Synthesis and structural characterization of macrocyclic carbohydrate derivatives obtained from catalytic metathesis reaction with chloro-aryloxide complexes of tungsten

Gérard Descotes; Jan Ramza; Jean Marie Basset; Salvatore Pagano; Emmanuel Gentil; Joseph Banoub

doi:10.1016/0040-4020(96)00612-6

Synthesis and structural characterization of macrocyclic carbohydrate derivatives obtained from catalytic metathesis reaction with chloro-aryloxide complexes of tungsten

Gérard Descotes^*, Jan Ramza, Jean Marie Basset, Salvatore Pagano, Emmanuel Gentil, Joseph Banoub

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

24 Scopus citations

Abstract

Tungsten aryloxo-complex 1 catalyses the intramolecular metathesis reactions of di- and tri-substituted ω-unsaturated glucose, and glucosamine derivatives, yielding bicyclic carbohydrate-based compounds 12, 13, 14, 15, containing 12-, and 14-atoms rings. Electrospray tandem mass spectrometry was used for the structural characterization of these novel bicyclic carbohydrate compounds.

Original language	English (US)
Pages (from-to)	10903-10920
Number of pages	18
Journal	Tetrahedron
Volume	52
Issue number	33
DOIs	https://doi.org/10.1016/0040-4020(96)00612-6
State	Published - Aug 12 1996
Externally published	Yes

ASJC Scopus subject areas

Biochemistry
Drug Discovery
Organic Chemistry

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title = "Synthesis and structural characterization of macrocyclic carbohydrate derivatives obtained from catalytic metathesis reaction with chloro-aryloxide complexes of tungsten",

abstract = "Tungsten aryloxo-complex 1 catalyses the intramolecular metathesis reactions of di- and tri-substituted ω-unsaturated glucose, and glucosamine derivatives, yielding bicyclic carbohydrate-based compounds 12, 13, 14, 15, containing 12-, and 14-atoms rings. Electrospray tandem mass spectrometry was used for the structural characterization of these novel bicyclic carbohydrate compounds.",

author = "G{\'e}rard Descotes and Jan Ramza and Basset, {Jean Marie} and Salvatore Pagano and Emmanuel Gentil and Joseph Banoub",

year = "1996",

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T1 - Synthesis and structural characterization of macrocyclic carbohydrate derivatives obtained from catalytic metathesis reaction with chloro-aryloxide complexes of tungsten

AU - Descotes, Gérard

AU - Ramza, Jan

AU - Basset, Jean Marie

AU - Pagano, Salvatore

AU - Gentil, Emmanuel

AU - Banoub, Joseph

PY - 1996/8/12

Y1 - 1996/8/12

N2 - Tungsten aryloxo-complex 1 catalyses the intramolecular metathesis reactions of di- and tri-substituted ω-unsaturated glucose, and glucosamine derivatives, yielding bicyclic carbohydrate-based compounds 12, 13, 14, 15, containing 12-, and 14-atoms rings. Electrospray tandem mass spectrometry was used for the structural characterization of these novel bicyclic carbohydrate compounds.

AB - Tungsten aryloxo-complex 1 catalyses the intramolecular metathesis reactions of di- and tri-substituted ω-unsaturated glucose, and glucosamine derivatives, yielding bicyclic carbohydrate-based compounds 12, 13, 14, 15, containing 12-, and 14-atoms rings. Electrospray tandem mass spectrometry was used for the structural characterization of these novel bicyclic carbohydrate compounds.

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U2 - 10.1016/0040-4020(96)00612-6

DO - 10.1016/0040-4020(96)00612-6

M3 - Article

AN - SCOPUS:0030581370

SN - 0040-4020

VL - 52

SP - 10903

EP - 10920

JO - Tetrahedron

JF - Tetrahedron

IS - 33

ER -

Synthesis and structural characterization of macrocyclic carbohydrate derivatives obtained from catalytic metathesis reaction with chloro-aryloxide complexes of tungsten

Abstract

ASJC Scopus subject areas

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