the macrocyclic trianion [{Sb(μ-NCy)}2N]33-.

UR - http://www.scopus.com/inward/record.url?scp=0036008062&partnerID=8YFLogxK

U2 - 10.1039/b110984g

DO - 10.1039/b110984g

M3 - Article

AN - SCOPUS:0036008062

SN - 1470-479X

SP - 481

EP - 483

JO - Journal of the Chemical Society, Dalton Transactions

JF - Journal of the Chemical Society, Dalton Transactions

IS - 4

ER -

Synthesis and structure of [{Sb(μ-NCy)}₂(μ-N)]₃(Li·THF)₃- (LiN=NH), containing a macrocyclic [{Sb(μ-NCy)}₂N]₃^3- trianion

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