Synthesis and structure of chiral coordination polymers of CoII, CuII, and MgII saccharates

M. S. Zavakhina; D. G. Samsonenko; D. N. Dybtsev; M. P. Yutkin; A. V. Virovets; V. P. Fedin

doi:10.1007/s11172-013-0098-x

Synthesis and structure of chiral coordination polymers of Co^II, Cu^II, and Mg^II saccharates

M. S. Zavakhina, D. G. Samsonenko, D. N. Dybtsev, M. P. Yutkin, A. V. Virovets, V. P. Fedin

Research output: Contribution to journal › Article › peer-review

4 Scopus citations

Abstract

Chiral metal-organic coordination polymers [Co₂(sacch) ₂]·1/₂H₂O·CH₃OH (1), [Cu(sacch)(H₂O)₂]·3H₂O (2), and [Mg(H₂O)₃(sacch)] (3) (H₂sacch is d-saccharic acid) were synthesized from aqueous or water-methanol solutions of potassium hydrogen saccharate and a salt of the corresponding metal. The compositions and structures of the resulting compounds were determined by single-crystal X-ray diffraction and confirmed by X-ray powder diffraction, IR spectroscopy, thermogravimetry, and elemental analysis.

Original language	English (US)
Pages (from-to)	716-721
Number of pages	6
Journal	Russian Chemical Bulletin
Volume	62
Issue number	3
DOIs	https://doi.org/10.1007/s11172-013-0098-x
State	Published - Mar 2013
Externally published	Yes

Keywords

X-ray diffraction
chiral complexes
cobalt(ii) complexes
coordination polymers
copper(ii) complexes
magnesium complexes
saccharic acid

ASJC Scopus subject areas

General Chemistry

Access to Document

10.1007/s11172-013-0098-x

Cite this

@article{287c355a88cc4d31954ead928d59fc99,

title = "Synthesis and structure of chiral coordination polymers of CoII, CuII, and MgII saccharates",

abstract = "Chiral metal-organic coordination polymers [Co2(sacch) 2]·1/2H2O·CH3OH (1), [Cu(sacch)(H2O)2]·3H2O (2), and [Mg(H2O)3(sacch)] (3) (H2sacch is d-saccharic acid) were synthesized from aqueous or water-methanol solutions of potassium hydrogen saccharate and a salt of the corresponding metal. The compositions and structures of the resulting compounds were determined by single-crystal X-ray diffraction and confirmed by X-ray powder diffraction, IR spectroscopy, thermogravimetry, and elemental analysis.",

keywords = "X-ray diffraction, chiral complexes, cobalt(ii) complexes, coordination polymers, copper(ii) complexes, magnesium complexes, saccharic acid",

author = "Zavakhina, {M. S.} and Samsonenko, {D. G.} and Dybtsev, {D. N.} and Yutkin, {M. P.} and Virovets, {A. V.} and Fedin, {V. P.}",

year = "2013",

month = mar,

doi = "10.1007/s11172-013-0098-x",

language = "English (US)",

volume = "62",

pages = "716--721",

journal = "Russian Chemical Bulletin",

issn = "1066-5285",

publisher = "Springer New York",

number = "3",

}

TY - JOUR

T1 - Synthesis and structure of chiral coordination polymers of CoII, CuII, and MgII saccharates

AU - Zavakhina, M. S.

AU - Samsonenko, D. G.

AU - Dybtsev, D. N.

AU - Yutkin, M. P.

AU - Virovets, A. V.

AU - Fedin, V. P.

PY - 2013/3

Y1 - 2013/3

N2 - Chiral metal-organic coordination polymers [Co2(sacch) 2]·1/2H2O·CH3OH (1), [Cu(sacch)(H2O)2]·3H2O (2), and [Mg(H2O)3(sacch)] (3) (H2sacch is d-saccharic acid) were synthesized from aqueous or water-methanol solutions of potassium hydrogen saccharate and a salt of the corresponding metal. The compositions and structures of the resulting compounds were determined by single-crystal X-ray diffraction and confirmed by X-ray powder diffraction, IR spectroscopy, thermogravimetry, and elemental analysis.

AB - Chiral metal-organic coordination polymers [Co2(sacch) 2]·1/2H2O·CH3OH (1), [Cu(sacch)(H2O)2]·3H2O (2), and [Mg(H2O)3(sacch)] (3) (H2sacch is d-saccharic acid) were synthesized from aqueous or water-methanol solutions of potassium hydrogen saccharate and a salt of the corresponding metal. The compositions and structures of the resulting compounds were determined by single-crystal X-ray diffraction and confirmed by X-ray powder diffraction, IR spectroscopy, thermogravimetry, and elemental analysis.

KW - X-ray diffraction

KW - chiral complexes

KW - cobalt(ii) complexes

KW - coordination polymers

KW - copper(ii) complexes

KW - magnesium complexes

KW - saccharic acid

UR - http://www.scopus.com/inward/record.url?scp=84891758406&partnerID=8YFLogxK

U2 - 10.1007/s11172-013-0098-x

DO - 10.1007/s11172-013-0098-x

M3 - Article

AN - SCOPUS:84891758406

SN - 1066-5285

VL - 62

SP - 716

EP - 721

JO - Russian Chemical Bulletin

JF - Russian Chemical Bulletin

IS - 3

ER -