Synthesis and structure of [{ButP2H}K·pmdeta]2, containing an organo diphosphido ligand [pmdeta = (Me2NCH2CH2)2NMe]

Michael A. Beswick; Alexander D. Hopkins; Lesley C. Kerr; Marta E.G. Mosquera; Julie S. Palmer; Paul R. Raithby; Alexander Rothenberger; D. Stalke; Alexander Steiner; Andrew E.H. Wheatley; Dominic S. Wright

doi:10.1039/a803834a

Synthesis and structure of [{Bu^tP₂H}K·pmdeta]₂, containing an organo diphosphido ligand [pmdeta = (Me₂NCH₂CH₂)₂NMe]

Michael A. Beswick, Alexander D. Hopkins, Lesley C. Kerr, Marta E.G. Mosquera, Julie S. Palmer, Paul R. Raithby, Alexander Rothenberger, D. Stalke, Alexander Steiner, Andrew E.H. Wheatley, Dominic S. Wright^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

27 Scopus citations

Abstract

Reduction of [Bu^tP]₄ with K metal (1:5 equiv.) followed by the addition of pmdeta and stoichiometric hydrolysis gives [{(Bu^tP)₂H}K·pmdeta]₂, a unique complex containing a [Bu^tP(H)PBu^t]^- anion ligand homologous with a phosphido anion (R₂P^-).

Original language	English (US)
Pages (from-to)	1527-1528
Number of pages	2
Journal	CHEMICAL COMMUNICATIONS
Issue number	15
DOIs	https://doi.org/10.1039/a803834a
State	Published - Aug 7 1998
Externally published	Yes

ASJC Scopus subject areas

Catalysis
Electronic, Optical and Magnetic Materials
Ceramics and Composites
General Chemistry
Surfaces, Coatings and Films
Metals and Alloys
Materials Chemistry

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Beswick, M. A., Hopkins, A. D., Kerr, L. C., Mosquera, M. E. G., Palmer, J. S., Raithby, P. R., Rothenberger, A., Stalke, D., Steiner, A., Wheatley, A. E. H., & Wright, D. S. (1998). Synthesis and structure of [{Bu^tP₂H}K·pmdeta]₂, containing an organo diphosphido ligand [pmdeta = (Me₂NCH₂CH₂)₂NMe]. CHEMICAL COMMUNICATIONS, (15), 1527-1528. https://doi.org/10.1039/a803834a

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title = "Synthesis and structure of [{ButP2H}K·pmdeta]2, containing an organo diphosphido ligand [pmdeta = (Me2NCH2CH2)2NMe]",

abstract = "Reduction of [ButP]4 with K metal (1:5 equiv.) followed by the addition of pmdeta and stoichiometric hydrolysis gives [{(ButP)2H}K·pmdeta]2, a unique complex containing a [ButP(H)PBut]- anion ligand homologous with a phosphido anion (R2P-).",

author = "Beswick, {Michael A.} and Hopkins, {Alexander D.} and Kerr, {Lesley C.} and Mosquera, {Marta E.G.} and Palmer, {Julie S.} and Raithby, {Paul R.} and Alexander Rothenberger and D. Stalke and Alexander Steiner and Wheatley, {Andrew E.H.} and Wright, {Dominic S.}",

year = "1998",

month = aug,

day = "7",

doi = "10.1039/a803834a",

language = "English (US)",

pages = "1527--1528",

journal = "CHEMICAL COMMUNICATIONS",

issn = "1359-7345",

publisher = "ROYAL SOC CHEMISTRY",

number = "15",

}

TY - JOUR

T1 - Synthesis and structure of [{ButP2H}K·pmdeta]2, containing an organo diphosphido ligand [pmdeta = (Me2NCH2CH2)2NMe]

AU - Beswick, Michael A.

AU - Hopkins, Alexander D.

AU - Kerr, Lesley C.

AU - Mosquera, Marta E.G.

AU - Palmer, Julie S.

AU - Raithby, Paul R.

AU - Rothenberger, Alexander

AU - Stalke, D.

AU - Steiner, Alexander

AU - Wheatley, Andrew E.H.

AU - Wright, Dominic S.

PY - 1998/8/7

Y1 - 1998/8/7

N2 - Reduction of [ButP]4 with K metal (1:5 equiv.) followed by the addition of pmdeta and stoichiometric hydrolysis gives [{(ButP)2H}K·pmdeta]2, a unique complex containing a [ButP(H)PBut]- anion ligand homologous with a phosphido anion (R2P-).

AB - Reduction of [ButP]4 with K metal (1:5 equiv.) followed by the addition of pmdeta and stoichiometric hydrolysis gives [{(ButP)2H}K·pmdeta]2, a unique complex containing a [ButP(H)PBut]- anion ligand homologous with a phosphido anion (R2P-).

UR - http://www.scopus.com/inward/record.url?scp=0003089022&partnerID=8YFLogxK

U2 - 10.1039/a803834a

DO - 10.1039/a803834a

M3 - Article

AN - SCOPUS:0003089022

SN - 1359-7345

SP - 1527

EP - 1528

JO - CHEMICAL COMMUNICATIONS

JF - CHEMICAL COMMUNICATIONS

IS - 15

ER -

Synthesis and structure of [{Bu^tP₂H}K·pmdeta]₂, containing an organo diphosphido ligand [pmdeta = (Me₂NCH₂CH₂)₂NMe]

Abstract

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